Investigating the Influence of Printing Parameters on the Helical Deformation of 4D-printed Liquid Crystal Elastomer Fiber-actuators

Chun Zhang; Reyihanguli Muhetaer; Tong-Zhi Zang; Shuang Fu; Jun-Peng Cheng; Li Yang; Jian Wang; Kun Yang; Guo-Xia Fei; Qing-Yuan Wang; Xi-Li Lu; He-Sheng Xia; Yue Zhao

doi:10.1007/s10118-025-3288-8

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Investigating the Influence of Printing Parameters on the Helical Deformation of 4D-printed Liquid Crystal Elastomer Fiber-actuators

RESEARCH ARTICLE | Updated：2025-07-14

- Investigating the Influence of Printing Parameters on the Helical Deformation of 4D-printed Liquid Crystal Elastomer Fiber-actuators
- Chinese Journal of Polymer Science Vol. 43, Issue 4, Pages: 605-615(2025)
- Affiliations：
  
  a.Institute for Advanced Study, Chengdu University, Chengdu 610106, China
  b.National Key Laboratory of Advanced Polymer Materials, Polymer Research Institute, Sichuan University, Chengdu 610065, China
  c.Center for Molecular Science and Engineering, College of Science, Northeastern University, Shenyang 110819, China
  d.Département de chimie, Université de Sherbrooke, Sherbrooke, Québec J1K 2R1, Canada
- Author bio：
  
  feiguoxia@scu.edu.cn (G.X.F.)
  wangqy@scu.edu.cn (Q.Y.W.)
  xililu@scu.edu.cn (X.L.L.)
  xiahs@scu.edu.cn (H.S.X.)
- Funds：
- DOI：10.1007/s10118-025-3288-8
  CLC：
- Received：26 November 2024，
  
  Revised：06 January 2025，
  
  Accepted：07 January 2025，
  
  Published Online：24 February 2025，
  
  Published：01 April 2025
- Accepted：
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Zhang, C.; Muhetaer, R.; Zang, T. Z.; Fu, S.; Cheng, J. P.; Yang, L.; Wang, J.; Yang, K.; Fei, G. X.; Wang, Q. Y.; Lu, X. L.; Xia, H. S.; Zhao, Y. Investigating the influence of printing parameters on the helical deformation of 4D-printed liquid crystal elastomer fiber-actuators. Chinese J. Polym. Sci. 2025, 43, 605–615

Chun Zhang, Reyihanguli Muhetaer, Tong-Zhi Zang, et al. Investigating the Influence of Printing Parameters on the Helical Deformation of 4D-printed Liquid Crystal Elastomer Fiber-actuators[J]. Chinese journal of polymer science, 2025, 43(4): 605-615.
Zhang, C.; Muhetaer, R.; Zang, T. Z.; Fu, S.; Cheng, J. P.; Yang, L.; Wang, J.; Yang, K.; Fei, G. X.; Wang, Q. Y.; Lu, X. L.; Xia, H. S.; Zhao, Y. Investigating the influence of printing parameters on the helical deformation of 4D-printed liquid crystal elastomer fiber-actuators. Chinese J. Polym. Sci. 2025, 43, 605–615 DOI： 10.1007/s10118-025-3288-8.

Chun Zhang, Reyihanguli Muhetaer, Tong-Zhi Zang, et al. Investigating the Influence of Printing Parameters on the Helical Deformation of 4D-printed Liquid Crystal Elastomer Fiber-actuators[J]. Chinese journal of polymer science, 2025, 43(4): 605-615. DOI： 10.1007/s10118-025-3288-8.

摘要

The plant-tendril-inspired

biomimetic liquid crystal elastomer fiber actuators shows various helical deformations via changing their three-dimensional structures and asymmetric core-sheath configurations using 4D-printing technology. The mechanism of helical shape-morphing behaviors of the fiber actuators is revealed by finite element simulations.

Abstract

Liquid crystal elastomers (LCEs) exhibit exceptional reversible deformation and unique physical properties owing to their order-disorder phase transition under external stimuli. Among these deformations

helical structures have attracted attention owing to their distinctive configurations and promising applications in biomimetics and microelectronics. However

the helical deformation behavior of fiber actuators is critically influenced by their morphologies and alignments; yet

the underlying mechanisms are not fully understood. Through a two-step aza-Michael addition reaction and direct ink writing (DIW) 4D printing technology

fiber-based LCE actuators with a core-sheath alignment structure were fabricated and exhibited reversible helical deformation upon heating. By adjusting the printing parameters

the filament number

width

thickness

and core-sheath structure of the fiber actuators can be precisely controlled

resulting in deformation behaviors

such as contraction

bending

and helical twisting. Finite element simulations were performed to investigate the deformation behaviors of the fiber actuators

providing insights into the variations in stress and strain during the shape-changing process

which can be used to explain the shape-morphing mechanism. These findings demonstrate that the precise tuning of printing parameters enables the controllable construction of LCE actuator morphology and customization of their functional properties

paving the way for advanced applications in smart fabrics

biomedical engineering

and flexible electronics.

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references

White, T. J.; Broer, D. J. Programmable and adaptive mechanics with liquid crystal polymer networks and elastomers. Nat. Mater. 2015 , 14 , 1087−1098..

Herbert, K. M.; Fowler, H. E.; McCracken, J. M.; Schlafmann, K. R.; Koch, J. A.; White, T. J. Synthesis and alignment of liquid crystalline elastomers. Nat. Rev. Mater. 2021 , 7 , 23−38..

Ware, T. H.; McConney, M. E.; Wie, J. J.; Tondiglia, V. P.; White, T. J. Voxelated liquid crystal elastomers. Science 2015 , 347 , 982−984..

Nie, Z. Z.; Wang, M.; Huang, S.; Liu, Z. Y.; Yang, H. Multimodal self-sustainable autonomous locomotions of light-driven Seifert ribbon actuators based on liquid crystal elastomers. Angew. Chem. Int. Ed. 2023 , 62 , e202304081..

Boothby, J. M.; Gagnon, J. C.; McDowell, E .; Van Volkenburg, T.; Currano, L.; Xia, Z. Y. An untethered soft robot based on liquid crystal elastomers. Soft Robot. 2022 , 9 , 154−162..

Guin, T.; Settle, M. J.; Kowalski, B. A.; Auguste, A. D.; Beblo, R. V.; Reich, G. W.; White, T. J. Layered liquid crystal elastomer actuators. Nat. Commun. 2018 , 9 , 2531..

Ohm, C.; Brehmer, M.; Zentel, R. Liquid crystalline elastomers as actuators and sensors. Adv. Mater. 2010 , 22 , 3366−3387..

Hou, W. H.;Wang, J.; Lv, J. A. Bioinspired liquid crystalline spinning enables scalable fabrication of high-performing fibrous artificial muscles. Adv. Mater. 2023 , 35 , 2211800..

Kim, I. H.; Choi, S.; Lee, J.; Jung, J.; Yeo, J.; Kim, J. T.; Ryu, S.; Ahn, S. K.; Kang, J.; Poulin, P.; Kim, S. O. Human-muscle-inspired single fibre actuator with reversible percolation. Nat. Nanotechnol. 2022 , 17 , 1198−1205..

Zhou, X. R.; Jin, B. J.; Zhu, Z.; Wu, J. J.; Zhao, Q.; Chen, G. C. Metal-ligand bonds based reprogrammable and re-processable supramolecular liquid c rystal elastomer network. Angew. Chem. Int. Ed. 2024 , 63 , e202409182..

Zeng, H.; Wani, O. M.; Wasylczyk, P.; Kaczmarek, R.; Priimagi, A. Self-regulating iris based on light-actuated liquid crystal elastomer. Adv. Mater. 2017 , 29 , 1701814..

Turiv, T.; Krieger, J.; Babakhanova, G.; Yu, H.; Shiyanovskii, S. V.; Wei, Q. H.; Kim, M. H.; Lavrentovich, O. D. Topology control of human fibroblast cells monolayer by liquid crystal elastomer. Sci. Adv. 2020 , 6 , eaaz6485..

Fu, P.; Li, H. M.; Gong, J.; Fan, Z. J.; Smith, A. T.; Shen, K. Y.; Khalfalla, T. O.; Huang, H. F.; Qian, X.; McCutcheon, J. R.; Sun, L. Y. 4D printing of polymers: techniques, materials, and prospects. Prog. Polym. Sci . 2022 , 126 , 101506..

Ghazal, A. F.; Zhang, M.; Mujumdar, A. S.; Ghamry, M. Progress in 4D/5D/6D printing of foods: applications and R & D opportunities. Crit. Rev. Food Sci. Nutr. 2023 , 63 , 7399−7422..

Zhou, X. L.; Ren, L. Q.; Song, Z. Y.; Li, G. W.; Zhang, J. F.; Li, B. Q.; Wu, Q.; Li, W. X.; Ren, L.; Liu, Q. P. Advances in 3D/4D printing of mechanical metamaterials: from manufacturing to applications. Compos. Part B Eng. 2023 , 254 , 110585..

Guan, Z. C.; Wang, L.; Bae, J. Advances in 4D printing of liquid crystalline elastomers: materials, techniques, and applications. Mater. Horiz. 2022 , 9 , 1825−1849..

Chen, M.; Gao, M.; Bai, L. C.; Zheng, H.; Qi, H. J.; Zhou, K. Recent advances in 4D printing of liquid crystal elastomers. Adv. Mater. 2023 , 35 , 2209566..

del Pozo, M.; Sol, J. A. H. P.; Schenning, A. P. H. J.; Debije, M. G. 4D printing of liquid crystals: What’s right for me? Adv. Mater. 2022 , 34 , 2104390..

Wan, X.; Luo, L.; Liu, Y. J.; Leng, J. S. Direct ink writing based 4D printing of materials and their applications. Adv. Sci. 2020 , 7 , 2001000..

Wang, Q. R.; Tian, X. Y.; Zhang, D. K.; Zhou, Y. L.; Yan, W. Q.; Li, D. C. Programmable spatial deformation by controllable off-center freestanding 4D printing of continuous fiber reinforced liquid crystal elast omer composites. Nat. Commun. 2023 , 14 , 3869..

Zhai, F.; Feng, Y. Y.; Li, Z. Y.; Xie, Y. X.; Ge, J.; Wang, H.; Qiu, W.; Feng, W. 4D-printed untethered self-propelling soft robot with tactile perception: rolling, racing, and exploring. Matter , 2021 , 4 , 3313−3326..

Ambulo, C. P.; Burroughs, J. J.; Boothby, J. M.; Kim, H.; Ravi Shankar, M.; Ware, T. H. Four-dimensional printing of liquid crystal elastomers. ACS Appl. Mater. Interfaces 2017 , 9 , 37332−37339..

Kotikian, A.; McMahan, C.; Davidson, E. C.; Muhammad, J. M.; Weeks, R. D.; Daraio, C.; Lewis, J. A. Untethered soft robotic matter with passive control of shape morphing and propulsion. Sci. Robot. 2019 , 4 , eaax7044..

Zhang, C.; Lu, X. L.; Fei, G. X.; Wang, Z. H.; Xia, H. S.; Zhao, Y. 4D printing of a liquid crystal elastomer with a controllable orientation gradient. ACS Appl. Mater. Interfaces 2019 , 11 , 44774−44782..

Ren, L. Q.; Li, B. Q.; He, Y. L.; Song, Z. Y.; Zhou, X. L.; Liu, Q. P.; Ren, L. Programming shape-morp hing behavior of liquid crystal elastomers via parameter-encoded 4D printing. ACS Appl. Mater. Interfaces 2020 , 12 , 15562−15572..

Wang, Z. J.; Wang, Z. J.; Zheng, Y.; He, Q. G.; Wang, Y.; Cai, S. Q. Three-dimensional printing of functionally graded liquid crystal elastomer. Sci. Adv. 2020 , 6 , eabc0034..

Liang, H.; Liu, Y. W.; Xu, H. T.; Yang, Y.; He, E. J.; Yang, Z. J.; Wei, Y.; Ji, Y. Thiol-acrylate catalyst enabled post-synthesis fabrication of liquid crystal actuators. Chin ese J. Polym. Sci ., 2023 , 41 , 1656-1662..

Sun, J. H.; Liao, W.; Yang, Z. Q. Additive manufacturing of liquid crystal elastomer actuators based on knitting technology. Adv. Mater. 2023 , 35 , 2302706..

Gerbode, S. J.; Puzey, J. R.; McCormick, A. G.; Mahadevan, L. How the cucumber tendril coils and overwinds. Science 2012 , 337 , 1087−1091..

Hu, Z. M.; Li, Y. L.; Lv, J. A. Phototunable self-oscillating system driven by a sel f-winding fiber actuator. Nat. Commun. 2021 , 12 , 3211..

Farahani, R. D.; Chizari, K.; Therriault, D. Three-dimensional printing of freeform helical microstructures: a review. Nanoscale 2014 , 6 , 10470−10485..

Wang, Y. P.; Sun, J. H.; Liao, W.; Yang, Z. Q. Liquid crystal elastomer twist fibers toward rotating microengines. Adv. Mater. 2022 , 34 , 2107840..

Lugger, S. J. D.; Engels, T. A. P.; Cardinaels, R.; Bus, T.; Mulder, D. J.; Schenning, A. P. H. J. Melt-extruded thermoplastic liquid crystal elastomer rotating fiber actuators. Adv. Funct. Mater. 2023 , 33 , 2306853..

Cui, B.; Ren, M.; Dong, L. Z.; Wang, Y. L.; He, J. F.; Wei, X. L.; Zhao, Y. R.; Xu, P. P.; Wang, X. N.; Di, J. T.; Li, Q. W. Pretension-free and self-recoverable coiled artificial muscle fibers with powerful cyclic work capability. ACS Nano 2023 , 17 , 12809−12819..

Chen, Z.; Majidi, C.; Srolovitz, D. J.; Haataja, M. Tunable helical ribbons. Appl. Phys. Lett. 2011 , 98 , 011906..

Armon, S.; Efrati, E.; Kupferman, R.; Sharon, E. Geometry and mechanics in the opening of chiral seed pods. Science 2011 , 333 , 1726−1730..

Sawa, Y.; Ye, F. F.; Urayama, K.; Takigawa, T.; Gimenez-Pinto, V.; Selinger, R. L. B.; Selinger, J. V. Shape selection of twist-nematic-elastomer ribbons. Proc. Natl. Acad. Sci. USA 2011 , 108 , 6364−6368..

Yin, L.; Miao, T. F.; Cheng, X. X.; Jiang, Z. C.; Tong, X.; Zhang, W.; Zhao, Y. Chiral liquid crystalline elastomer for twisting motion without preset alignment of mesogens. ACS Macro Lett. 2021 , 10 , 690−696..

Zhang, C.; Fei, G. X.; Lu, X. L.; Xia, H. S.; Zhao, Y. Liquid crystal elastomer artificial tendrils with asymmetric core–sheath structure showing evolutionary biomimetic locomotion. Adv. Mater. 2024 , 36 , 2307210..

Kim, S. T.; Finkelmann, H. Cholesteric liquid single-crystal elastomers (LSCE) obtained by the anisotropic deswelling method. Macromol. Rapid Commun. 2001 , 22 , 429−433..

Kizhakidathazhath, R.; Geng, Y.; Jampani, V. S. R.; Charni, C.; Sharma, A.; Lagerwall, J. P. F. Facile anisotropic deswelling method for realizing large-area cholesteric liquid crystal elastomers with uniform structural color and broad-range mechanochromic response. Adv. Funct. Mater. 2020 , 30 , 1909537..

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