Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane

He-Cheng Wu; Shu-Ren Shao; Shuo-Hong Dong; Ao Wang; Zhen Li; Xiang-Long Han; Feng Luo; Jie-Hua Li; Dai-Guo Zhao; Wan-Ling Lan; Hong Tan

doi:10.1007/s10118-023-2957-8

Your Location：

Home >

Browse articles >

Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane

RESEARCH ARTICLE | Updated：2023-07-18

- Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane
- Chinese Journal of Polymer Science Vol. 41, Issue 8, Pages: 1230-1237(2023)
- Affiliations：
  
  a.College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Med-X Center for Materials, Sichuan University, Chengdu 610065, China
  b.State Key Laboratory of Oral Diseases, National Clinical Research Center for Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610041, China
  c.Sichuan Institute for Food and Drug Control, Chengdu 611731, China
- Author bio：
  
  zhenli@scu.edu.cn (Z.L.)
  hongtan@scu.edu.cn (H.T.)
- Funds：
- DOI：10.1007/s10118-023-2957-8
  CLC： M
- Received：28 November 2022，
  
  Revised：2023-1-22，
  
  Accepted：31 January 2023，
  
  Online First：10 March 2023，
  
  Published：01 August 2023
- Accepted：
Scan QR Code
Wu, H. C.; Shao, S. R.; Dong, S. H.; Wang, A.; Li, Z.; Han, X. L.; Luo, F.; Li, J. H.; Zhao, D. G.; Lan, W. L.; Tan, H. Influence of hydrogen bonding on the temperature-accelerated hydrolysis of silicone based polyetherurethane. Chinese J. Polym. Sci. 2023, 41, 1230–1237

He-Cheng Wu, Shu-Ren Shao, Shuo-Hong Dong, et al. Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1230-1237.
Wu, H. C.; Shao, S. R.; Dong, S. H.; Wang, A.; Li, Z.; Han, X. L.; Luo, F.; Li, J. H.; Zhao, D. G.; Lan, W. L.; Tan, H. Influence of hydrogen bonding on the temperature-accelerated hydrolysis of silicone based polyetherurethane. Chinese J. Polym. Sci. 2023, 41, 1230–1237 DOI： 10.1007/s10118-023-2957-8.

He-Cheng Wu, Shu-Ren Shao, Shuo-Hong Dong, et al. Influence of Hydrogen Bonding on the Temperature-Accelerated Hydrolysis of Silicone Based Polyetherurethane[J]. Chinese Journal of Polymer Science, 2023, 41(8): 1230-1237. DOI： 10.1007/s10118-023-2957-8.

摘要

Abstract

Temperature-accelerated

in vitro

degradation was established to estimate the longevity of polyurethane applied for long-term implantation. However

the prediction did not correlate well with the data from clinical explants and the rationality of accelerated

in vitro

test is still in a controversial due to the deviation. To improve the accuracy of the

in vitro

prediction

the influence of hydrogen bonding (HB) on the accelerated hydrolysis of silicone based polyetherurethans (SPEUs) extended with three side chains. Combining the temperature-controlled FTIR and the physical properties after temperature-accelerated

in vitro

degradation

it was demonstrated that side chain could increase the degree of hydrogen bond dissociation at higher temperature

resulting in the decrease of the calculated activation energy (

) of hydrolysis. At low temperatures

changes in surface morphology and molar mass of PEUs are minimal and HB are less easily dissociated

which had barely impact on the hydrolysis resistance. It was proposed that the

will not be impacted and that the accuracy of prediction will be increased if the acceleration temperature is lower than 70 °C and HB change is less than 15%.

关键词

Keywords

references

Tian,C.X.;Zhang,T.;Song,Y.Q.;Ming,H.;Liu,P.Q.;Jiang,M.J.;Luo,F.;Li,J.H.;Tan,H.;Fu,Q.Elaboratingpolyurethanepillowysoftmatonpolypropylenemonofilamentsurfacewithstepwisesurfacetreatments. Chinese J. Polym. Sci. 2022 , 40 ,1389−1401..

Dandeniyage,L.S.;Adhikari,R.;Bown,M.;Shanks,R.;Adhikari,B.;Easton,C.D.;Gengenbach,T.R.;Cookson,D.;Gunatillake,P.A.Morphologyandsurfacepropertiesofhighstrengthsiloxanepoly(urethane-urea)sdevelopedforheartvalveapplication. J. Biomed. Mater. Res. B 2019 , 107 ,112−121..

Stokes,K.;Cobian,K.Polyetherpolyurethanesforimplantablepacemakerleads. Biomaterials 1982 , 3 ,225−231..

Chaffin,K.A.Longevityexpectationsforpolymersinmedicaldevicesdemandnewapproachestoevaluatingtheirbiostability. ACS Macro. Lett. 2020 , 9 ,1793−1798..

Padsalgikar,A.;Cosgriff-Hernandez,E.;Gallagher,G.;Touchet,T.;Iacob,C.;Mellin,L.;Norlin-Weissenrieder,A.;Runt,J.Limitationsofpredictinginvivobiostabilityofmultiphasepolyurethaneelastomersusingtemperature-accelerateddegradationtesting. J. Biomed. Mater. Res. B 2015 , 103 ,159−168..

Chaffin,K.A.;Buckalew,A.J.;Schley,J.L.;Chen,X.;Jolly,M.;Alkatout,J.A.;Miller,J.P.;Untereker,D.F.;Hillmyer,M.A.;Bates,F.S.InfluenceofwateronthestructureandpropertiesofPDMS-containingmultiblockpolyurethanes. Macromolecules 2012 , 45 ,9110−9120..

Chaffin,K.A.;Chen,X.;McNamara,L.;Bates,F.S.;Hillmyer,M.A.Polyetherurethanehydrolyticstabilityafterexposuretodeoxygenatedwater. Macromolecules 2014 , 47 ,5220−5226..

Hernandez,R.;Weksler,J.;Padsalgikar,A.;Choi,T.;Angelo,E.;Lin,J.S.;Xu,L.C.;Siedlecki,C.A.;Runt,J.Acomparisonofphaseorganizationofmodelsegmentedpolyurethaneswithdifferentintersegmentcompatibilities. Macromolecules 2008 , 41 ,9767−9776..

Kleemann,T.;Nonnenmacher,F.;Strauss,M.;Kouraki,K.;Werner,N.;Fendt,A.;Zahn,R.Long-termperformanceandleadfailureanalysisoftheDuratadefibrillationleadcomparedtoitspreviousmodel,therecalledRiatadefibrillationlead. J. Cardiovasc. Electrophysiol. 2019 , 30 ,2012−2019..

Gunatillake,P.A.;Dandeniyage,L.S.;Adhikari,R.;Bown,M.;Shanks,R.;Adhikari,B.Advancementsinthedevelopmentofbiostablepolyurethanes. Polym. Rev. 2019 , 59 ,391−417..

Rueda,L.;Fernandezd'Arlas,B.;Corcuera,M.A.;Eceiza,A.Biostabilityofpolyurethanes.Studyfromtheviewpointofmicrophaseseparatedstructure. Polym. Degrad. Stabil. 2014 , 108 ,195−200..

Hergenrother,R.W.;Wabers,H.D.;Cooper,S.L.Effectofhardsegmentchemistryandstrainonthestabilityofpolyurethanes: in vivo biostability. Biomaterials 1993 , 14 ,449−458..

Liu,W.K.;Zhao,Y.;Wang,R.;Luo,F.;Li,J.S.;Li,J.H.;Tan,H.Effectofchainextenderonhydrogenbondandmicrophasestructureofbiodegradablethermoplasticpolyurethanes. Chinese J. Polym. Sci. 2018 , 36 ,514−520..

Pongkitwitoon;S.;Hernandez;R.;Weksler;J.;Padsalgikar;A.;Choi;T.Temperaturedependentmicrophasemixingofmodelpolyurethaneswithdifferentintersegmentcompatibilities. Polymer 2009 , 50 ,6305−6311..

Wu,H.;Dai,T.;Ao,W.;Shao,S.;Li,Z.;Luo,F.;Li,J.;Zhao,D.;Lan,W.;Zhang,H.;etal.Theroleofsegmentalmixingonthemechanicalpropertiesandoxidativestabilityofpolydimethylsiloxane-basedpolyetherurethane. Polymer 2022 , 261 ,125401..

Li,Y.;Yuan,L.;Ming,H.;Li,X.;Tang,L.;Zhang,J.;Wang,R.;Wang,G.;Jiang,Y.;Li,Z.;Luo,F.;Li,J.H.;Tan,H.;Fu,Q.Enhancedhydrolyticresistanceoffluorinatedsilicon-containingpolyetherurethanes. Biomacromolecules 2020 , 21 ,1460−1470..

LeGac,P.Y.;Choqueuse,D.;Melot,D.Descriptionandmodelingofpolyurethanehydrolysisusedasthermalinsulationinoiloffshoreconditions. Polym. Test. 2013 , 32 ,1588−1593..

Gerlock,J.L.;Braslaw,J.;Mahoney,L.R.;Ferris,F.C.Reactionofpolyurethanefoamwithdrysteam:kineticsandmechanismofreactions. J. Polym. Sci., Part A: Polym. Chem. 1980 , 18 ,541−557..

Murata,S.;Nakajima,T.;Tsuzaki,N.;Yasuda,M.;Kato,T.Synthesisandhydrolysisresistanceofpolyurethanederivedfrom2,4-diethyl-1,5-pentanediol. Polym. Degrad. Stabil. 1998 , 61 ,527−534..

Li,Z.;Yang,J.;Ye,H.;Ding,M.M.;Luo,F.;Li,J.S.;Li,J.H.;Tan,H.;Fu,Q.Simultaneousimprovementofoxidativeandhydrolyticresistanceofpolycarbonateurethanesbasedonpolydimethylsiloxane/poly(hexamethylenecarbonate)mixedmacrodiols. Biomacromolecules 2018 , 19 ,2137−2145..

VanBogart,J.W.C.;Bluemke,D.A.;Cooper,S.L.Annealing-inducedmorphologicalchangesinsegmentedelastomers. Polymer 1981 , 22 ,1428−1438..

Dempsey,D.K.;Carranza,C.;Chawla,C.P.;Gray,P.;Eoh,J.H.;Cereceres,S.;Cosgriff-Hernandez,E.M.Comparativeanalysisofinvitrooxidativedegradationofpoly(carbonateurethanes)forbiostabilityscreening. J. Biomed. Mater. Res. Part A 2014 , 102 ,3649−3665..

Speckhard,T.A.;Cooper,S.L.Ultimatetensilepropertiesofsegmentedpolyurethaneelastomers:factorsleadingtoreducedpropertiesforpolyurethanesbasedonnonpolarsoftsegments. Rubber Chem. Technol. 1986 , 59 ,405−431..

Runt,S.P.J.Temperaturedependentmicrophasemixingofmodelpolyurethaneswithdifferentintersegmentcompatibilities. Polymer 2009 , 7 ,6305−6311..

Wang,A.;Shao,S.R.;Wu,H.C.;Tian,C.X.;Luo,F.;Li,J.H.;Li,Z.;Tan,H.Effectoffluorocarbonsidechainonthemicrophasemorphologyandrheologicalbehaviorofthermoplasticpolyurethanes. Chinese J. Polym. Sci. 2022 ,10.1007/s10118-022-2865-3..

Teo,L.S.;Chen,C.Y.;Kuo,J.F.Fouriertransforminfraredspectroscopystudyoneffectsoftemperatureonhydrogenbondinginamine-containingpolyurethanesandpoly(urethane-urea)s. Macromolecules 1997 , 30 ,1793−1799..

Views

228

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

Regulation of Microphase Separation in Bio-based Thermoplastic Polyurethanes Driven by Hard Segment Content

Hydrogen Bonding in Gel Polymer Electrolyte Enables High Performance High-mass-loading Silicon Anode

Anti-biofouling Hydrogels: Surface Hydration, Classification, and Biomedical Applications

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Related Author

Yu-Hong Zhang

Jian-Fei Ma

Hao-Bo Wei

Jie Wang

Feng Wang

De-Xian Yin

Yu-Qiong Hu

Ya-Nan Cheng

Related Institution

Department of Polymer Science and Engineering, University of Science and Technology of China

School of Chemistry and Pharmaceutical Engineering, Jilin University of Chemical Technology

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology

School of Energy (National Industry-Education Platform for Energy Storage), Tianjin University

School of Materials Science and Engineering, State Key Laboratory of Advanced Materials for Intelligent Sensing, Tianjin University

⁰