3D Printed Polyimide/Silica Composite Aerogels for Customizable Thermal Insulation from −50 °C to 1300 °C

Dingyi Yu; Tiantian Xue; Zhuocheng Ma; Zaiyin Hu; Lijuan Long; Yue-E Miao; Wei Fan; Tianxi Liu

doi:10.1007/s10118-024-3130-8

Your Location：

Home >

Browse articles >

3D Printed Polyimide/Silica Composite Aerogels for Customizable Thermal Insulation from −50 °C to 1300 °C

RESEARCH ARTICLE | Updated：2024-06-26

- 3D Printed Polyimide/Silica Composite Aerogels for Customizable Thermal Insulation from −50 °C to 1300 °C
- Chinese Journal of Polymer Science Vol. 42, Issue 7, Pages: 936-945(2024)
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
  c.Guizhou Aerospace Wujiang Electro-Mechanical Equipment Co., Ltd., Zunyi 563000, China
  d.School of Materials and Architectural Engineering, Guizhou Normal University, Guiyang 550025, China
- Author bio：
  
  weifan@dhu.edu.cn or weifan@jiangnan.edu.cn
- Funds：
- DOI：10.1007/s10118-024-3130-8
  CLC：
- Received：12 January 2024，
  
  Revised：2024-03-24，
  
  Accepted：28 March 2024，
  
  Online First：17 May 2024，
  
  Published：01 July 2024
- Accepted：
Scan QR Code
Yu, D. Y.; Xue, T. T.; Ma, Z. C.; Hu, Z. Y.; Long, L. J.; Miao, Y. E.; Fan, W.; Liu, T. X. 3D printed polyimide/silica composite aerogels for customizable thermal insulation from −50 °C to 1300 °C. Chinese J. Polym. Sci. 2024, 42, 936–945

Dingyi Yu, Tiantian Xue, Zhuocheng Ma, et al. 3D Printed Polyimide/Silica Composite Aerogels for Customizable Thermal Insulation from −50 °C to 1300 °C[J]. Chinese Journal of Polymer Science, 2024, 42(7): 936-945.
Yu, D. Y.; Xue, T. T.; Ma, Z. C.; Hu, Z. Y.; Long, L. J.; Miao, Y. E.; Fan, W.; Liu, T. X. 3D printed polyimide/silica composite aerogels for customizable thermal insulation from −50 °C to 1300 °C. Chinese J. Polym. Sci. 2024, 42, 936–945 DOI： 10.1007/s10118-024-3130-8.

Dingyi Yu, Tiantian Xue, Zhuocheng Ma, et al. 3D Printed Polyimide/Silica Composite Aerogels for Customizable Thermal Insulation from −50 °C to 1300 °C[J]. Chinese Journal of Polymer Science, 2024, 42(7): 936-945. DOI： 10.1007/s10118-024-3130-8.

摘要

3D printed polyimide/silica composite aerogels exhibit excellent flame-retardant properties and thermal insulation from -50 to 1300 °C

promising to be used as customizable insulating materials in a variety of complex and extreme applications.

Abstract

Aerogels are widely used as thermal insulation materials because of their high porosity and low bulk density. However

the insulation performance of aerogels is limited to a narrow temperature range. Besides

the preparation of aerogel materials with precisely controlled and complex architectures is still challenging. Here

we report 3D printed polyimide/silica aerogel particle (PI/SAP) composite aerogels for thermal insulation in a wide range of temperature with customized applications. The printability and shape fidelity of 3D printed composite aerogels is improved by adding hydrophilic SAP as a rheology modifier. The resulting PI/SAP composite aerogel exhibits excellent flame-retardant properties and thermal insulation from −50 °C to 1300 °C. Moreover

the PI/SAP composite aerogel with customized shape can be applied for battery insulation at subzero temperatures

promising to be used as customizable and stable insulating materials in a variety of complex and extreme applications.

关键词

Keywords

references

An, L.; Armstrong, J. N.; Hu, Y.; Huang, Y. L.; Li, Z.; Zhao, D. H.; Sokolow, J.; Guo, Z. P.; Zhou, C.; Ren, S. Q. High temperature ceramic thermal insulation material. Nano Res. 2022 , 15 , 6662−6669..

Wang, Y. T.; Chu, C. Y.; Duan, C. Q.; Dong, J. J.; Chen, H.; Ying, S.; Guo, J.; Xu, G.; Hu, F.; Cheng, Y. Thermal insulation of 3D printed complex and miniaturized SiO 2 aerogels at medium-high temperatures. J. Non. Cryst. Solids. 2023 , 608 , 122251..

Wu, K. D.; Zhou, Q.; Cao, J. X.; Qian, Z.; Niu, B.; Long, D. H. Ultrahigh-strength carbon aerogels for high temperature thermal insulation. J. Colloid Interface Sci 2021 , 609 , 667−675..

Tian, J.; Yang, Y.; Xue, T. T.; Chao, G. J.; Fan, W.; Liu, T. X. Highly flexible and compressible polyimide/silica aerogels with integrated double network for thermal insulation and fire-retardancy. J. Mater. Sci. Technol. 2021 , 105 , 194−220..

Jadhav, P. S.; Sarkar, A.; Pasupathy, S.; Ren, S. Q. Biogenic straw aerogel thermal insulation materials. Adv. Eng. Mater. 2023 , 25 , 2300037..

Zhang, C. J.; Song, S. C.; Liu, Q.; Li, J. H.; Cao, Q.; Zhang, S. H.; Jian, X. G.; Weng, Z. H. Fabrication of cross-linked polysulfone aerogels for thermal insulation. Mater. Lett. 2023 , 351 , 135000..

Zou, F. X.; Budtova, T. Polysaccharide-based aerogels for thermal insulation and superinsulation: an overview. Carbohydr. Polym. 2021 , 266 , 118130..

Coquard, R.; Baillis, D.; Quenard, D. Numerical and experimental study of the IR opacification of polystyrene foams for thermal insulation enhancement. Energy Build. 2018 , 183 , 54−63..

Ge, C. B.; Zhai, W. T. Cellular thermoplastic polyurethane thin film: preparation, elasticity, and thermal insulation performance. Ind. Eng. Chem. Res. 2018 , 57 , 4688−4696..

Sair, S.; Mandili, B.; Taqi, M.; Bouari, A. E. Development of a new eco-friendly composite material based on gypsum reinforced with a mixture of cork fibre and cardboard waste for building thermal insulation. Compos. Commun. 2019 , 16 , 20−24..

Li, M. M.; Chen, X.; Li, X. T.; Dong, J.; Teng, C. Q.; Zhao, X.; Zhang, Q. H. Ultralight aerogel textiles based on aramid nanofibers composites with excellent thermal insulation and electromagnetic shielding properties. Compos. Commun. 2022 , 35 , 101346..

Wu, Z. H.; Feng, X. L.; Qu, Y. X.; Gong, L. X.; Cao, K.; Zhang, G. D.; Shi, Y. Q.; Gao, J. F.; Song, P. G.; Tang, L. C. Silane modified MXene/polybenzazole nanocomposite aerogels with exceptional surface hydrophobicity, flame retardance and thermal insulation. Compos. Commun. 2023 , 37 , 101402..

Baetens, R.; Jelle, B. P.; Gustavsen, A. Aerogel insulation for building applications: a state-of-the-art review. Energy Build. 2010 , 43 , 761−769..

Fan, W.; Zhang, X.; Zhang, Y.; Zhang, Y. F.; Liu, T. X. Lightweight, strong, and super-thermal insulating polyimide composite aerogels under high temperature. Compos. Sci. Technol 2019 , 173 , 47−52..

Xu, G. F.; Li, M. J.; Wu, T. T.; Teng, C. Q. Highly compressible and anisotropic polyimide aerogels containing aramid nanofibers. React. Funct. Polym. 2020 , 154 , 104672..

Zhao, S. Y.; Siqueira, G.; Drdova, S.; Norris, D.; Ubert, C.; Bonnin, A.; Sandra Galmarini, S. Additive manufacturing of silica aerogels. Nature 2020 , 584 , 387−392..

Li, C. D.; Zhang, G. H.; Lin, L. L.; Wu, T. T.; Brunner, S.; Galmarini, S.; Bi, J. T.;J. Malfait, W.; Zhao, S. Y.; Ostrikov, K. Silica aerogels: from materials research to industrial applications. Int. Mater. Rev. 2023 , 68 , 862−900..

Liu, Z. H.; Ding, Y. D.; Wang, F.; Deng, Z. P. Thermal insulation material based on SiO 2 aerogel. Constr. Build Mater. 2016 , 122 , 547−554..

Guo, B. F.; Wang, Y. J.; Qu, Z. H.; Yang, F.; Qin, Y. Q.; Li, Y.; Zhang, G. D.; Gao, J. F.; Shi, Y. Q.; Song, P. G.; Tang. L. C. Hydrosilylation adducts to produce wide-temperature flexible polysiloxane aerogel under ambient temperature and pressure drying. Small 2023 , 20 , 2309272..

Zhang, Z. H.; Chen, Z. Y.; Tang, Y. H.; Li, Y. T.; Zhang, G. D.; Cao, C. F.; Gong, L. X.; Tang, L. C. Silicone/graphene oxide co-cross-linked aerogels with wide-temperature mechanical flexibility, super-hydrophobicity and flame resistance for exceptional thermal insulation and oil/water separation. J. Mater. Sci. Technol. 2022 , 114 , 131−142..

Zhang, X.; Zhao, X. Y.; Xue, T. T.; Yang, F.; Fan, W.; Liu, T. X. Bidirectional anisotropic polyimide/bacterial cellulose aerogels by freeze-drying for super-thermal insulation. Chem. Eng. J. 2019 , 385 , 123963..

Fraleoni-Morgera, A.; Chhikara, M. Polymer-based nano-composites for thermal insulation. Adv. Eng. Mater. 2019 , 21 , 1801162..

Zhao, W.; Zhu, J.; Liu, L. W.; Leng, J. S.; Liu, Y. J. A bio-inspired 3D metamaterials with chirality and anti-chirality topology fabricated by 4D printing. Int. J. Smart Nano Mater. 2023 , 14 , 1−20..

Jiang, Y. Q.; Xu, Z.; Huang, T. Q.; Liu, Y. J.; Guo, F.; Xi, J. B.; Gao, W. W.; Gao, C. Direct 3D printing of ultralight graphene oxide aerogel microlattices. Adv. Funct. Mater. 2018 , 28 , 1707024..

Joo, P.; Yao, Y.; Teo, N.; Jana, S. C. Modular aerogel brick fabrication via 3D-printed molds. Addit. Manuf. 2021 , 46 , 102069..

Zhang, Q. Q.; Zhang, F.; Medarametla, S. P.; Li, H.; Zhou, C.; Lin, D. 3D printing of graphene aerogels. Small 2016 , 12 , 1702−1708..

Cheng, Q. Q.; Sheng, Z. Z.; Wang, Y. F.; Lyu, J.; Zhang, X. T. General suspended printing strategy toward programmatically spatial Kevlar aerogels. ACS Nano 2022 , 16 , 4905−4916..

Chen, N.; Luo, F. Y.; Yang, G. W.; Yao, J. R.; Chen, X.; Shao, Z. Z. Production of functional materials derived from regenerated silk fibroin by utilizing 3D printing and biomimetic enzyme-induced mineralization. Chinese J. Polym. Sci. 2023 , 42 , 299−310..

Ching, T.; Li, Y. Y.; Karyappa, R.; Ohno, A.; Toh, Y. C.; Hashimoto, M. Fabrication of integrated microfluidic devices by direct ink writing (DIW) 3D printing. Sens. Actuators B Chem. 2019 , 297 , 126609..

Guan, R. H.; Zheng, H. Y.; Liu, Q. X.; Ou, K. T.; Li, D. S.; Fan, J.; Fu, Q.; Sun, Y. Y. DIW 3D printing of hybrid magnetorheological materials for application in soft robotic grippers. Compos. Sci. Technol. 2022 , 223 , 109409..

Yang, G. Y.; Sun, Y. Y.; Qin, L. M.; Li, M. R.; Ou, K. T.; Fang, J.; Fu, Q. Direct-ink-writing (DIW) 3D printing functional composite materials based on supra-molecular interaction. Compos. Sci. Technol. 2021 , 215 , 109013..

Yang, G. Y.; Guan, R. H.; Zhen, H. Y.; Ou, K. T.; Fang, J.; Li, D. S.; Fu, Q.; Sun, Y. Y. Tunable size of hierarchically porous alumina ceramics based on DIW 3D printing supramolecular gel. ACS Appl. Mater. Interfaces 2022 , 14 , 10998−11005..

Feng, C. A.; Yu, S. S. 3D printing of thermal insulating polyimide/cellulose nanocrystal composite aerogels with low dimensional shrinkage. Polymers 2021 , 13 , 3614..

Ma, Z. C.; Xue, T. T.; Wali, Q.; Miao, Y. E.; Fan, W.; Liu, T. X. Direct ink writing of polyimide/bacterial cellulose composite aerogel for thermal insulation. Compos. Commun. 2023 , 39 , 101528..

Wu, T. T.; Ganobjak, M.; Siqueira, G.; Zeng, Z. H.; Li, M. M.; Filimonova, E.; Saghamanesh, S.; Bonnin, A.; Sivaraman, D.; Yip, J.; Li, L.; Wu, H.; Nyström, G.; Malfalt, W. J.; Zhao, S. 3D printed polyimide nanocomposite aerogels for electromagnetic interference shielding and thermal management. Adv. Mater. Technol . 2023 , 8 , 2202155..

Xue, T. T.; Yang, Y.; Yu, D. Y.; Wali, Q.; Wang, Z. Y.; Cao, X. S.; Fan, W.; Liu, T. X. 3D printed integrated gradient-conductive MXene/CNT/polyimide aerogel frames for electromagnetic interference shielding with ultra-low reflection. Nano-Micro Lett 2023 , 15 , 45..

Yang, Y.; Fan, W.; Yuan, S. J.; Tian, J.; Chao, G. J.; Liu, T. X. A 3D-printed integrated MXene-based evaporator with a vertical array structure for salt-resistant solar desalination. J. Mater. Chem. A 2021 , 9 , 23968−23976..

Zhang, T. T.; Zhou, M. X.; Guo, Z. Y.; Zhao, Y. B.; Han, D.; Xiu, H.; Bai, H. W.; Zhang, Q.; Fu, Q. Improving impact toughness of polylactide/ethylene- co -vinyl-acetate blends via adding fumed silica nanoparticles: effects of specific surface area-dependent interfacial selective distribution of silica. Chinese J. Polym. Sci. 2021 , 39 , 1040−1049..

Chen, Q. F.; Wang, H.; Sun, L. Y. Preparation and characterization of silica aerogel microspheres. Materials 2017 , 10 , 435..

Peng, T. P.; Zhu, J. D.; Huang, T.; Jiang, C. W.; Zhao, F. X.; Ge, S. Z.; Xie, L. Facile preparation for gelatin/hydroxyethyl cellulose-SiO 2 composite aerogel with good mechanical strength, heat insulation, and water resistance. J. Appl. Polym. Sci. 2021 , 138 , e50539..

Babiarczuk, B.; Lewandowski, D.; Szczurek, A.; Kierzek, K.; Meffert, M.; Gerthsen, D.; Kaleta, J.; Krzak, J. Novel approach of silica-PVA hybrid aerogel synthesis by simultaneous sol-gel process and phase separation. J. Supercrit. Fluids 2020 , 166 , 104997..

Wang, F.; Yang, Z. J.; Hu, X. Z.; Pan, Y.; Lu, Y.; Jiang, M. Coaxial 3D printed anisotropic thermal conductive composite aerogel with aligned hierarchical porous carbon nanotubes and cellulose nanofibers. Smart Mater. Struct. 2022 , 31 , 045002..

Liu, C. H.; Li, M. C.; Liu, X. Y.; Zhou, G. Q.; Liu, C. Z.; Mei, C. T. 3D printing of customized lignocellulose nanofibr il aerogels for efficient thermal insulation. Addit. Manuf . 2023 , 78 , 103841..

Maleki, H.; Montes, S.; Hayati-Roodbari, N.; Putz, F.; Huesing, N. Compressible, thermally insulating, and fire retardant aerogels through self-assembling silk fibroin biopolymers inside a silica structure—an approach towards 3D printing of aerogels. ACS Appl. Mater. Interfaces 2018 , 10 , 22718..

Wang, Y. J.; Cui, Y.; Shao, Z. Y.; Gao, W. W.; Fan, W.; Liu, T. X.; Bai, H. Multifunctional polyimide aerogel textile inspired by polar bear hair for thermoregulation in extreme environments. Chem. Eng. J. 2020 , 390 , 124623..

Views

2697

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Fabrication of Polytetrafluoroethylene Aerogels with Excellent Sound Absorption and Thermal Insulation

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

3D Printing of Strong, Tough, Multifunctional and Sustainable Material from Dynamic Imidazole-urea-epoxy Chemistry

Activated Carbon-derived Polyester Elastomer Foams with Tailored Structure and Blackness for High-performance Thermally Insulating Applications

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Related Author

Cong-Cong Li

You-Lei Tu

Shao-Yun Guo

Jia-Bin Shen

Qiao-Ran Zhang

Xin-Fei Wang

Ya-Nan Chen

Bo-Yuan Zhou

Related Institution

State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), Sichuan Provincial Engineering Laboratory of Plastic/Rubber Complex Processing Technology

Department of Mechanics, College of Architecture & Environment, Sichuan University

School of Chemistry and Chemical Engineering, Henan University of Technology

Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences

Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University

⁰