Nucleation of Polymers in Nanopores and Nanocomposites with Nanoparticles/Nanosheets

Ming Wang; Ye Yao; Hui Zhao; Wei-Long Ju; Yun-Lan Su; Du-Jin Wang; Guo-Ming Liu

doi:10.1007/s10118-025-3508-2

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Nucleation of Polymers in Nanopores and Nanocomposites with Nanoparticles/Nanosheets

FEATURE ARTICLE | Updated：2025-12-26

- Nucleation of Polymers in Nanopores and Nanocomposites with Nanoparticles/Nanosheets
- Chinese Journal of Polymer Science Vol. 44, Pages: 1-12(2026)
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino-Alessandria Campus, Alessandria 15121, Italy
- Author bio：
  
  ylsu@iccas.ac.cn (Y.L.S.)
  gmliu@iccas.ac.cn (G.M.L.)
- Funds：
- DOI：10.1007/s10118-025-3508-2
  CLC：
- Received：16 October 2025，
  
  Accepted：19 November 2025，
  
  Published Online：25 December 2025，
  
  Published：15 January 2026
- Accepted：
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Wang, M.; Yao, Y.; Zhao, H.; Ju, W. L.; Su, Y. L.; Wang, D. J.; Liu, G. M. Nucleation of polymers in nanopores and nanocomposites with nanoparticles/nanosheets. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-025-3508-2

Ming Wang, Ye Yao, Hui Zhao, et al. Nucleation of Polymers in Nanopores and Nanocomposites with Nanoparticles/Nanosheets[J/OL]. Chinese Journal of Polymer Science, 2026, 441-12.
Wang, M.; Yao, Y.; Zhao, H.; Ju, W. L.; Su, Y. L.; Wang, D. J.; Liu, G. M. Nucleation of polymers in nanopores and nanocomposites with nanoparticles/nanosheets. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-025-3508-2 DOI：

Ming Wang, Ye Yao, Hui Zhao, et al. Nucleation of Polymers in Nanopores and Nanocomposites with Nanoparticles/Nanosheets[J/OL]. Chinese Journal of Polymer Science, 2026, 441-12. DOI： 10.1007/s10118-025-3508-2.

摘要

This feature article reviews recent advances in polymer nucleation under confined and interface-dominated conditions

focusing on AAO templates and nanocomposites containing nanoparticles or nanosheets. The interplay of finite-size and interfacial effects gives rise to distinctive phenomena

including homogeneous nucleation

surface nucleation

prefreezing

and supernucleation.

Abstract

Nucleation

which is the initial step of crystallization

critically governs the polymer crystallization behavior

influencing the crystallization temperature

kinetics

and morphology. However

the direct observation of the nucleation process in polymers remains elusive owing to spatial and temporal resolution limitations. This feature article summarizes the recent progress in understanding polymer nucleation within confined and interface-dominated environments

focusing on three representative systems: anodic aluminum oxide templates and nanocomposites containing nanoparticles or nanosheets. The interplay between finite size and interfacial effects has revealed some novel phenomena

such as homogeneous nucleation

surface nucleation

prefreezing

and supernucleation.

关键词

Keywords

references

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