Mechanical Strong, Highly Adhesive, Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding

Yu-Cai Lin; Feng Chen; Shou-Bin Yang; Shu-Yue Gong; Yu-Xiang Luo; Fang-Fang Wei; Fu-Chuan Ding; Wei-Bin Bai; Rong-Kun Jian

doi:10.1007/s10118-023-2966-7

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Mechanical Strong, Highly Adhesive, Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding

RESEARCH ARTICLE | Updated：2023-11-10

- Mechanical Strong, Highly Adhesive, Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding
- Chinese Journal of Polymer Science Vol. 41, Issue 11, Pages: 1796-1804(2023)
- Affiliations：
  
  Fujian Key Laboratory of Polymer Materials, Fujian Provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
- Author bio：
  
  yucailin@fjnu.edu.cn (Y.C.L.)
  jrkht1987@fjnu.edu.cn (R.K.J.)
- Funds：
- DOI：10.1007/s10118-023-2966-7
  CLC：
- Received：21 December 2022，
  
  Revised：2023-1-30，
  
  Accepted：09 February 2023，
  
  Online First：17 March 2023，
  
  Published：01 November 2023
- Accepted：
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Lin, Y. C.; Chen, F.; Yang, S. B.; Gong, S. Y.; Luo, Y. X.; Wei, F. F.; Ding, F. C.; Bai, W. B.; Jian, R. K. Mechanical strong, highly adhesive, recyclable and transparent supramolecular silicone coatings with easy water/oil sliding. Chinese J. Polym. Sci. 2023, 41, 1796–1804

Yu-Cai Lin, Feng Chen, Shou-Bin Yang, et al. Mechanical Strong, Highly Adhesive, Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1796-1804.
Lin, Y. C.; Chen, F.; Yang, S. B.; Gong, S. Y.; Luo, Y. X.; Wei, F. F.; Ding, F. C.; Bai, W. B.; Jian, R. K. Mechanical strong, highly adhesive, recyclable and transparent supramolecular silicone coatings with easy water/oil sliding. Chinese J. Polym. Sci. 2023, 41, 1796–1804 DOI： 10.1007/s10118-023-2966-7.

Yu-Cai Lin, Feng Chen, Shou-Bin Yang, et al. Mechanical Strong, Highly Adhesive, Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1796-1804. DOI： 10.1007/s10118-023-2966-7.

摘要

Novel supramolecular silicone poly(urea-urethane) (SSPu) coatings with excellent mechanical performance

strong interfacial adhesion and multiple time recycling capability are developed by incorporating noncovalent bonds (2-amino-4-hydroxy-6-methylpyrimidine (UPy) quadruple hydrogen bonds) into the side chain of silicone backbone.

Abstract

Traditional silicone materials have poor mechanical properties

poor interfacial adhesion and lack the ability to be reprocessed or recycled. Herein

we developed a novel strategy of incorporating dynamic noncovalent bonds (2-amino-4-hydroxy-6-methylpyrimidine (UPy)) into side chain of silicone backbones to construct supramolecular silicone poly(urea-urethane) (SSPu) coatings with excellent mechanical performance

strong interfacial adhesion and multiple time recycling capability. Impressively

the prepared SSPu is endowed with simultaneously enhanced stiffness (272.0±23.2 MPa) and toughness (8.0±2.0 MJ·m

−3

). Besides

SSPu shows strong interfacial adhesion (up to 9.0±1.3 MPa) to diverse substrate (stainless steel

aluminum

copper

epoxy and glass) with long term stability. Moreover

SSPu exhibits excellent multi-recyclability and reusability without significantly decrease of its performance. In addition to the abovementioned features

the enrichment of siloxane backbones in the surface layer endows SSPu with robust repellency to water/oil. Our strategy provides a powerful route to fabricate a new multifunctional silicone elastomer. It is highly anticipated that our strategy can effectively extend the service life of silicone coating which can be applied in a wide variety of areas including self-cleaning

antifouling.

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