A Perspective on the Dynamics Properties in Polymer Nanocomposites

Xu-Ze Zhang; Zhong-Yuan Lu; Hu-Jun Qian

doi:10.1007/s10118-023-2956-9

Your Location：

Home >

Browse articles >

A Perspective on the Dynamics Properties in Polymer Nanocomposites

PERSPECTIVE | Updated：2023-08-24

- A Perspective on the Dynamics Properties in Polymer Nanocomposites
- Chinese Journal of Polymer Science Vol. 41, Issue 9, Pages: 1355-1360(2023)
- Affiliations：
  
  State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China
- Author bio：
  
  hjqian@jlu.edu.cn
- Funds：
- DOI：10.1007/s10118-023-2956-9
  CLC：
- Received：31 December 2022，
  
  Accepted：09 February 2023，
  
  Online First：24 March 2023，
  
  Published：01 September 2023
- Accepted：
Scan QR Code
Zhang, X. Z.; Lu, Z. Y.; Qian, H. J. A perspective on the dynamics properties in polymer nanocomposites. Chinese J. Polym. Sci. 2023, 41, 1355–1360

Xu-Ze Zhang, Zhong-Yuan Lu, Hu-Jun Qian. A Perspective on the Dynamics Properties in Polymer Nanocomposites[J]. Chinese Journal of Polymer Science, 2023, 41(9): 1355-1360.
Zhang, X. Z.; Lu, Z. Y.; Qian, H. J. A perspective on the dynamics properties in polymer nanocomposites. Chinese J. Polym. Sci. 2023, 41, 1355–1360 DOI： 10.1007/s10118-023-2956-9.

Xu-Ze Zhang, Zhong-Yuan Lu, Hu-Jun Qian. A Perspective on the Dynamics Properties in Polymer Nanocomposites[J]. Chinese Journal of Polymer Science, 2023, 41(9): 1355-1360. DOI： 10.1007/s10118-023-2956-9.

摘要

Recent researches about dynamics properties in the field of polymer nanocomposites are reviewed and a theoretical model successfully explains the non-Einstein like viscosity reduction phenomena found in all-polymer nanocomposites

which is expected to be applicable for various polymer nanocomposite systems with different interactions between polymers and nanoparticles.

Abstract

Polymer nanocomposites (PNCs) usually have superior properties than pristine polymers. Understanding the dynamics properties in PNC system is crucial to reveal the mechanism of property change unpon the addition of nanoparticles (NPs)

and therefore for a better design of the material properties. In this short perspective

we summarize recent advances mainly from theoretical and simulation studies of dynamics properties in polymer nanocomposite system. One is the "vehicle model" which reveals that diffusion dynamics of sticky NP is coupled to surrounding chain segments. Similarly

recent simulations demonstrate that such coupling also exists in all-polymer nanocomposite wich is composed of linear polymer chains and single-chain nanoparticles (SCNPs). These SCNPs have almost the same chemical composition as the matrix chain. Therefore

it is assumed that such all-polymer nanocomposite can act as a model system where there are no enthalpic interactions between NPs and polymer chains. Although the above dynamic coupling was found in the above two different systems containing inorganic NPs or relatively small organic SCNPs

it was found that the length scale of such dynamic coupling (the thickness of the matrix/NP interface) is comparable to the NP size

which is surprisingly consistent in the above two different systems. In addition

a chain-length dependence of the NP influence on the chain dynamics reported from a recent joint simulaiton and experimental study of all-polymer nanocomposite system

and a theoretical model developed for such phenomena are also reviewed. At the end

we give an outlook of this field

especially for possible chain-length dependence of complex dynamics in sticky-NP systems.

关键词

Keywords

references

Li,S.;MengLin,M.;Toprak,M.S.;Kim,D.K.;Muhammed,M.Nanocompositesofpolymerandinorganicnanoparticlesforopticalandmagneticapplications. Nano Rev. 2010 , 1 ,5214..

Cong,H.;Radosz,M.;Towler,B.F.;Shen,Y.Polymer-inorganicnanocompositemembranesforgasseparation. Sep. Purific. Technol. 2007 , 55 ,281−291..

Thakur,V.K.;Gupta,R.K.Recentprogressonferroelectricpolymer-basednanocompositesforhighenergydensitycapacitors:synthesis,dielectricproperties,andfutureaspects. Chem. Rev. 2016 , 116 ,4260−4317..

Tanaka,T.Dielectricnanocompositeswithinsulatingproperties. IEEE Transactions on Dielectrics and Electrical Insulation 2005 , 12 ,914−928..

Anderson,B.J.;Zukoski,C.F.Rheologyandmicrostructureofanunentangledpolymernanocompositemelt. Macromolecules 2008 , 41 ,9326−9334..

Nguyen,C.;Desgranges,F.;Galanis,N.;Roy,G.;Maré,T.;Boucher,S.;Mintsa,H.A.ViscositydataforAl 2 O 3 -waternanofluid—hysteresis:isheattransferenhancementusingnanofluidsreliable? Int. J. Thermal Sci. 2008 , 47 ,103−111..

Duangthongsuk,W.;Wongwises,S.Measurementoftemperature-dependentthermalconductivityandviscosityofTiO 2 -waternanofluids. Experimental Thermal and Fluid Sci. 2009 , 33 ,706−714..

Einstein,A.,etal.Onthemotionofsmallparticlessuspendedinliquidsatrestrequiredbythemolecular-kinetictheoryofheat. Annalen der physik 1905 , 17 ,208..

Batchelor,G.TheeffectofBrownianmotiononthebulkstressinasuspensionofsphericalparticles. J. Fluid Mechanics 1977 , 83 ,97−117..

Guzeyev,V.;Rafikov,M.;Malinskii,Y.M.Theeffectoffillerdispersityofthemeltviscosityofpolyvinylchloride(PVC). Polym. Sci. USSR 1975 , 17 ,923−926..

Tuteja,A.;Duxbury,P.M.;Mackay,M.E.Multifunctionalnanocompositeswithreducedviscosity. Macromolecules 2007 , 40 ,9427−9434..

Tan,H.;Lin,Y.;Zheng,J.;Gong,J.;Qiu,J.;Xing,H.;Tang,T.Particle-sizedependentmeltviscositybehaviorandthepropertiesofthree-armstarpolystyrene-Fe 3 O 4 composites. Soft Matter 2015 , 11 ,3986−3993..

Schmidt,R.G.;Gordon,G.V.;Dreiss,C.A.;Cosgrove,T.;Krukonis,V.J.;Williams,K.;Wetmore,P.M.Acriticalsizeratioforviscosityreductioninpoly(dimethylsiloxane)-polysilicatenanocomposites. Macromolecules 2010 , 43 ,10143−10151..

Tan,H.;Xu,D.;Wan,D.;Wang,Y.;Wang,L.;Zheng,J.;Liu,F.;Ma,L.;Tang,T.MeltviscositybehaviorofC60containingstarpolystyrenecomposites. Soft Matter 2013 , 9 ,6282−6290..

Mangal,R.;Srivastava,S.;Archer,L.A.Phasestabilityanddynamicsofentangledpolymer-nanoparticlecomposites. Nat. Commun. 2015 , 6 ,1−9..

Kim,D.;Srivastava,S.;Narayanan,S.;Archer,L.A.Polymernanocomposites:polymerandparticledynamics. Soft Matter 2012 , 8 ,10813−10818..

Goldansaz,H.;Goharpey,F.;Afshar-Taromi,F.;Kim,I.;Stadler,F.J.;VanRuymbeke,E.;Karimkhani,V.Anomalousrheologicalbehaviorofdendriticnanoparticle/linearpolymernanocomposites. Macromolecules 2015 , 48 ,3368−3375..

Jancar,J.;Douglas,J.;Starr,F.W.;Kumar,S.;Cassagnau,P.;Lesser,A.;Sternstein,S.S.;Buehler,M.Currentissuesinresearchonstructure-propertyrelationshipsinpolymernanocomposites. Polymer 2010 , 51 ,3321−3343..

Gong,S.;Chen,Q.;Moll,J.F.;Kumar,S.K.;Colby,R.H.Segmentaldynamicsofpolymermeltswithsphericalnanoparticles. ACS Macro Lett. 2014 , 3 ,773−777..

Cheng,S.;Carroll,B.;Lu,W.;Fan,F.;Carrillo,J.M.Y.;Martin,H.;Holt,A.P.;Kang,N.-G.;Bocharova,V.;Mays,J.W.;Sumpter,B.G.;Dadmum,M.;Sokolov,A.P.Interfacialpropertiesofpolymernanocomposites:roleofchainrigidityanddynamicheterogeneitylengthscale. Macromolecules 2017 , 50 ,2397−2406..

Jimenez,A.M.;Zhao,D.;Misquitta,K.;Jestin,J.;Kumar,S.K.Exchangelifetimesoftheboundpolymerlayeronsilicananoparticles. ACS Macro Lett. 2019 , 8 ,166−171..

Cheng,S.;Bocharova,V.;Belianinov,A.;Xiong,S.;Kisliuk,A.;Somnath,S.;Holt,A.P.;Ovchinnikova,O.S.;Jesse,S.;Martin,H.,etal.Unravelingthemechanismofnanoscalemechanicalreinforcementinglassypolymernanocomposites. Nano Lett. 2016 , 16 ,3630−3637..

Carroll,B.;Cheng,S.;Sokolov,A.P.Analyzingtheinterfaciallayerpropertiesinpolymernanocompositesbybroadbanddielectricspectroscopy. Macromolecules 2017 , 50 ,6149−6163..

Yamamoto,U.;Carrillo,J.M.Y.;Bocharova,V.;Sokolov,A.P.;Sumpter,B.G.;Schweizer,K.S.Theoryandsimulationofattractivenanoparticletransportinpolymermelts. Macromolecules 2018 , 51 ,2258−2267..

Carroll,B.;Bocharova,V.;Carrillo,J.M.Y.;Kisliuk,A.;Cheng,S.;Yamamoto,U.;Schweizer,K.S.;Sumpter,B.G.;Sokolov,A.P.Diffusionofstickynanoparticlesinapolymermelt:crossoverfromsuppressedtoenhancedtransport. Macromolecules 2018 , 51 ,2268−2275..

Mackay,M.E.;Dao,T.T.;Tuteja,A.;Ho,D.L.;VanHorn,B.;Kim,H.C.;Hawker,C.J.Nanoscaleeffectsleadingtonon-Einstein-likedecreaseinviscosity. Nat. Mater. 2003 , 2 ,762−766..

Chen,T.;Qian,H.J.;Zhu,Y.L.;Lu,Z.Y.Structureanddynamicspropertiesatinterphaseregioninthecompositeofpolystyreneandcross-linkedpolystyrenesoftnanoparticle. Macromolecules 2015 , 48 ,2751−2760..

Qian,H.J.;Carbone,P.;Chen,X.;Karimi-Varzaneh,H.A.;Liew,C.C.;MüllerPlathe,F.Temperature-transferablecoarse-grainedpotentialsforethylbenzene,polystyrene,andtheirmixtures. Macromolecules 2008 , 41 ,9919−9929..

Jia,X.M.Moleculardynamicssimulationstudyoninterfacepropertiesofpolymernanocomposites.Ph.D.thesis,JilinUniversity, 2021 .

Chen,T.;Qian,H.J.;Lu,Z.Y.Diffusiondynamicsofnanoparticleanditscouplingwithpolymersinpolymernanocomposites. Chem. Phys. Lett. 2017 , 687 ,96−100..

Chen,T.;Qian,H.J.;Lu,Z.Y.Note:Chainlengthdependentnanoparticlediffusioninpolymermelt:effectofnanoparticlesoftness. J. Chem. Phys. 2016 , 145 ,106101..

Chen,T.;Zhao,H.Y.;Shi,R.;Lin,W.F.;Jia,X.M.;Qian,H.J.;Lu,Z.Y.;Zhang,X.X.;Li,Y.K.;Sun,Z.Y.Anunexpected N -dependenceintheviscosityreductioninall-polymernanocomposite. Nat. Commun. 2019 , 10 ,1−8..

Views

237

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Conformational Disorder Within the Crystalline Region of Silica-Filled Polydimethylsiloxane: A Solid-State NMR Study

Dual Effects of Interfacial Interaction and Geometric Constraints on Structural Formation of Poly(butylene terephthalate) Nanorods

Thermo-sensitive Poly(DEGMMA-co-MEA) Microgels: Synthesis, Characterization and Interfacial Interaction with Adsorbed Protein Layer

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

Related Author

Wei Chen

Liang-Bin Li

Ai Lu

Chang-Lin Li

Yu-Qi Xiong

Xiaoguang Li

Yan Cao

Xing Ouyang

Related Institution

National Synchrotron Radiation Laboratory, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China

Department of Accelerator Science and Engineering Physics, School of Nuclear Science and Technology, University of Science and Technology of China

Institute of Chemical Materials, China Academy of Engineering Physics

Institute for Advanced Study (IAS), Shenzhen University

College of Materials Science and Engineering, Shenzhen University

⁰