Covalent Organic Framework/Carbon Nanotube Composites for Enhanced Lithium-ion Battery Performance

Yu Wu; Hui Liu; Jia-Heng Hou; Qing-Yan Pan; Nai-Xiu Ding; Ying-Jie Zhao

doi:10.1007/s10118-025-3432-5

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Covalent Organic Framework/Carbon Nanotube Composites for Enhanced Lithium-ion Battery Performance

RESEARCH ARTICLE | Updated：2026-04-30

- Covalent Organic Framework/Carbon Nanotube Composites for Enhanced Lithium-ion Battery Performance
- Chinese Journal of Polymer Science Vol. 44, Issue 5, Pages: 1355-1363(2026)
- Affiliations：
  
  Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266000, China
- Author bio：
  
  qingyanpan@qust.edu.cn (Q.Y.P.)
  nxding1717@163.com (N.X.D.)
  yz@qust.edu.cn (Y.J.Z.)
- Funds：
- DOI：10.1007/s10118-025-3432-5
  CLC：
- Received：02 July 2025，
  
  Accepted：08 August 2025，
  
  Online First：22 December 2025，
  
  Published：05 May 2026
- Accepted：
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Wu, Y.; Liu, H.; Hou, J. H.; Pan, Q. Y.; Ding, N. X.; Zhao, Y. J. Covalent organic framework/carbon nanotube composites for enhanced lithium-ion battery performance. Chinese J. Polym. Sci. 2026, 44, 1355–1363

Yu Wu, Hui Liu, Jia-Heng Hou, et al. Covalent Organic Framework/Carbon Nanotube Composites for Enhanced Lithium-ion Battery Performance[J]. Chinese Journal of Polymer Science, 2026, 44(5): 1355-1363.
Wu, Y.; Liu, H.; Hou, J. H.; Pan, Q. Y.; Ding, N. X.; Zhao, Y. J. Covalent organic framework/carbon nanotube composites for enhanced lithium-ion battery performance. Chinese J. Polym. Sci. 2026, 44, 1355–1363 DOI： 10.1007/s10118-025-3432-5.

Yu Wu, Hui Liu, Jia-Heng Hou, et al. Covalent Organic Framework/Carbon Nanotube Composites for Enhanced Lithium-ion Battery Performance[J]. Chinese Journal of Polymer Science, 2026, 44(5): 1355-1363. DOI： 10.1007/s10118-025-3432-5.

摘要

This study develops a new electrode material by hybridizing covalent organic frameworks (COFs) with carbon nanotubes to enhance charge transfer

stability

and cycling performance in lithium-ion batteries.

Abstract

This study focuses on the development and optimization of electrode materials composed of covalent organic frameworks (COFs) integrated with carbon nanotubes (CNTs) for lithium-ion battery applications. The findings reveal that incorporating CNTs into COFs markedly enhances their electrochemical performance by reducing charge transfer resistance and accelerating charge transport kinetics. Impressively

the COFs/CNT composites delivered a high specific capacity of 307 mAh·g

–1

at a low current density of 0.05 A·g

–1

and maintained strong capacity retention even at elevated current densities. Furthermore

the composites demonstrated outstanding cycling stability and structural robustness

retaining significant capacity after 1000 charge/discharge cycles.

关键词

Keywords

references

Song, Z.; Zhou, H. Towards sustainable and versatile energy storage devices: an overview of organic electrode materials. Energy Environ. Sci. 2013 , 6 , 2280−2301..

Xu, K. Electrolytes and interphases in Li-ion batteries and beyond. Chem. Rev. 2014 , 114 , 11503−11618..

Goodenough, J. B.; Park, K.S. The Li-ion rechargeable battery: a perspective. J. Am. Chem. Soc. 2013 , 135 , 1167−1176..

Ren, Y.; Xu, Y. Recent advances in two-dimensional polymers: synthesis, assembly and energy-related applications. Chem. Soc. Rev. 2024 , 53 , 1823−1869..

Li, W.; Song, B.; Manthiram, A. High-voltage positive electrode materials for lithium-ion batteries. Chem. Soc. Rev. 2017 , 46 , 3006−3059..

Weiss, M.; Ruess, R.; Kasnatscheew, J.; Levartovsky, Y.; Levy, N. R.; Minnmann, P.; Stolz, L.; Waldmann, T.; Wohlfahrt-Mehrens, M.; Aurbach, D.; Winter, M.; Ein-Eli, Y.; Janek, J. Fast charging of lithium-ion batteries: a review of materials aspects. Adv. Energy Mater. 2021 , 11 , 2101126..

Wu, F.; Maier, J.; Yu, Y. Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries. Chem. Soc. Rev. 2020 , 49 , 1569−1614..

Zhu, D.; Xu, G.; Barnes, M.; Li, Y.; Tseng, C. P.; Zhang, Z.; Zhang, J. J.; Zhu, Y.; Khalil, S.; Rahman, M. M.; Verduzco, R.; Ajayan, P. M. Covalent organic frameworks for batteries. Adv. Funct. Mater. 2021 , 31 , 2100505..

Haldar, S.; Schneemann, A.; Kaskel, S. Covalent organic frameworks as model materials for fundamental and mechanistic understanding of organic battery design principles. J. Am. Chem. Soc. 2023 , 145 , 13494−13513..

Geng, K.; He, T.; Liu, R.; Dalapati, S.; Tan, K. T.; Li, Z.; Tao, S.; Gong, Y.; Jiang, Q.; Jiang, D. Covalent organic frameworks: design, synthesis, and functions. Chem. Rev. 2020 , 120 , 8814−8933..

Ding, S.-Y.; Wang, W. Covalent organic frameworks (COFs): from design to applications. Chem. Soc. Rev. 2013 , 42 , 548−568..

Xu, S.; Wang, G.; Biswal, B. P.; Addicoat, M.; Paasch, S.; Sheng, W.; Zhuang, X.; Brunner, E.; Heine, T.; Berger, R.; Feng, X. A nitrogen-rich 2D sp2-carbon-linked conjugated polymer framework as a high-performance cathode for lithium-ion batteries. Angew. Chem. Int. Ed. 2019 , 58 , 849−853..

Côté, A. P.; Benin, A. I.; Ockwig, N. W.; O'Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Porous, crystalline, covalent organic frameworks. Science 2005 , 310 , 1166−1170..

Jiang, Y.; Zhang, Z.; Chen, D.; Du, J.; Yang, Y.; Wang, S.; Guo, F.; Chen, X.; Gao, C.; Wang, W. J.; Liu, P. Vertical growth of 2D covalent organic framework nanoplatelets on a macroporous scaffold for high-performance electrodes. Adv. Mater. 2022 , 34 , 2204250..

Xu, X.; Zhang, S.; Xu, K.; Chen, H.; Fan, X.; Huang, N. Janus dione-based conjugated covalent organic frameworks with high conductivity as superior cathode materials. J. Am. Chem. Soc. 2023 , 145 , 1022−1030..

Li, S. Y.; Li, W. H.; Wu, X. L.; Tian, Y.; Yue, J.; Zhu, G. Pore-size dominated electrochemical properties of covalent triazine frameworks as anode materials for K-ion batteries. Chem. Sci. 2019 , 10 , 7695−7701..

Wu, M.; Zhao, Y.; Zhao, R.; Zhu, J.; Liu, J.; Zhang, Y.; Li, C.; Ma, Y.; Zhang, H.; Chen, Y. Chemical design for both molecular and morphology optimization toward high-performance lithium-ion batteries cathode material based on covalent organic framework. Adv. Funct. Mater. 2022 , 32 , 2107703..

Yang, Y.; Zhang, C.; Zhao, G.; An, Q.; Mei, Z.-y.; Sun, Y.; Xu, Q.; Wang, X.; Guo, H. Regulating the electron structure of covalent organic frameworks by strong electron-withdrawing nitro to construct specific Li + oriented channel. Adv. Energy Mater. 2023 , 13 , 2300725..

Wang, S.; Wang, Q.; Shao, P.; Han, Y.; Gao, X.; Ma, L.; Yuan, S.; Ma, X.; Zhou, J.; Feng, X.; Wang, B. Exfoliation of covalent organic frameworks into few-layer redox-active nanosheets as cathode materials for lithium-ion batteries. J. Am. Chem. Soc. 2017 , 139 , 4258−4261..

Lei, Z.; Yang, Q.; Xu, Y.; Guo, S.; Sun, W.; Liu, H.; Lv, L. P.; Zhang, Y.; Wang, Y. Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry. Nat. Commun. 2018 , 9 , 576..

[Li, M.; Liu, J.; Zhang, T.; Song, X.; Chen, W.; Chen, L. 2D redox-active covalent organic frameworks for supercapacitors: design, synthesis, and challenges. Small 2021, 17 , 2005073..

Zhang, Y.; Riduan, S. N.; Wang, J. Redox active metal– and covalent organic frameworks for energy storage: balancing porosity and electrical conductivity. Chem. Eur. J. 2017 , 23 , 16419−16431..

Zhao, G.; Li, H.; Gao, Z.; Xu, L.; Mei, Z.; Cai, S.; Liu, T.; Yang, X.; Guo, H.; Sun, X. Dual-active-center of polyimide and triazine modified atomic-layer covalent organic frameworks for high-performance li storage. Adv. Funct. Mater. 2021 , 31 , 2101019..

Zhao, G.; Zhang, Y.; Gao, Z.; Li, H.; Liu, S.; Cai, S.; Yang, X.; Guo, H.; Sun, X. Dual active site of the azo and carbonyl-modified covalent organic framework for high-performance Li storage. ACS Energy Lett. 2020 , 5 , 1022−1031..

Yang, X.; Gong, L.; Liu, X.; Zhang, P.; Li, B.; Qi, D.; Wang, K.; He, F.; Jiang, J. Mesoporous polyimide-linked covalent organic framework with multiple redox-active sites for high-performance cathodic Li storage. Angew. Chem. Int. Ed. 2022 , 61 , e202207043..

Xu, F.; Jin, S.; Zhong, H.; Wu, D.; Yang, X.; Chen, X.; Wei, H.; Fu, R.; Jiang, D. Electrochemically active, crystalline, mesoporous covalent organic frameworks on carbon nanotubes for s ynergistic lithium-ion battery energy storage. Sci. Rep. 2015 , 5 , 8225..

Wang, K.; Jia, Z.; Bai, Y.; Wang, X.; Hodgkiss, S. E.; Chen, L.; Chong, S. Y.; Wang, X.; Yang, H.; Xu, Y.; Feng, F.; Ward, J. W.; Cooper, A. I. Synthesis of stable thiazole-linked covalent organic frameworks via a multicomponent reaction. J. Am. Chem. Soc. 2020 , 142 , 11131−11138..

Kong, L.; Liu, M.; Huang, H.; Xu, Y.; Bu, X. H. Metal/covalent-organic framework based cathodes for metal-ion batteries. Adv. Energy Mater. 2022 , 12 , 2100172..

Zhou, L.; Jo, S.; Park, M.; Fang, L.; Zhang, K.; Fan, Y.; Hao, Z.; Kang, Y.-M. Structural engineering of covalent organic frameworks for rechargeable batteries. Adv. Energy Mater. 2021 , 11 , 2003054..

Chen, X.; Li, Y.; Wang, L.; Xu, Y.; Nie, A.; Li, Q.; Wu, F.; Sun, W.; Zhang, X.; Vajtai, R.; Ajayan, P. M.; Chen, L.; Wang, Y. High-lithium-affinity chemically exfoliated 2D covalent organic frameworks. Adv. Mater. 2019 , 31 , 1901640..

Zhao,J.; Zhou, M.; Chen, J.; Wang, L.; Zhang, Q.; Zhong, S.; Xie, H.; Li, Y. Two birds one stone: graphene assisted reaction kinetics and ionic conductivity in phthalocyanine-based covalent organic framework anodes for lithium-ion batteries. Small 2023 , 19 , 2303353..

Luo, Z.; Liu, L.; Ning, J.; Lei, K.; Lu, Y.; Li, F.; Chen, J. A microporous covalent–organic framework with abundant accessible carbonyl groups for lithium-ion batteries. Angew. Chem. Int. Ed. 2018 , 57 , 9443−9446..

Wang, H.; Zeng, Z.; Xu, P.; Li, L.; Zeng, G.; Xiao, R.; Tang, Z.; Huang, D.; Tang, L.; Lai, C.; Jiang, D.; Liu, Y.; Yi, H.; Qin, L.; Ye, S.; Ren, X.; Tang, W. Recent progress in covalent organic framework thin films: fabrications, applications and perspectives. Chem. Soc. Rev. 2019 , 48 , 488−516..

Xu, S.; Wu, J.; Wang, X.; Zhang, Q. Recent advances in the utilization of covalent organic frameworks (COFs) as electrode materials for supercapacitors. Chem. Sci. 2023 , 14 , 13601−13628..

Luo, X. X.; Li, W. H.; Liang, H. J.; Zhang, H. X.; Du, K. D.; Wang, X. T.; Liu, X.F.; Zhang, J. P.; Wu, X. L. Covalent organic framework with highly accessible carbonyls and π -cation effect for advanced potassium-ion batteries. Angew. Chem. Int. Ed. 2022 , 61 , e202117661..

Chen, X.; Zhang, H.; Ci, C.; Sun, W.; Wang, Y. Few-Layered boronic ester based covalent organic frameworks/carbon nanotube composites for high-performance k-organic batteries. ACS Nano 2019 , 13 , 3600−3607..

Gao, H.; Zhu, Q.; Neale, A. R.; Bahri, M.; Wang, X.; Yang, H.; Liu, L.; Clowes, R.; Browning, N. D.; Sprick, R. S.; Little, M. A.; Hardwick, L. J.; Cooper, A. I. Integrated covalent organic framework/carbon nanotube composite as Li-ion positive electrode with ultra-high rate performance. Adv. Energy Mater. 2021 , 11 , 2101880..

Gao, H.; Neale, A. R.; Zhu, Q.; Bahri, M.; Wang, X.; Yang, H.; Xu, Y.; Clowes, R.; Browning, N. D.; Little, M. A.; Hardwick, L. J.; Cooper, A. I. A pyrene-4,5,9,10-tetraone-based covalent organic framework delivers high specific capacity as a Li-ion positive electrode. J. Am. Chem. Soc. 2022 , 144 , 9434−9442..

Wang, G.; Chandrasekhar, N.; Biswal, B. P.; Becker, D.; Paasch, S.; Brunner, E.; Addicoat, M.; Yu, M.; Berger, R.; Feng, X. A crystalline, 2D polyarylimide cathode for ultrastable and ultrafast Li storage. Adv. Mater. 2019 , 31 , 1901478..

Xu, Q.; Liu, Z.; Jin, Y.; Yang, X.; Sun, T.; Zheng, T.; Li, N.; Wang, Y.; Li, T.; Wang, K.; Jiang, J. A bipolar-type covalent organic framework on carbon nanotubes with enhanced density of redox-active sites for high-performance lithium-ion batteries. Energy Environ. Sci. 2024 , 17 , 5451−5460..

Yang, X.; Lin, C.; Han, D.; Li, G.; Huang, C.; Liu, J.; Wu, X.; Zhai, L.; Mi, L. In situ construction of redox-active covalent organic frameworks/carbon nanotube composites as anodes for lithium-ion batteries. J. Mater. Chem. A 2022 , 10 , 3989−3995..

Chen, L.; Li, Y.; Zhang, Y.; Ren, S. B.; Bi, J.; Xue, X.; Han, D. M.; Wu, D.; Wang, Y.; Chen, X.; Wu, Y. Pyrene-4,5,9,10-tetraone-based covalent organic framework/carbon nanotube composite as sodium-ion cathodes with high-rate capability. Chem. Eng. J. 2024 , 497 , 154743..

Jia, C.; Duan, A.; Liu, C.; Wang, W. Z.; Gan, S. X.; Qi, Q. Y.; Li, Y.; Huang, X.; Zhao, X. One-dimensional covalent organic framework as high-herformance cathode materials for lithium-ion batteries. Small 2023 , 19 , 2300518..

Yan, D.; Song, L.; Kang, F.; Mo, X.; Lv, Y.; Sun, J.; Tang, H.; Zhou, X.; Zhang, Q. In situ growth of covalent organic frameworks on carbon nanotubes for high-performance potassium-ion batteries. Angew. Chem. Int. Ed. 2024 , 64 , e202422851..

Zhao, J.; Zhou, M.; Chen, J.; Tao, L.; Zhang, Q.; Li, Z.; Zhong, S.; Fu, H.; Wang, H.; Wu, L. Phthalocyanine-based covalent organic frameworks as novel anode materials for high-performance lithium-ion/sodium-ion batteries. Chem. Eng. J. 2021 , 425 , 131630..

Hou, J.; Liu, H.; Gao, M.; Pan, Q.; Zhao, Y. Triazine-based large-sized single-crystalline two-dimensional covalent organic framework for high-performance lithium-ion batteries. Angew. Chem. Int. Ed. 2025 , 64 , e202414566..

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