Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers <italic style="font-style: italic">via</italic> Successive Flow START Polymerization and Cu(0)-Mediated RDRP

Peng Wang; Shuai-Jie Chen; Jian-Nan Cheng; Wei-Wei He; Li-Fen Zhang; Zhen-Ping Cheng

doi:10.1007/s10118-023-3003-6

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Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers via Successive Flow START Polymerization and Cu(0)-Mediated RDRP

RAPID COMMUNICATION | Updated：2023-07-18

- Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers via Successive Flow START Polymerization and Cu(0)-Mediated RDRP
- Chinese Journal of Polymer Science Vol. 41, Issue 8, Pages: 1155-1161(2023)
- Affiliations：
  
  a.State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials; Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application; Suzhou key Laboratory of Macromolecular Design and Precision Synthesis; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
  b.State Key Laboratory of Radiation Medicine and Protection, School of Radiological and Interdisciplinary Sciences (RADX), Soochow University, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, Suzhou 215123, China
- Author bio：
  
  wwhe@suda.edu.cn (W.W.H.)
  zhanglifen@suda.edu.cn (L.F.Z.)
  chengzhenping@suda.edu.cn (Z.P.C.)
- Funds：
- DOI：10.1007/s10118-023-3003-6
  CLC：
- Received：22 April 2023，
  
  Revised：2023-5-14，
  
  Accepted：16 May 2023，
  
  Online First：12 June 2023，
  
  Published：01 August 2023
- Accepted：
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Wang, P.; Chen, S. J.; Cheng, J. N.; He, W. W.; Zhang, L. F.; Cheng, Z. P. Continuous synthesis of main-chain-type fluorinated graft copolymers via successive flow START polymerization and Cu(0)-mediated RDRP. Chinese J. Polym. Sci. 2023, 41, 1155–1161

Peng Wang, Shuai-Jie Chen, Jian-Nan Cheng, et al. Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers via Successive Flow START Polymerization and Cu(0)-Mediated RDRP[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1155-1161. DOI: 10.1007/s10118-023-3003-6.
Wang, P.; Chen, S. J.; Cheng, J. N.; He, W. W.; Zhang, L. F.; Cheng, Z. P. Continuous synthesis of main-chain-type fluorinated graft copolymers via successive flow START polymerization and Cu(0)-mediated RDRP. Chinese J. Polym. Sci. 2023, 41, 1155–1161 DOI： 10.1007/s10118-023-3003-6.

Peng Wang, Shuai-Jie Chen, Jian-Nan Cheng, et al. Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers via Successive Flow START Polymerization and Cu(0)-Mediated RDRP[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1155-1161. DOI: 10.1007/s10118-023-3003-6. DOI：

摘要

Abstract

Fluorinated polymers are receiving more and more attention worldwide due to their unique chemical properties

and modified fluorinated polymers with different topologies are persued for enriching and enhancing their performance in a variety of application fields. In this work

main-chain-type semifluorinated graft copolymers are produced steadily in continuous tube reactors

via

photocontrolled step transfer-addition and radical-termination (START) polymerization and Cu(0)-mediated reversible deactivation radical polymerization (Cu(0)-RDRP) at room temperature for the first time. Specifically

semifluorinated alternating copolymer (AB)

B is prepared by START polymerization of 1

6-diiodoperfluorohexane (A) and 1

7-octadiene (B) in the first quartz pipeline under irradiation with purple LED light at 20 °C. The (AB)

B with periodic C―I bonds is then flowed into the second copper pipeline directly and acts as the macroinitiators for Cu(0)-RDRP of methyl acrylate (MA) to obtain corresponding graft copolymer (AB)

B-

-PMA. This work provides a new strategy for continuous synthesis of fluorinated graft copolymer materials.

关键词

Keywords

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Continuous Synthesis of Main-Chain-type Fluorinated Graft Copolymers via Successive Flow START Polymerization and Cu(0)-Mediated RDRP

DOI：10.1007/s10118-023-3003-6

摘要

Abstract

关键词

Keywords

references