Relaxation of Mechanical Stress in Poly(vinyl alcohol) Cryogels of Different Compositions

Vladimir N. Manzhai; Maria S. Fufaeva; Ekaterina S. Kashlach

doi:10.1007/s10118-022-2889-8

Your Location：

Home >

Browse articles >

Relaxation of Mechanical Stress in Poly(vinyl alcohol) Cryogels of Different Compositions

RESEARCH ARTICLE | Updated：2023-01-18

- Relaxation of Mechanical Stress in Poly(vinyl alcohol) Cryogels of Different Compositions
- Chinese Journal of Polymer Science Vol. 41, Issue 3, Pages: 442-447(2023)
- Affiliations：
  
  Institute of Petroleum Chemistry of the Siberian Branch of the Russian Academy of Sciences, Tomsk 634055, Russia
- Author bio：
  
  kashlatch.cat@yandex.ru
- Funds：
- DOI：10.1007/s10118-022-2889-8
  CLC：
- Received：21 May 2022，
  
  Revised：2022-10-13，
  
  Accepted：17 October 2022，
  
  Online First：12 December 2022，
  
  Published：01 March 2023
- Accepted：
Scan QR Code
Manzhai, V. N.; Fufaeva, M. S.; Kashlach, E. S. Relaxation of mechanical stress in poly(vinyl alcohol) cryogels of different compositions. Chinese J. Polym. Sci. 2023, 41, 442–447

Vladimir N. Manzhai, Maria S. Fufaeva, Ekaterina S. Kashlach. Relaxation of Mechanical Stress in Poly(vinyl alcohol) Cryogels of Different Compositions[J]. Chinese Journal of Polymer Science, 2023, 41(3): 442-447.
Manzhai, V. N.; Fufaeva, M. S.; Kashlach, E. S. Relaxation of mechanical stress in poly(vinyl alcohol) cryogels of different compositions. Chinese J. Polym. Sci. 2023, 41, 442–447 DOI： 10.1007/s10118-022-2889-8.

Vladimir N. Manzhai, Maria S. Fufaeva, Ekaterina S. Kashlach. Relaxation of Mechanical Stress in Poly(vinyl alcohol) Cryogels of Different Compositions[J]. Chinese Journal of Polymer Science, 2023, 41(3): 442-447. DOI： 10.1007/s10118-022-2889-8.

摘要

Macromolecular coils in the externally influenced cryogels are transferred from the stress state to the equilibrium state to acquire the shape of a ball over time. Then the relaxation time is the characteristic time for the system to return to the equilibrium state.

Abstract

The study presents the experimental results of measurements of the relaxation time of cryogels formed from various colloid-dispersed systems based on a poly(vinyl alcohol) aqueous solution. It is shown that the value of relaxation time

which characterizes the relationship between the viscosity and elasticity of real bodies

describes the rheological properties of materials more objectively than the traditional assessment of their physical and mechanical characteristics only by the elasticity modulus of the samples.

关键词

Keywords

references

Du Toit, J. P.; Pott, R. W. M . Transparent polyvinyl-alcohol cryogel as immobilisation matrix for continuous biohydrogen production by phototrophic bacteria . Biotechnol. Biofuels , 2020 . 13 105 - 121 . DOI: 10.1186/s13068-020-01743-7 http://doi.org/10.1186/s13068-020-01743-7 .

Wan, W.; Bannerman, A. D.; Yang, L.; Mak, H. in Poly(vinyl alcohol) cryogels for biomedical applications, Vol. 263, ed. by Okay, O., Springer, Cham, 2014 , p. 330.

Altunina, L. K.; Kuvshinov, V. A.; Dolgikh, S. N. Cryogels—promising material for underground works in permafrost. Advances in the Geological Storage of Carbon Dioxide. NATO Science Series. IV. Earth and Environmental Sciences. Springer, 2006 , 65 , 103–110.

Lozinsky, V. I.; Podorozhko, E. A.; Vasil’ev, V. G.; Burmistrov, A. A.; Nikitina, Y. B.; Klabukova, L. F.; Kondrashov, Y. G., Vasiliev, N. K. A study of cryostructuring of polymer systems. 45 . Effect of porosity of dispersed filler on physicochemical characteristics of composite poly(vinyl alcohol) cryogels . Colloid J. , 2017 . 79 497 - 507 . DOI: 10.1134/S1061933X17040081 http://doi.org/10.1134/S1061933X17040081 .

Manzhai V. N.; Altunina L. K.; Fufaeva M. S.; Bondaletov V. G.; Bondaletova L. I. 2016 , patent RF, 2605112.

Vasiliev, N. K.; Pronk, A. D. C.; Shatalina, I. N.; Janssen, F. H. M. E.; Houben, R. W. G. A review on the development of reinforced ice for use as a building material in cold regions cold regions. Cold regions science and technology. Eindhoven University of Technology, Eindhoven, Netherlands, 2015 , 115 , 56–63.

Altunina, L. K.; Fufaeva, M. S.; Manzhai, V. N.; Bondaletov, V. G.; Fisenko, D. V . Effect of an oxidized polymeric petroleum resin on the properties of cryogels . Chem. Sustain. Dev. , 2019 . 27 120 - 125 . .

Lozinsky, V. I.; Savina, I. N . Study of cryostructuring of polymer systems: 22. Composite poly(vinyl alcohol) cryogels filled with dispersed particles of various degrees of hydrophilicity/hydrophobicity . Colloid J. , 2002 . 64 336 - 343 . DOI: 10.1023/A:1015920810103 http://doi.org/10.1023/A:1015920810103 .

Lozinsky V. I.; Podorozhko E. A. 2006 , patent RF, 2326908.

Manzhai, V. N.; Fufaeva, M. S . Polyvinyl alcohol cryogels as an efficient spent-oil utilization method . Chem. Tech. Fuels Oil. , 2015 . 51 487 - 492 . DOI: 10.1007/s10553-015-0629-2 http://doi.org/10.1007/s10553-015-0629-2 .

Altunina, L. K.; Manzhai, V. N.; Fufaeva M. S . Mechanical and thermal properties of cryogels and foamed cryogels produced from aqueous solutions of poly(vinyl alcohol) . J. Appl. Chem. , 2006 . 79 1669 - 1672 . .

Podorozhko, E. A.; Korlyukov, A. A.; Lozinsky, V. I. Cryostructuring of polymer systems. XXX . Poly(vinyl alcohol)-based composite cryogels filled with small disperse oil droplets: a gel system capable of mechanically induced releasing of the lipophilic constituents . J. Appl. Polym. Sci. , 2010 . 117 1332 - 1349 . .

Kolosova, O. U.; Kurochkin, I. N.; Kurochkin, I. I.; Lozinsky, V. I. Cryostructuring of polymeric systems. 48 . Influence of organic chaotropes and kosmotropes on the cryotropic gel-formation of aqueous poly(vinyl alcohol) solutions . Eur. Polym. J. , 2018 . 102 169 - 177 . DOI: 10.1016/j.eurpolymj.2018.03.010 http://doi.org/10.1016/j.eurpolymj.2018.03.010 .

Podorozhko, E. A.; Ul’yabaeva, G. R.; Tikhonov, V. E.; Grachev, A. V.; Vladimirov, L. V.; Antonov, Yu. A.; Kil'deeva, N. R.; Lozinsky, V. I. A study of cryostructuring of polymer systems. 43 . Characteristics of microstructure of chitosan-containing complex and composite poly(vinyl alcohol) cryogels . Colloid J. , 2017 . 79 94 - 105 . DOI: 10.1134/S1061933X16060119 http://doi.org/10.1134/S1061933X16060119 .

Lozinsky, V. I.; Damshkaln, L. G.; Kurochkin, I. N.; Kurochkin. I. I. Cryostructuring of polymeric systems. 36 . Poly(vinyl alcohol) cryogels prepared from solutions of the polymer in water/low-molecular alcohol mixtures . Eur. Polym. J. , 2014 . 53 189 - 205 . DOI: 10.1016/j.eurpolymj.2014.01.020 http://doi.org/10.1016/j.eurpolymj.2014.01.020 .

Altunina, L. K.; Manzhai, V. N.; Stasyeva, L. A.; Fufaeva, M. S. 2006 , patent RF, 2288924.

Altunina, L. K.; Manzhai, V. N.; Stasyeva, L. A.; Fufaeva, M. S . Production of foamed cryogels by chemical gas generation in an aqueous solution of poly(vinyl alcohol) . J. Appl. Chem. , 2007 . 80 1647 - 1650 . .

Manzhai, V. N.; Fufaeva, M. S . Dispersity and stability of foams obtained from poly(vinyl alcohol) solution and the properties of resulting foamed cryogels . Colloid J. , 2014 . 76 455 - 458 . DOI: 10.1134/S1061933X14040097 http://doi.org/10.1134/S1061933X14040097 .

Lozinsky, V. I.; Sakhno, N. G.; Damshkaln, L. G.; Bakeeva, I. V.; Zubov, V. P.; Kurochkin, I. N.; Kurochkin, I. I . Study of cryostructuring of polymer systems: 31. Effect of additives of alkali metal chlorides on physicochemical properties and morphology of poly(vinyl alcohol) cryogels . Colloid J. , 2011 . 73 234 - 243 . DOI: 10.1134/S1061933X11020086 http://doi.org/10.1134/S1061933X11020086 .

Watase, M; Nishinari, K . Rheological and DSC changes in poly(vinyl alcohol) gels induced by immersion in water . J. Polym. Sci. Polym. Phys. Ed. , 1985 . 23 1803 DOI: 10.1002/pol.1985.180230906 http://doi.org/10.1002/pol.1985.180230906 .

Malkin, A. Ya.; Isayev, A. I., Rheology: concepts, methods and applications , ChemTec Publishing, Toronto, 2006 , p. 474.

Montgomery, T. S., in Introduction to polymer rheology , John Wiley & Sons, Inc., 2012 , p. 416.

Sunthar, P., in Polymer rheology . Rheology of complex fluids , Springer, New York, 2010 , p. 171–191.

Christanti, Y.; Walker, L. M . Effect of fluid relaxation time of dilute polymer solutions on jet breakup due to a forced disturbance . J. Rheol. , 2002 . 46 733 - 748 . DOI: 10.1122/1.1463418 http://doi.org/10.1122/1.1463418 .

Graessley, W. W . Elasticity and chain dimensions in gaussian networks . Macromolecules , 1975 . 8 865 - 868 . DOI: 10.1021/ma60048a031 http://doi.org/10.1021/ma60048a031 .

Volkenstein, M. V., in Entropy and Information, Nauka, Moscow, 1986 , p. 191.

Ravve, A., in Principles of Polymer Chemistry, Springer, New York, 2016 , p. 801.

Barnes, H. A.; Hutton, J. F.; Walters, K., in An Introduction to Rheology, Elsevier, Amsterdam, 1989 , p. 199.

Wang, J. P.; Yu, Y. H.; Guo, Y. Q.; Luo, W.; Hu, W. B . Local transient jamming in stress relaxation of bulk amorphous polymers . Chinese J. Polym. Sci. , 2021 . 39 906 - 913 . DOI: 10.1007/s10118-021-2570-7 http://doi.org/10.1007/s10118-021-2570-7 .

Volkenstein, M. V . The configurational statistics of polymeric chains . J. Polym. Sci. , 1958 . 29 441 - 454 . DOI: 10.1002/pol.1958.1202912012 http://doi.org/10.1002/pol.1958.1202912012 .

Lozinsky, V. I.; Damshkaln, L. G.; Kurochkin, I. N.; Kurochkin, I. I . Study of cryostructuring of polymer systems: 28. Physicochemical properties and morphology of poly(vinyl alcohol) cryogels formed by multiple freezing-thawing . Colloid J. , 2008 . 70 189 - 198 . DOI: 10.1134/S1061933X08020117 http://doi.org/10.1134/S1061933X08020117 .

Views

132

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Construction of Pressure-resistance Polyethylene-based Pipes with Highly Biaxially Oriented Structure and Self-reinforcing Mechanism

A Macroporous Cryogel with Enhanced Mechanical Properties for Osteochondral Regeneration In vivo

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Related Author

Lin Ye

Bu-Yong Wu

Xiao-Wen Zhao

Yu-Dong Cai

Chang-You Gao

Xin-Yu Wu

Jun Yang

Fang-Hui Wu

Related Institution

School of Materials Science and Engineering, Jiangsu University of Science and Technology

Synthetic Resin Laboratory, Petrochemical Research Institute, PetroChina

State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University

Bio-nanomaterials and Regenerative Medicine Research Division, Zhejiang-California International Nanosystem Institute, Zhejiang University

Department of Orthopaedics, the Third Hospital Affiliated to Wenzhou Medical University & Rui’an People’s Hospital, Rui’an

⁰