Brominated Butyl Rubber Anticorrosive Coating and Its Self-healing Behaviors

Guang-Bing Luo; Bo Pang; Xing-Qi Luo; Yi Wang; Hong Zhou; Li-Juan Zhao

doi:10.1007/s10118-022-2844-8

Your Location：

Home >

Browse articles >

Brominated Butyl Rubber Anticorrosive Coating and Its Self-healing Behaviors

RESEARCH ARTICLE | Updated：2023-01-06

- Brominated Butyl Rubber Anticorrosive Coating and Its Self-healing Behaviors
- Chinese Journal of Polymer Science Vol. 41, Issue 2, Pages: 297-305(2023)
- Affiliations：
  
  a.College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, China
  b.The Second Research Institute of Civil Aviation Administration of China (CAAC), Chengdu 610041, China
- Author bio：
  
  zhhans77@163.com (H.Z.)
  lijuan_zhao@sicnu.edu.cn (L.J.Z.)
- Funds：
- DOI：10.1007/s10118-022-2844-8
  CLC：
- Received：22 May 2022，
  
  Revised：2022-7-9，
  
  Accepted：27 July 2022，
  
  Online First：09 October 2022，
  
  Published：01 February 2023
- Accepted：
Scan QR Code
Luo, G. B.; Pang, B.; Luo, X. Q.; Wang, Y.; Zhou, H.; Zhao, L. J. Brominated butyl rubber anticorrosive coating and its self-healing behaviors. Chinese J. Polym. Sci. 2023, 41, 297–305

Guang-Bing Luo, Bo Pang, Xing-Qi Luo, et al. Brominated Butyl Rubber Anticorrosive Coating and Its Self-healing Behaviors[J]. Chinese Journal of Polymer Science, 2023, 41(2): 297-305.
Luo, G. B.; Pang, B.; Luo, X. Q.; Wang, Y.; Zhou, H.; Zhao, L. J. Brominated butyl rubber anticorrosive coating and its self-healing behaviors. Chinese J. Polym. Sci. 2023, 41, 297–305 DOI： 10.1007/s10118-022-2844-8.

Guang-Bing Luo, Bo Pang, Xing-Qi Luo, et al. Brominated Butyl Rubber Anticorrosive Coating and Its Self-healing Behaviors[J]. Chinese Journal of Polymer Science, 2023, 41(2): 297-305. DOI： 10.1007/s10118-022-2844-8.

摘要

The TBP-BIIR coating exhibits a protection efficiency of up to 94% respectively in a strong acid (HNO

pH=2)

strong base (NaOH

pH=12)

and salt solution (3.5 wt% NaCl)

and it could maintain its self-healing and corrosion resistance performance in the strong corrosion environment.

Abstract

Self-healing anticorrosive coatings in extreme environment have attracted considerable interest from researchers. In this work

tert

-butylpyridine (TBP) was incorporated into brominated butyl rubber (BIIR) polymer networks to form a reversible ionic bond with the highly reactive bromine anion. Based on the low glass transition temperature of the BIIR polymer and the electrostatic effects

a robust self-healing anticorrosive coating of TBP-BIIR was prepared. TBP-BIIR coating showed a maximum protection efficiency (PE) of more than 94% (TBP-BIIR-acid

94.37%; TBP-BIIR-alkali

94.95%; TBP-BIIR-salt

95.49%) when treated with a strong acid (HNO

pH=2)

strong base (NaOH

pH=12) and high salt solution (3.5 wt% NaCl). In addition

the PE of coating repaired exceed 89%

and the maximum PE value was approximately 95% in different solutions

which demonstrated its extinguished self-healing abilities. These results indicated that the TBP-BIIR anticorrosive coating could provide excellent safety and durability in special environment

which would be extremely beneficial to improve the working life of metal parts used in aviation and shipping

oil and gas and related industries.

关键词

Keywords

references

Wei, J.; Li, B.; Jing, L.; Tian, N.; Zhao, X.; Zhang, J . Efficient protection of Mg alloy enabled by combination of a conventional anti-corrosion coating and a superamphiphobic coating . Chem. Eng. J. , 2020 . 390 124562 DOI: 10.1016/j.cej.2020.124562 http://doi.org/10.1016/j.cej.2020.124562 .

Lazorenko, G.; Kasprzhitskii, A.; Nazdracheva, T . Anti-corrosion coatings for protection of steel railway structures exposed to atmospheric environments: a review . Constr. Build. Mater. , 2021 . 288 123115 DOI: 10.1016/j.conbuildmat.2021.123115 http://doi.org/10.1016/j.conbuildmat.2021.123115 .

Chen, Y.; Lou, X.; Yang, L.; Wang, C.; Zhou, K.; Chen, M.; Wang, Q.; Zhu, S.; Wang, F . Oxidation and corrosion protection of ZG 12 Cr 9 Mo1Co1NiVNbNB (CB2) ferritic stainless steel by inorganic composite coatings at 650 °C . Corros. Sci. , 2020 . 177 109000 DOI: 10.1016/j.corsci.2020.109000 http://doi.org/10.1016/j.corsci.2020.109000 .

Lu, Y.; Chen, Z.; Wang, C.; Zhao, Q.; Zhang, K.; Du, Y.; Xin, L.; Zhu, S.; Wang, F . Protection of 304 stainless steel by nano-modified silicone coating in cyclically alternate corrosion environment . Corros. Sci. , 2021 . 190 109712 DOI: 10.1016/j.corsci.2021.109712 http://doi.org/10.1016/j.corsci.2021.109712 .

Zhu, G.; Zhao, Y.; Liu, L.; Wang, L.; Wang, J.; Yu, S . Facile fabrication and evaluation of self-healing Zn-Al layered double hydroxide superhydrophobic coating on aluminum alloy . J. Mater. Sci. , 2021 . 56 14803 - 14820 . DOI: 10.1007/s10853-021-06247-9 http://doi.org/10.1007/s10853-021-06247-9 .

Wang, S.; Liu, W.; Shi, H.; Zhang, F.; Liu, C.; Liang, L.; Pi, K . Co-modification of nano-silica and lysine on graphene oxide nanosheets to enhance the corrosion resistance of waterborne epoxy coatings in 3.5% NaCl solution . Polymer , 2021 . 222 123665 DOI: 10.1016/j.polymer.2021.123665 http://doi.org/10.1016/j.polymer.2021.123665 .

Kim, H.; Yarin, A. L.; Lee, M. W . Self-healing corrosion protection film for marine environment . Compos. Part B-Eng. , 2020 . 182 107598 DOI: 10.1016/j.compositesb.2019.107598 http://doi.org/10.1016/j.compositesb.2019.107598 .

Cui, Y.; Song, S.; Tang, Y.; Chen, Y.; Yang, H.; Yang, B.; Huang, J . Decoupling the roles of the catechol content from those of glass transition temperature and dynamic mechanical modulus in determining self-healing and anti-corrosion of mussel-inspired polymers . Polymer , 2019 . 185 121928 .

Yao, J.; Li, N.; Grothe, H.; Qi, Z.; Dong, C . Determination of the hydrogen effects on the passive film and the micro-structure at the surface of 2205 duplex stainless steel . Appl. Surf. Sci. , 2021 . 554 149597 DOI: 10.1016/j.apsusc.2021.149597 http://doi.org/10.1016/j.apsusc.2021.149597 .

Chen, H.; Kim, S. H.; Kim, C.; Chen, J.; Jang, C . Corrosion behaviors of four stainless steels with similar chromium content in supercritical carbon dioxide environment at 650 °C . Corros. Sci. , 2019 . 156 16 - 31 . DOI: 10.1016/j.corsci.2019.04.043 http://doi.org/10.1016/j.corsci.2019.04.043 .

Sun, P.; Wang, Z.; Lu, Y.; Shen, S.; Yang, R.; Xue, A.; Parker, T.; Wang, J.; Wang, Q . Analysis of the corrosion failure of a semiconductor polycrystalline distillation column . Process. Saf. Environ. , 2020 . 135 244 - 256 . DOI: 10.1016/j.psep.2020.01.007 http://doi.org/10.1016/j.psep.2020.01.007 .

Song, Z.; Zhang, C.; Fu, X.; Zhang, H.; Xian, J.; Lin, J . Graphene nanosheet as a new particle dispersant for the jet-electrodeposition of high-performance Ni-P-WC composite coatings . Surf. Coat. Technol. , 2021 . 425 127740 DOI: 10.1016/j.surfcoat.2021.127740 http://doi.org/10.1016/j.surfcoat.2021.127740 .

Ma, A.; Liu, D.; Zhang, X.; Liu, D.; He, G.; Yin, X . Solid particle erosion behavior and failure mechanism of TiZrN coatings for Ti-6Al-4V alloy . Surf. Coat. Technol. , 2021 . 426 127701 .

Wu, Y.; Zhao, W.; Ou, J . Stable, superfast and self-healing fluid coating with active corrosion resistance . Adv. Colloid Interfaces , 2021 . 295 102494 DOI: 10.1016/j.cis.2021.102494 http://doi.org/10.1016/j.cis.2021.102494 .

Ming, H. L.; Zhang, Z. M.; Wang, S. Y.; Wang, J. Q.; Han, E. H.; Ke, W . Short time oxidation behavior of 308L weld metal and 316L stainless steel with different surface state in simulated primary water with 0.1 mg/L dissolved oxygen . Mater. Corros. , 2015 . 66 869 - 881 . DOI: 10.1002/maco.201408013 http://doi.org/10.1002/maco.201408013 .

Zhang, H.; Liang, T.; Liu, Y.; Misra, R. D. K.; Zhao, Y . Low-surface-free-energy GO/FSiAC coating with self-healing function for anticorrosion and antifouling applications . Surf. Coat. Technol. , 2021 . 425 127690 DOI: 10.1016/j.surfcoat.2021.127690 http://doi.org/10.1016/j.surfcoat.2021.127690 .

Zhang, D.; Peng, F.; Qiu, J.; Tan, J.; Zhang, X.; Chen, S.; Qian, S.; Liu, X . Regulating corrosion reactions to enhance the anti-corrosion and self-healing abilities of PEO coating on magnesium . Corros Sci , 2021 . 192 109840 DOI: 10.1016/j.corsci.2021.109840 http://doi.org/10.1016/j.corsci.2021.109840 .

Zhuo, S.; Liu, Y.; Zhou, L.; Feng, X . Enhanced dual-responsive shape memory nanocomposites with rapid and efficient self-healing capability . J. Mater. Sci. , 2018 . 53 13936 - 13948 . DOI: 10.1007/s10853-018-2591-y http://doi.org/10.1007/s10853-018-2591-y .

Yue, D. W.; Wang, H. Q.; Tao, H. Q.; Zheng, P.; Li, C. H.; Zuo, J. L . A fast and room-temperature self-healing thermal conductive polymer composite . Chinese J. Polym. Sci. , 2021 . 39 1328 - 1336 . .

Yang, Y.; Davydovich, D.; Hornat, C. C.; Liu, X.; Urban, M. W . Leaf-inspired self-healing polymers . Chem , 2018 . 4 1928 - 1936 . DOI: 10.1016/j.chempr.2018.06.001 http://doi.org/10.1016/j.chempr.2018.06.001 .

Zhai, L.; Narkar, A.; Ahn, K . Self-healing polymers with nanomaterials and nanostructures . Nano Today , 2020 . 30 100826 .

Wang, S.; Urban, M. W . Self-healing polymers . Nat. Rev. Mater. , 2020 . 5 562 - 583 . .

Yin, Q. Y.; Dai, C. H.; Chen, H.; Gou, K.; Guan, H. Z.; Wang, P. H.; Jiang, J. T.; Weng, G. S . Tough double metal-ion cross-linked elastomers with temperature-adaptable self-healing andluminescence properties . Chinese J. Polym. Sci. , 2021 . 39 554 - 565 . .

Le, H. H.; Hoang, T. X.; Schoene, E.; Reuter, U.; Stöckelhuber, K. W.; Mandal, S.; Dhakal, K . N.; Adhikari, R.; Wiessner, S. Effect of phase selective wetting of hybrid filler on the self-healing properties of rubber blends . Polymer , 2021 . 231 124146 .

Das, A.; Le, H. H.; Vuorinen, J.; Heinrich, G . Comment on "monitoring network and interfacial healing processes by broadband dielectric spectroscopy: a case study on natural rubber" . ACS Appl. Mater. Interfaces , 2017 . 9 14547 - 14551 . DOI: 10.1021/acsami.6b16045 http://doi.org/10.1021/acsami.6b16045 .

Parent, J. S.; Thom, D. J.; White, G.; Whitney, R. A.; Hopkins, W . Thermal stability of brominated poly(isobutylene- co -isoprene) . J. Polym. Sci., Part A: Polym. Chem. , 2010 . 39 2019 - 2026 . DOI: 10.1002/pola.1177 http://doi.org/10.1002/pola.1177 .

Zhang, L.; Wang, H.; Zhu, Y.; Xiong, H.; Wu, J . Electron-donating effect enabled simultaneous improvement on the mechanical and self-healing properties of bromobutyl rubber ionomers . ACS Appl. Mater. Interfaces , 2020 . 12 53239 - 53246 . DOI: 10.1021/acsami.0c14901 http://doi.org/10.1021/acsami.0c14901 .

Li, C.; He, R.; Liang, Q.; Cao, J.; Yin, J.; Tang, Y . 4- Tert -butylpyridine-assisted low-cost and soluble copper phthalocyanine as dopant-free hole transport layer for efficient Pb- and Sn-based perovskite solar cells . Sci. China Chem. , 2020 . 63 1053 - 1058 . DOI: 10.1007/s11426-020-9725-3 http://doi.org/10.1007/s11426-020-9725-3 .

Phan, T. A. P.; Nguyen, N. P.; Nguyen, L. T.; Nguyen, P. H.; Le, T. K.; Huynh, T. V.; Lund, T.; Tsai, D. H.; Wei, T.C.; Nguyen, P. T . Direct experimental evidence for the adsorption of 4- tert -butylpyridine and 2,2′-bipyridine on TiO 2 surface and their influence on dye-sensitized solar cells’ performance . Appl. Surf. Sci. , 2020 . 509 144878 .

Malmberg, S. M.; Parent, J. S.; Pratt, D. A.; Whitney, R. A . Isomerization and elimination reactions of brominated poly(isobutylene- co -isoprene) . Macromolecules , 2010 . 43 8456 .

Zhang, F.; Liu, W.; Wang, S.; Shi, H.; Liu, C.; Liang, L.; Pi, K . Engineering MXenes (Ti 3 C 2 T x ) surface with TiO 2 for enhancing anti-corrosion performance of coatings . Polymer , 2021 . 230 124086 .

Vinodhini, S. P.; Xavier, J. R . Evaluation of corrosion protection performance and mechanical properties of epoxy-triazole/graphene oxide nanocomposite coatings on mild steel . J. Mater. Sci. , 2021 . 56 7094 - 7110 . DOI: 10.1007/s10853-020-05636-w http://doi.org/10.1007/s10853-020-05636-w .

Cui, G.; Zhang, C.; Wang, A.; Zhou, X.; Xing, X.; Liu, J.; Li, Z.; Chen, Q.; Lu, Q . Research progress on self-healing polymer/graphene anticorrosion coatings . Prog. Org. Coat. , 2021 . 155 106231 .

Zaffora, A.; Di Franco, F.; Santamaria, M . Corrosion of stainless steel in food and pharmaceutical industry . Curr. Opin. Electrochem. , 2021 . 29 100760 DOI: 10.1016/j.coelec.2021.100760 http://doi.org/10.1016/j.coelec.2021.100760 .

Sah, S. P . Corrosion of 304 stainless steel in carbonates melt—a state of enhanced dissolution of corrosion products . Corros. Sci. , 2020 . 169 108535 DOI: 10.1016/j.corsci.2020.108535 http://doi.org/10.1016/j.corsci.2020.108535 .

Views

263

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

Soft-segment-engineered Self-healing Polyurethane for High-performance Electrorheological Elastomers and Capacitive Sensors

Molecular Engineering of Fluorine-containing Polyurethane Adhesives: Toughness and Self-healing Enhancement via Synergistic Disulfide-Zr4+ Coordination Bonds

On-demand Peelable UV-curable Adhesives with Superior Bonding Strength: Rational Molecular Engineering of Cohesion-adhesion Synergy

2026-9 Contents

Related Author

Dan-Min Wu

Chao-Qun Wu

De-Xiang Sun

Xiao-Dong Qi

Jing-Hui Yang

Yong Wang

Yan-Bo Yang

Yao Wan

Related Institution

Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Chemistry, Southwest Jiaotong University

Center for Advanced Structural Materials, State Key Lab of Metastable Materials Science and Technology, and College of Materials Science and Engineering, Yanshan University

Department of Polymer Science and Engineering, Inha University

School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Extreme Environment-tolerant Specialty Chemicals, University of Jinan

Shandong Institute of Non-Metallic Materials

⁰