Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery

Yan-Kun Xie; Lu-Kun Feng; Dong-Dong Li; Yin Tang; Cai-Zhen Zhu; Ming-Liang Wang; Jian Xu

doi:10.1007/s10118-023-2970-y

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Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery

RESEARCH ARTICLE | Updated：2023-11-10

- Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery
- Chinese Journal of Polymer Science Vol. 41, Issue 11, Pages: 1695-1705(2023)
- Affiliations：
  
  Institute of Low-Dimensional Materials Genome Initiative, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China
- Author bio：
  
  czzhu@szu.edu.cn (C.Z.Z.)
  wangml@szu.edu.cn (M.L.W.)
  jxu@iccas.ac.cn (J.X.)
- Funds：
- DOI：10.1007/s10118-023-2970-y
  CLC：
- Received：14 December 2022，
  
  Revised：2023-2-18，
  
  Accepted：20 February 2023，
  
  Online First：18 April 2023，
  
  Published：01 November 2023
- Accepted：
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Xie, Y. K.; Feng, L. K.; Li, D. D.; Tang, Y.; Zhu, C. Z.; Wang, M. L.; Xu, J. Novel quasi solid-state succinonitrile-based electrolyte with low-flammability for lithium-ion battery. Chinese J. Polym. Sci. 2023, 41, 1695–1705

Yan-Kun Xie, Lu-Kun Feng, Dong-Dong Li, et al. Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1695-1705.
Xie, Y. K.; Feng, L. K.; Li, D. D.; Tang, Y.; Zhu, C. Z.; Wang, M. L.; Xu, J. Novel quasi solid-state succinonitrile-based electrolyte with low-flammability for lithium-ion battery. Chinese J. Polym. Sci. 2023, 41, 1695–1705 DOI： 10.1007/s10118-023-2970-y.

Yan-Kun Xie, Lu-Kun Feng, Dong-Dong Li, et al. Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1695-1705. DOI： 10.1007/s10118-023-2970-y.

摘要

The SN-based electrolyte with low-flammability has been successfully through in-situ polymerization method. The as-prepared SN-based electrolyte exhibited good electrochemical performance and low-flammability.

Abstract

Quasi solid-state succinonitrile (SN)-based polymer electrolytes have emerged for lithium-metal batteries due to their excellent ion-conductivity at room temperature

wide electrochemical stability window (ESW

usually

5 V). However

the practical application of these solid SN-based polymer electrolytes is hampered by the flammability and the inherent instability of SN to Li-metal anode. In this work

solid SN-based polymer electrolytes were prepared with succinonitrile

ethoxylated trimethylolpropane triacrylate (ETPTA)

triethyl phosphate (TEP) and fluoroethylene carbonate for Li-metal battery

via

in situ

polymerization method. The SN-based polymer electrolytes with 5 wt% triethyl phosphate and FEC showed good nonflammability

superior ion-conductivity as high as 1.01×10

−3

S/cm

and wide ESW of 5.41 V. This SN-based polymer electrolyte also exhibited excellent interfacial compatibility to lithium metal anode. And it also delivered a high specific capacity of 156 mAh/g at 0.2 C at ambient temperature

and presented stable cycling at 1.0 C with a specific capacity retention of 98.4% after 1000 cycles. This work provides an alternative and simple strategy to realize the practical application of the solid-state SN-based polymer electrolyte.

关键词

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references

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