Zeng, K. W.; Peng, H. S. Metal-backboned polymer: conception, design and synthesis. Chinese J. Polym. Sci. 2023, 41, 3–6
Kai-Wen Zeng, Hui-Sheng Peng. Metal-Backboned Polymer: Conception, Design and Synthesis[J]. Chinese Journal of Polymer Science, 2023, 41(1): 3-6.
Zeng, K. W.; Peng, H. S. Metal-backboned polymer: conception, design and synthesis. Chinese J. Polym. Sci. 2023, 41, 3–6DOI: 10.1007/s10118-022-2887-x.
Kai-Wen Zeng, Hui-Sheng Peng. Metal-Backboned Polymer: Conception, Design and Synthesis[J]. Chinese Journal of Polymer Science, 2023, 41(1): 3-6.DOI: 10.1007/s10118-022-2887-x.
Metal-Backboned Polymer: Conception, Design and Synthesis
A new type of polymers whose backbones are composed of metal atoms has been designed
synthesized
and studied
opening up a new avenue to design new functional polymers in the future.
Abstract
The backbones of polymers are generally composed of non-metal elements such as C
N
O and Si. Here we propose and synthesize a new class of polymers whose backbones are completely made from metal atoms connected by chemical bonds
and they are thus named metal-backboned polymers. As a demonstration
nickel is selected as the metal to construct the nickel-backboned polymers with varied lengths
which are verified by mass spectrometry and studied by ultraviolet-visible spectroscopy. These metal-bonded polymers open up a new avenue to develop functional polymers in the future.
Wilbon, P . A.; Chu, F.; Tang, C. Progress in renewable polymers from natural terpenes, terpenoids, and rosin . Macromol. Rapid Commun. , 2013 . 34 8 - 37 . DOI: 10.1002/marc.201200513 http://doi.org/10.1002/marc.201200513 .
Saheb, D. N.; Jog, J. P . Natural fiber polymer composites: a review . Adv. Polym. Technol. , 1999 . 18 351 - 363 . DOI: 10.1002/(SICI)1098-2329(199924)18:4<351::AID-ADV6>3.0.CO;2-X http://doi.org/10.1002/(SICI)1098-2329(199924)18:4<351::AID-ADV6>3.0.CO;2-X .
Mohammed, L.; Ansari, M. N. M.; Pua, G.; Jawaid, M.; Islam, M. S . A review on natural fiber reinforced polymer composite and its applications . Int. J. Polym. Sci. , 2015 . 2015 243947 DOI: 10.1155/2015/243947 http://doi.org/10.1155/2015/243947 .
Li, T.; Cai, G.; Lin, Y.; Lu, X.; Zhan, X . Effects of thieno[3,2- b ]thiophene number on narrow-bandgap fused-ring electron acceptors . Chinese J. Polym. Sci. , 2022 . 40 914 - 920 . DOI: 10.1007/s10118-022-2735-z http://doi.org/10.1007/s10118-022-2735-z .
Harisomayajula, N. V. S.; Wu, B. H.; Lu, D. Y.; Kuo, T. S.; Chen, I. C.; Tsai, Y. C . Ligand-unsupported cuprophilicity in the preparation of dodecacopper(I) complexes and raman studies . Angew. Chem. Int. Ed. , 2018 . 57 9925 - 9929 . DOI: 10.1002/anie.201801955 http://doi.org/10.1002/anie.201801955 .
Rivada-Wheelaghan, O.; Aristizabal, S. L.; Lopez-Serrano, J.; Fayzullin, R. R.; Khusnutdinova, J. R . Controlled and reversible stepwise growth of linear copper(I) chains enabled by dynamic ligand scaffolds . Angew. Chem. Int. Ed. , 2017 . 56 16267 - 16271 . DOI: 10.1002/anie.201709167 http://doi.org/10.1002/anie.201709167 .
Ismayilov, R. H.; Wang, W. Z.; Lee, G. H.; Yeh, C. Y.; Hua, S. A.; Song, Y.; Rohmer, M. M.; Benard, M.; Peng, S. M . Two linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings . Angew. Chem. Int. Ed. , 2011 . 50 2045 - 2053 . DOI: 10.1002/anie.201006695 http://doi.org/10.1002/anie.201006695 .
Dyker, G.; Mastalerz, M.; Merz, K . From a calix[4]arene to a hexameric supracycle . Eur. J. Org. Chem. , 2003 . 2003 4355 - 4362 . DOI: 10.1002/ejoc.200300380 http://doi.org/10.1002/ejoc.200300380 .
Hua, S. A.; Cheng, M. C.; Chen, C. H.; Peng, S. M . From homonuclear metal string complexes to heteronuclear metal string complexes . Eur. J. Inorg. Chem. , 2015 . 2510 - 2523 . DOI: 10.1002/ejic.201403237 http://doi.org/10.1002/ejic.201403237 .
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