Surface Functionalization Modification of Metal Organic Frameworks with Polymer <italic style="font-style: italic">via</italic> Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

Hong-Ye Li; Zi-An Wang; Li-Ping Wang; Guang Li

doi:10.1007/s10118-026-3667-9

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Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

RESEARCH ARTICLE | Updated：2026-07-10

- Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation
- Chinese Journal of Polymer Science Vol. 44, Issue 8, Pages: 2797-2808(2026)
- Affiliations：
  
  School of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, China
- Author bio：
  
  wangliping5@163.com (L.P.W.)
  lglzsd@126.com (G.L.)
- Funds：
- DOI：10.1007/s10118-026-3667-9
  CLC：
- Received：22 April 2026，
  
  Accepted：16 May 2026，
  
  Online First：09 July 2026，
  
  Published：15 August 2026
- Accepted：
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Li, H. Y.; Wang, Z. A.; Wang, L. P.; Li, G. Surface functionalization modification of metal organic frameworks with polymer via metal-free atom transfer radical polymerization for oil-water separation. Chinese J. Polym. Sci. 2026, 44, 2797–2808

Hong-Ye Li, Zi-An Wang, Li-Ping Wang, et al. Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2797-2808. DOI: 10.1007/s10118-026-3667-9.
Li, H. Y.; Wang, Z. A.; Wang, L. P.; Li, G. Surface functionalization modification of metal organic frameworks with polymer via metal-free atom transfer radical polymerization for oil-water separation. Chinese J. Polym. Sci. 2026, 44, 2797–2808 DOI： 10.1007/s10118-026-3667-9.

Hong-Ye Li, Zi-An Wang, Li-Ping Wang, et al. Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2797-2808. DOI: 10.1007/s10118-026-3667-9. DOI：

摘要

PMMA were grafted from the surface of ZIF-8-Br using SI-metal-free ATRP. Compared to ZIF-8-NH

ZIF-8-

-PMMA exhibits improved water stability and hydrophobicity. The fabric modified with ZIF-8-

-PMMA exhibits superhydrophobicity

and the oil-water separation efficiency reaches 96%.

Abstract

We present a method for modifying metal organic frameworks (MOFs) surface functionalization using metal-free atom transfer radical polymerization (ATRP). Amino-functionalized zeolitic imidazolate frameworks-8 (ZIF-8-NH

) was synthesized at room temperature

and ZIF-8-Br was obtained by the reaction of the amino group in ZIF-8-NH

with the acyl bromide group in 2-bromoisobutyl bromide (BIBB)

thereby introducing secondary bromine groups onto the surface of ZIF-8-NH

. Then

ZIF-8-

-poly(methyl methacrylate) (ZIF-8-

-PMMA) hybrid materials were synthesized using ZIF-8-Br as an initiator

via

surface-initiated metal-free atom transfer radical polymerization (metal-free ATRP). The structural and morphological evolutions were monitored using Fourier transform infrared spectroscopy (FTIR)

X-ray photoelectron spectroscopy (XPS)

X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) measurements. Thermogravimetry (TG) analysis verified that ZIF-8-

PMMA had excellent thermal stability

and the water stability test demonstrated that after grafting PMMA from the ZIF-8-NH

surface

the hydrophobicity and water stability were improved significantly. The BET results proved that ZIF-8-

PMMA had a high specific surface area of 835.24 m

/g. By immobilizing ZIF-8-

-PMMA hybrid material on fabrics

the modified fabrics exhibit excellent superhydrophobicity

with the water contact angle as high as 159.2

. Attributed to the synergistic effect of the micro- and nano-graded porous structure and low-surface-energy PMMA coatings

ZIF-8-

-PMMA hybrid material modified fabrics achieves highly efficient oil-water separation

with excellent adsorption effects on both light and heavy oils. Among them

the heavy oil can pass through the modified fabric within seconds with an oil-water separation efficiency of 96%. This method will further expand the scope of application of metal-free ATRP technology and MOFs materials.

关键词

Keywords

references

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⁰

Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

DOI：10.1007/s10118-026-3667-9

摘要

Abstract

关键词

Keywords

references