Phase Patterning of Poly(oxime-ester) for Information Encryption by Photo-induced Isomerization

Yu-Fan Yang; Yun Bai; Yi-Bao Li; Chang-Fei He

doi:10.1007/s10118-024-3183-8

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Phase Patterning of Poly(oxime-ester) for Information Encryption by Photo-induced Isomerization

RESEARCH ARTICLE | Updated：2024-09-23

- Phase Patterning of Poly(oxime-ester) for Information Encryption by Photo-induced Isomerization
- Chinese Journal of Polymer Science Vol. 42, Issue 10, Pages: 1488-1494(2024)
- Affiliations：
  
  School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China
- Author bio：
  
  liyibao@gnnu.edu.cn (Y.B.L.)
  hechangfei@gnnu.edu.cn (C.F.H.)
- Funds：
- DOI：10.1007/s10118-024-3183-8
  CLC： M
- Received：29 April 2024，
  
  Revised：2024-06-04，
  
  Accepted：05 June 2024，
  
  Online First：28 August 2024，
  
  Published：01 October 2024
- Accepted：
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Yang, Y. F.; Bai, Y.; Li, Y. B.; He, C. F. Phase patterning of poly(oxime-ester) for information encryption by photo-induced isomerization. Chinese J. Polym. Sci. 2024, 42, 1488–1494

Yu-Fan Yang, Yun Bai, Yi-Bao Li, et al. Phase Patterning of Poly(oxime-ester) for Information Encryption by Photo-induced Isomerization[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1488-1494.
Yang, Y. F.; Bai, Y.; Li, Y. B.; He, C. F. Phase patterning of poly(oxime-ester) for information encryption by photo-induced isomerization. Chinese J. Polym. Sci. 2024, 42, 1488–1494 DOI： 10.1007/s10118-024-3183-8.

Yu-Fan Yang, Yun Bai, Yi-Bao Li, et al. Phase Patterning of Poly(oxime-ester) for Information Encryption by Photo-induced Isomerization[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1488-1494. DOI： 10.1007/s10118-024-3183-8.

摘要

We introduce a straightforward method for fabricating information encryption materials based on a poly(oxime-ester) network with a programmable crystallization temperature induced by UV light. Thus complex patterns and information can be encrypted through different selective regional exposure time and decrypted under specific temperature or cooling time.

Abstract

Crystal polymers or liquid crystal elastomers undergo a phase transition that results in a change in the corresponding optical properties

which has the potential to be applied in areas such as information encryption and anti-counterfeiting. The utilization of these materials for patterning purposes requires different phase transition temperatures. However

once prepared

altering the phase transition temperature of them presents significant challenges. Herein

a poly(oxime-ester) (POE) network is developed to achieve high-resolution and multilevel patterning by photo-induced isomerization. The as-prepared POE exhibits the ability to transition from an opaque state to a transparent state under temperature stimuli

with the transition temperature and kinetics dependent on UV light exposure time. Thus

complex patterns and information can be encrypted through different selective regional exposure time and decrypted under specific temperature or cooling time. Furthermore

we illustrate an example of temporal communication

where cooling time or temperature serves as the encoded information. This research expands the application scope of advanced encryption materials

showcasing the potential of POE in dynamic information encryption and decryption processes.

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