Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites

Zi-Ye Liu; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-026-3632-7

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Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites

RESEARCH ARTICLE | Updated：2026-07-01

- Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites
- Chinese Journal of Polymer Science Vol. 44, Issue 7, Pages: 2341-2351(2026)
- Affiliations：
  
  MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China
- Author bio：
  
  s_yh0411@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-026-3632-7
  CLC：
- Received：04 January 2026，
  
  Accepted：24 February 2026，
  
  Online First：20 May 2026，
  
  Published：05 July 2026
- Accepted：
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Liu, Z. Y.; Song, Y. H.; Zheng, Q. Influence of antioxidants and deep eutectic solvent on vulcanization kinetics and mechanical behaviors of natural rubber/styrene-butadiene rubber blend and composites. Chinese J. Polym. Sci. 2026, 44, 2341–2351

Zi-Ye Liu, Yi-Hu Song, Qiang Zheng. Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2341-2351.
Liu, Z. Y.; Song, Y. H.; Zheng, Q. Influence of antioxidants and deep eutectic solvent on vulcanization kinetics and mechanical behaviors of natural rubber/styrene-butadiene rubber blend and composites. Chinese J. Polym. Sci. 2026, 44, 2341–2351 DOI： 10.1007/s10118-026-3632-7.

Zi-Ye Liu, Yi-Hu Song, Qiang Zheng. Influence of Antioxidants and Deep Eutectic Solvent on Vulcanization Kinetics and Mechanical Behaviors of Natural Rubber/Styrene-Butadiene Rubber Blend and Composites[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2341-2351. DOI： 10.1007/s10118-026-3632-7.

摘要

Deep eutectic solvent (DES) modulates vulcanization kinetics and crosslinking structure; when combined with MB and carbon black (CB)/black talc (BT)

it facilitates the preparation of high-strength natural rubber (NR)/styrene-butadiene rubber (SBR) composites with reduced hysteresis and weakened Mullins effect.

Abstract

Antioxidants are generally used for prolonging the lifespan of rubber products

while their influences on the vulcanization kinetics and mechanical properties are rarely investigated. Herein

the synergistic roles of conventional antioxidants (6PPD

2246) and deep eutectic solvent (DES) in natural rubber (NR)

styrene-butadiene rubber (SBR)

their blends

and the blends filled with carbon black (CB) and black talc (BT) were examined. The results showed that antioxidants and DES influenced the vulcanization kinetics

crosslinking density and mechanical behaviors markedly. A combination of MB and DES resulted in NR/SBR-CB/BT composite vulcanizates with high strength and low dissipation characteristics. DES formed hydrogen bond/ion-pair complexes with antioxidants

and

in NR

interacted with non-rubber constituents

thereby modulating cure intermediates and sulfur-bond distributions

paving the way for preparing high performance rubber composites.

关键词

Keywords

references

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