Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application

Hao Chen; Fang-Yuan Chu; Hai-Yan Zhuang; Lu Wang; Zhi-Min Ye; Wei Dong; Zhi-Peng Xie; A-Ming Xie

doi:10.1007/s10118-023-2962-y

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Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application

RESEARCH ARTICLE | Updated：2023-07-18

- Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application
- Chinese Journal of Polymer Science Vol. 41, Issue 8, Pages: 1305-1316(2023)
- Affiliations：
  
  a.School of Mechanical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
  b.State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute (LSMRI), Xiamen 361100, China
  c.School of Chemistry and Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
- Author bio：
  
  zhipengxie1982@163.com (Z.P.X.)
  xieaming@njust.edu.cn (A.M.X.)
- Funds：
- DOI：10.1007/s10118-023-2962-y
  CLC：
- Received：20 December 2022，
  
  Revised：2023-2-26，
  
  Accepted：27 February 2023，
  
  Online First：18 April 2023，
  
  Published：01 August 2023
- Accepted：
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Chen, H.; Chu, F. Y.; Zhuang, H. Y.; Wang, L.; Ye, Z. M.; Dong, W.; Xie, Z. P.; Xie, A. M. Hyper-crosslinked conjugated microporous polymers with increased micropores promotes confining polymerization for electromagnetic absorption application. Chinese J. Polym. Sci. 2023, 41, 1305–1316

Hao Chen, Fang-Yuan Chu, Hai-Yan Zhuang, et al. Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1305-1316.
Chen, H.; Chu, F. Y.; Zhuang, H. Y.; Wang, L.; Ye, Z. M.; Dong, W.; Xie, Z. P.; Xie, A. M. Hyper-crosslinked conjugated microporous polymers with increased micropores promotes confining polymerization for electromagnetic absorption application. Chinese J. Polym. Sci. 2023, 41, 1305–1316 DOI： 10.1007/s10118-023-2962-y.

Hao Chen, Fang-Yuan Chu, Hai-Yan Zhuang, et al. Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1305-1316. DOI： 10.1007/s10118-023-2962-y.

摘要

Abstract

Conjugated microporous polymers have excellent skeleton structures but poor electrical conductivity limits their applications in microwave absorption. To solve this problem

a strategy of molecular expansion and confining polymerization is proposed in this work to synthesize conductive hyper-crosslinked conjugated microporous polymer. The topology of the conjugated microporous polymer is changed into a three-dimensional skeleton structure with high specific surface area by using molecular expansion technique

and the controlled growth of polypyrrole in the channel constructs a unique network structure. The balance of excellent composite backbone structure

proper conductivity

attenuation capability and impedance matching enable the material to exhibit electromagnetic wave absorption performance. As a result

with low filler loading of 10 wt%

a strongest reflection loss of −52.68 dB and a maximum effective bandwidth of 5.76 GHz. Additionally

CST simulations of the radar scattering cross section have been carried out to verify the excellent material properties. This study provides new concepts for new conductive polymers and broadens the application of hyper-crosslinked conjugated microporous polymer in the field of electromagnetic wave absorption.

关键词

Keywords

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