Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO<sub>2</sub>

Sergey A. Lermontov; Aleksey V. Maksimkin; Nataliya A. Sipyagina; Tarek Dayyoub; Alena N. Malkova; Evgeniy A. Kolesnikov; Elena A. Straumal; Inna O. Gozhikova; Saidkhodzha G. Nematulloev; Dmitry V. Telyshev

doi:10.1007/s10118-023-3036-x

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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂

RESEARCH ARTICLE | Updated：2023-12-26

- Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂
- Chinese Journal of Polymer Science Vol. 42, Issue 1, Pages: 97-104(2024)
- Affiliations：
  
  a.Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka 142432, Russia
  b.Institute for Bionic Technologies and Engineering, I.M. Sechenov First Moscow State Medical University (Sechenov University), Moscow 119991, Russia
  c.National University of Science and Technology "MISIS", Moscow 119049, Russia
  d.Institute of Biomedical Systems, National Research University of Electronic Technology, Zelenograd, Moscow 124498, Russia
- Author bio：
  
  lermontov52@yandex.ru (S.A.L.)
  tarekzd@windowslive.com (T.D.)
- Funds：
- DOI：10.1007/s10118-023-3036-x
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Lermontov, S. A.; Maksimkin, A. V.; Sipyagina, N. A.; Dayyoub, T.; Malkova, A. N.; Kolesnikov, E. A.; Straumal, E. A.; Gozhikova, I. O.; Nematulloev, S. G.; Telyshev, D. V. Porous shish-kebab structure prepared from oriented UHMWPE films by processing in supercritical CO₂. Chinese J. Polym. Sci. 2024, 42, 97–104

Sergey A. Lermontov, Aleksey V. Maksimkin, Nataliya A. Sipyagina, et al. Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂. [J]. Chinese Journal of Polymer Science 42(1):97-104(2024)
Lermontov, S. A.; Maksimkin, A. V.; Sipyagina, N. A.; Dayyoub, T.; Malkova, A. N.; Kolesnikov, E. A.; Straumal, E. A.; Gozhikova, I. O.; Nematulloev, S. G.; Telyshev, D. V. Porous shish-kebab structure prepared from oriented UHMWPE films by processing in supercritical CO₂. Chinese J. Polym. Sci. 2024, 42, 97–104 DOI： 10.1007/s10118-023-3036-x.

Sergey A. Lermontov, Aleksey V. Maksimkin, Nataliya A. Sipyagina, et al. Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂. [J]. Chinese Journal of Polymer Science 42(1):97-104(2024) DOI： 10.1007/s10118-023-3036-x.

摘要

A highly crystalline porous "shish-kebab" structure with a high degree of crystallinity can be prepared by the treatment of the oriented UHMWPE films using supercritical carbon dioxide (scCO2). The particularity of the prepared porous shish-kebab is the absence of the amorphous phase between kebab crystals. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO2 gives the possibility to control the size of both lamellar disks and pores formed.

Abstract

For the first time, a highly crystalline porous shish-kebab structure with a high degree of crystallinity was obtained by using a combination of two methods for the formation of porous polymeric materials. A treatment procedure using supercritical carbon dioxide (scCO,2,) was carried out for oriented ultrahigh molecular weight polyethylene (UHMWPE) films, which provided special conditions for the crystallization of dissolved UHMWPE macromolecules on the surface of oriented UHMWPE crystals. The prepared porous materials were investigated by scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The particularity of the obtained porous shish-kebab is the absence of the amorphous phase between lamellar crystals (kebabs). The obtained pores had an oval shape, and they were oriented in the orientation direction of the UHMWPE macromolecules. The pore size ranged from 0.05 μm to 4 μm. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO,2, gives the possibility to control the size of both lamellar disks and pores formed.

关键词

Keywords

UHMWPESupercritical CO2Porous shish-kebab structure

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Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119992, Russian Federation

. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, Moscow 119991, Russian Federation

Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Profsoyuznaya Str., 70, Moscow 117393, Russian Federation

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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO2

DOI：10.1007/s10118-023-3036-x

摘要

Abstract

关键词

Keywords

references

Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO₂