

FOLLOWUS
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Research Institute of Polymer Materials, Shanghai Jiao Tong University, Shanghai 200240, China
ningren@sjtu.edu.cn (N.R.)
yzhu@sjtu.edu.cn (X.Y.Z.)
Received:15 May 2022,
Revised:2022-6-24,
Accepted:02 July 2022,
Online First:08 October 2022,
Published:01 February 2023
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Ge, M. Q.; Wang, X. Y.; Ren, N.; Tong, G. S.; Zhu, X. Y. Multi-polymerization: from simple to complex. Chinese J. Polym. Sci. 2023, 41, 179–186
Meng-Qi Ge, Xiang-Yi Wang, Ning Ren, et al. Multi-Polymerization: From Simple to Complex[J]. Chinese Journal of Polymer Science, 2023, 41(2): 179-186.
Ge, M. Q.; Wang, X. Y.; Ren, N.; Tong, G. S.; Zhu, X. Y. Multi-polymerization: from simple to complex. Chinese J. Polym. Sci. 2023, 41, 179–186 DOI: 10.1007/s10118-022-2836-8.
Meng-Qi Ge, Xiang-Yi Wang, Ning Ren, et al. Multi-Polymerization: From Simple to Complex[J]. Chinese Journal of Polymer Science, 2023, 41(2): 179-186. DOI: 10.1007/s10118-022-2836-8.
Three basic logical relationships between different mechanisms for multi-polymerization judged by the extent of mutual interactions: orthogonal
hybrid
and sequential.
Multi-polymerization in which different polymerization mechanisms are performed together serves as an essential synthetic methodology for the construction of polymers with specific architectures
constitutions
and properties. Compared to single mechanism polymerization
the scope of multi-polymerization is significantly broadened by both the available synthetic methods and the synthesized polymeric materials. In this mini-review
multi-polymerizations are categorized into three major types based on the logical relationship between different mechanisms: sequential/tandem polymerization
orthogonal/concurrent polymerization
and hybrid polymerization. Each type of multi-polymerization is briefly introduced and summarized. This mini-review also discussed the importance of mutual influence in multi-polymerization and the potential research interests in this field.
Zhu, Y.; Gao, L.; Li, Z.; Liu, B.; Zhang, Z.; Tong, H.; Qu, Y.; Quan, Y.; Zou, X.; Guo, K . Merging of cationic RAFT and radical RAFT polymerizations with ring-opening polymerizations for the synthesis of asymmetric ABCD type tetrablock copolymers in one pot . Polym. Chem. , 2021 . 12 4974 - 4985 . DOI: 10.1039/D1PY00971K http://doi.org/10.1039/D1PY00971K .
Song, B.; Li, X.; Qin, A.; Tang, B. Z . Direct conversion from carbon dioxide to luminescent poly( β -alkoxyacrylate)s via multicomponent tandem polymerization-induced emission . Macromolecules , 2021 . 54 9019 - 9026 . DOI: 10.1021/acs.macromol.1c01070 http://doi.org/10.1021/acs.macromol.1c01070 .
Sabury, S.; LaRiviere, B.; Ericson, M. N.; Kilbey, S. M . Nucleobase-functionalized poly(alkylthiophene)s: one-pot, sequential direct arylation polymerization and deprotection, and surface modification for oil-water separations . ACS Appl. Polym. Mater. , 2021 . 3 1012 - 1021 . DOI: 10.1021/acsapm.0c01281 http://doi.org/10.1021/acsapm.0c01281 .
Kaur, M.; Mayank; Bains, D.; Singh, G.; Kaur, N.; Singh, N . The solvent-free one-pot multicomponent tandem polymerization of 3,4-dihydropyrimidin-2(1 H )-ones (DHPMs) catalyzed by ionic-liquid@Fe 3 O 4 NPs: the development of polyamide gels . Polym. Chem. , 2021 . 12 1165 - 1175 . DOI: 10.1039/D0PY01769H http://doi.org/10.1039/D0PY01769H .
Song, B.; Qin, A. J.; Tang, B. Z . Green monomer of CO 2 and alkyne-based four-component tandem polymerization toward regio- and stereoregular poly(aminoacrylate)s . Chinese J. Polym. Sci. , 2021 . 39 51 - 59 . DOI: 10.1007/s10118-020-2454-2 http://doi.org/10.1007/s10118-020-2454-2 .
Luo, W.; Wang, Y.; Jin, Y.; Zhang, Z.; Wu, C . One-pot tandem ring-opening polymerization of N -sulfonyl aziridines and “click” chemistry to produce well-defined star-shaped polyaziridines . J. Polym. Sci. , 2020 . 58 2116 - 2125 . DOI: 10.1002/pol.20200154 http://doi.org/10.1002/pol.20200154 .
Zhou, L.; Xu, L.; Song, X.; Kang, S. M.; Liu, N.; Wu, Z. Q . Nickel(II)-catalyzed living polymerization of diazoacetates toward polycarbene homopolymer and polythiophene-block-polycarbene copolymers . Nat. Commun. , 2022 . 13 811 DOI: 10.1038/s41467-022-28475-6 http://doi.org/10.1038/s41467-022-28475-6 .
Tanaka, J.; Hakkinen, S.; Boeck, P. T.; Cong, Y.; Perrier, S.; Sheiko, S. S.; You, W . Orthogonal cationic and radical RAFT polymerizations to prepare bottlebrush polymers . Angew. Chem. Int. Ed. , 2020 . 59 7203 - 7208 . DOI: 10.1002/ange.202000700 http://doi.org/10.1002/ange.202000700 .
Zhang, C. J.; Zhang, X.; Zhang, X. H . Dual cooperative organocatalysts for one-pot synthesis of polyester-polythiocarbonate block copolymers from multiple monomers . Sci. China Chem. , 2020 . 63 1807 - 1814 . DOI: 10.1007/s11426-020-9816-4 http://doi.org/10.1007/s11426-020-9816-4 .
Theato, P. Multi-component and sequential reactions in polymer synthesis . Springer . Cham, Switzerland, 2015 .
Zhou, X. P.; Zhao, Y. J.; Wang, Y.; Xie, X. L. 2019 , CN Pat. 110511336.
Zhou, X. P.; Zhao, Y. J.; Wang, Y.; Xie, X. L. 2020 , CN Pat. 110894287.
Tang, B. Z.; Tian, W.; Hu, R. R.; Qin, A. J.; Zhao, Z. J. 2018 , CN Pat. 107759776.
Tonga, M.; Yesilbag Tonga, G.; Seber, G.; Gok, O.; Sanyal, A . Dendronized polystyrene via orthogonal double-click reactions . J. Polym. Sci., Part A: Polym. Chem. , 2013 . 51 5029 - 5037 . DOI: 10.1002/pola.26933 http://doi.org/10.1002/pola.26933 .
Tunca, U . Orthogonal multiple click reactions in synthetic polymer chemistry . J. Polym. Sci., Part A: Polym. Chem. , 2014 . 52 3147 - 3165 . DOI: 10.1002/pola.27379 http://doi.org/10.1002/pola.27379 .
Shahrokhinia, A.; Biswas, P.; Reuther, J. F . Orthogonal synthesis and modification of polymer materials . J. Polym. Sci. , 2021 . 59 1748 - 1786 . DOI: 10.1002/pol.20210345 http://doi.org/10.1002/pol.20210345 .
Le, D.; Montembault, V.; Pascual, S.; Legoupy, S.; Fontaine, L . An orthogonal modular approach to macromonomers using clickable cyclobutenyl derivatives and RAFT polymerization . Macromolecules , 2012 . 45 7758 - 7769 . DOI: 10.1021/ma3016163 http://doi.org/10.1021/ma3016163 .
Jia, Z.; Bell, C. A.; Monteiro, M. J . Directing the pathway of orthogonal 'click' reactions by modulating copper-catalytic activity . Chem. Commun. , 2011 . 47 4165 - 4167 . DOI: 10.1039/c0cc05478j http://doi.org/10.1039/c0cc05478j .
Han, D.; Tong, X.; Zhao, Y . One-pot synthesis of brush diblock copolymers through simultaneous ATRP and click coupling . Macromolecules , 2011 . 44 5531 - 5536 . DOI: 10.1021/ma200772j http://doi.org/10.1021/ma200772j .
Geng, J.; Lindqvist, J.; Mantovani, G.; Haddleton, D. M . Simultaneous copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) and living radical polymerization . Angew. Chem. Int. Ed. , 2008 . 47 4180 - 4183 . DOI: 10.1002/anie.200800179 http://doi.org/10.1002/anie.200800179 .
Gungor, E.; Hizal, G.; Tunca, U . One-pot double click reactions for the preparation of H-shaped ABCDE-type quintopolymer . J. Polym. Sci., Part A: Polym. Chem. , 2009 . 47 3409 - 3418 . DOI: 10.1002/pola.23421 http://doi.org/10.1002/pola.23421 .
Durmaz, H.; Hizal, G.; Tunca, U . Linear tetrablock quaterpolymers via triple click reactions, azide-alkyne, Diels-Alder, and nitroxide radical coupling in a one-pot fashion . J. Polym. Sci., Part A: Polym. Chem. , 2011 . 49 1962 - 1968 . DOI: 10.1002/pola.24622 http://doi.org/10.1002/pola.24622 .
Dag, A.; Durmaz, H.; Demir, E.; Hizal, G.; Tunca, U . Heterograft copolymers via double click reactions using one-pot technique . J. Polym. Sci., Part A: Polym. Chem. , 2008 . 46 6969 - 6977 . DOI: 10.1002/pola.23007 http://doi.org/10.1002/pola.23007 .
Li, Y. P.; Zhu, M.; Sa, Z. P.; Li, Y. X.; Wang. Y. Z.; Wang, J. Y. 2013 , CN Pat. 103242497.
Krappitz, T.; Jovic, K.; Feist, F.; Frisch, H.; Blinco, J. P.; Barner-Kowollik, C.; Feist, F.; Rigoglioso, V. P.; Boydston, A. J.; Barner-Kowollik, C . Hybrid photo-induced copolymerization of ring-strained and vinyl monomers utilizing metal-free ring-opening metathesis polymerization conditions . J. Am. Chem. Soc. , 2019 . 141 16605 - 16609 . DOI: 10.1021/jacs.9b09025 http://doi.org/10.1021/jacs.9b09025 .
Zhang, G. Z. . Hybrid copolymerization . Acta Polymerica Sinica (in Chinese) , 2018 . 668 - 673 . DOI: 10.11777/j.issn1000-3304.2018.18074 http://doi.org/10.11777/j.issn1000-3304.2018.18074 .
Jia, Z.; Li, G.; Zhu, Q.; Yan, D.; Zhu, X.; Chen, H.; Wu, J.; Tu, C.; Sun, J . Hybrid polymerization of vinyl and hetero-ring groups of glycidyl methacrylate resulting in thermoresponsive hyperbranched polymers displaying a wide range of lower critical solution temperatures . Chem. Eur. J. , 2009 . 15 7593 - 7600 . DOI: 10.1002/chem.200900345 http://doi.org/10.1002/chem.200900345 .
Pang, Y.; Liu, J. Y.; Wu, J. L.; Li, G. L.; Wang, R. B.; Su, Y.; He, P.; Zhu, X. Y.; Yan, D. Y.; Zhu, B. S . Synthesis, characterization, and in vitro evaluation of long-chain hyperbranched poly(ethylene glycol) as drug carrier . Bioconjugate Chem. , 2010 . 21 2093 - 2102 . DOI: 10.1021/bc100325a http://doi.org/10.1021/bc100325a .
Pang, Y.; Zhu, Q.; Liu, J. Y.; Wu, J. L.; Wang, R. B.; Chen, S. Y.; Zhu, X. Y.; Yan, D. Y.; Huang, W.; Zhu, B. S . Design and synthesis of cationic drug carrier based on hyperbranched poly(amine-ester)s . Biomacromolecules , 2010 . 11 575 - 582 . DOI: 10.1021/bm100007s http://doi.org/10.1021/bm100007s .
Li, G. L.; Liu, J. Y.; Pang, Y.; Wang, R. B.; Mao, L. M.; Yan, D. Y.; Zhu, X. Y.; Sun, J . Polymeric micelles with water-insoluble drug as hydrophobic moiety for drug delivery . Biomacromolecules , 2011 . 12 2016 - 2026 . DOI: 10.1021/bm200372s http://doi.org/10.1021/bm200372s .
Pang, Y.; Liu, J. Y.; Su, Y.; Wu, J. L.; Zhu, L. J.; Zhu, X. Y.; Yan, D. Y.; Zhu, B. S . Design and synthesis of thermo-responsive hyperbranched poly(aimine-ester)s as acid-sensitive drug carriers . Polym. Chem. , 2011 . 2 1661 - 1670 . DOI: 10.1039/C1PY00053E http://doi.org/10.1039/C1PY00053E .
Hu, M.; Chen, M. S.; Li, G. L.; Pang, Y.; Wang, D. L.; Wu, J. L.; Qiu, F.; Zhu, X. Y.; Sun, J . Biodegradable hyperbranched polyglycerol with ester linkages for drug delivery . Biomacromolecules , 2012 . 13 3552 - 3561 . DOI: 10.1021/bm300966d http://doi.org/10.1021/bm300966d .
Li, P. P.; Zhou, G. Y.; Zhu, X. Y.; Li, G. L.; Yan, P.; Shen, L. Y.; Xu, Q.; Hamblin, M. R . Photodynamic therapy with hyperbranched poly(ether-ester) chlorin(e6) nanoparticles on human tongue carcinoma CAL-27 cells . Photodiagnosis Photodyn. Ther. , 2012 . 9 76 - 82 . DOI: 10.1016/j.pdpdt.2011.08.001 http://doi.org/10.1016/j.pdpdt.2011.08.001 .
Solaro, R.; D'Antone, S.; Orsini, M.; Andruzzi, F.; Chiellini, E . Hybrid copolymerization of alkyl vinyl ethers with glycidyl ethers . J. Appl. Polym. Sci. , 1983 . 28 3651 - 3663 . DOI: 10.1002/app.1983.070281206 http://doi.org/10.1002/app.1983.070281206 .
Li, J. W.; Chen, M.; Zhang, Z.; Pan, C. Y.; Zhang, W. J.; Hong, C. Y . Hybrid copolymerization of acrylate and thiirane monomers mediated by trithiocarbonate . Polym. Chem. , 2022 . 13 402 - 410 . DOI: 10.1039/D1PY01031J http://doi.org/10.1039/D1PY01031J .
Xiao, W.; Liu, P.; Chen, Y.; Zhang, J.; Xu, J.; Xu, L . Hybrid copolymerization of ethylene oxide and tert -butyl methacrylate with organocatalyst . Polymers , 2021 . 13 2546 - 2555 . DOI: 10.3390/POLYM13152546 http://doi.org/10.3390/POLYM13152546 .
Yang, H. J.; Chai, C. Q.; Zuo, Y. K.; Huang, J. F.; Song, Y. Y.; Jiang, L.; Huang, W. Y.; Jiang, Q. M.; Xue, X. Q.; Jiang, B. B . Hybrid copolymerization via the combination of proton transfer and ring-opening polymerization . Chinese J. Polym. Sci. , 2020 . 38 231 - 239 . DOI: CNKI:SUN:GFZK.0.2020-03-004 http://doi.org/CNKI:SUN:GFZK.0.2020-03-004 .
Xia, L.; Zhang, Z.; Hong, C. Y.; You, Y. Z . Synthesis of copolymer via hybrid polymerization: from random to well-defined sequence . Eur. Polym. J. , 2020 . 122 109374 DOI: 10.1016/j.eurpolymj.2019.109374 http://doi.org/10.1016/j.eurpolymj.2019.109374 .
Yang, H.; Xu, J.; Pispas, S.; Zhang, G . Hybrid copolymerization of ε-caprolactone and methyl methacrylate . Macromolecules , 2012 . 45 3312 - 3317 . DOI: 10.1021/ma300291q http://doi.org/10.1021/ma300291q .
Okada, M.; Yamashita, Y.; Ishii, Y . Cationic copolymerization of 1,3-dioxolane with styrene . Makromol. Chem. , 1966 . 94 181 - 193 . DOI: 10.1002/macp.1966.020940120 http://doi.org/10.1002/macp.1966.020940120 .
Yu, L.; Wu, K. T.; Ding, J. D. 2020 , CN Pat., 111253558.
Song, P. F.; Ma, J. P.; Le, Y. L.; Ma, J. J.; Yuan, X. L.; Xi, Q.; Wu, X. 2022 , CN Pat. 114149571.
Zhu, X. Y.; Ren, N. Tong, G. S. 2019 , CN Pat. 109111564.
Kim, T. J.; Baek, J. W.; Moon, S. H.; Lee, H. J.; Park, K. L.; Bae, S. M.; Lee, J. C.; Lee, P. C.; Lee, B. Y . Polystyrene chain growth initiated from dialkylzinc for synthesis of polyolefin-polystyrene block copolymers . Polymers , 2020 . 12 537 - 550 . DOI: 10.3390/polym12030537 http://doi.org/10.3390/polym12030537 .
Denk, A.; Kernbichl, S.; Schaffer, A.; Kränzlein, M.; Pehl, T.; Rieger, B . Heteronuclear, monomer-selective Zn/Y catalyst combines copolymerization of epoxides and CO 2 with group-transfer polymerization of michael-type monomers . ACS Macro Lett. , 2020 . 9 571 - 575 . DOI: 10.1021/acsmacrolett.9b01025 http://doi.org/10.1021/acsmacrolett.9b01025 .
Lei, L.; Li, F.; Zhao, H.; Wang, Y . One-pot synthesis of block copolymers by ring-opening polymerization and ultraviolet light-induced ATRP at ambient temperature . J. Polym. Sci., Part A: Polym. Chem. , 2018 . 56 699 - 704 . DOI: 10.1002/pola.28940 http://doi.org/10.1002/pola.28940 .
Petersen, S. R.; Wilson, J. A.; Becker, M. L . Versatile ring-opening copolymerization and postprinting functionalization of lactone and poly(propylene fumarate) block copolymers: resorbable building blocks for additive manufacturing . Macromolecules , 2018 . 51 6202 - 6208 . DOI: 10.1021/acs.macromol.8b01372 http://doi.org/10.1021/acs.macromol.8b01372 .
Trindade, S. G.; Bortolotto, T.; Ciolino, A. E.; Schmidt, V.; Giacomelli, C . One-pot two-step (first ROP, then SET-LRP) synthesis of polycaprolactone-polyacrylate star block copolymers . Macromol. Chem. Phys. , 2018 . 219 1700486 DOI: 10.1002/macp.201700486 http://doi.org/10.1002/macp.201700486 .
Zhao, J . P.; Pahovnik, D.; Gnanou, Y.; Hadjichristidis, N. A "catalyst switch" strategy for the sequential metal-free polymerization of epoxides and cyclic esters/carbonate . Macromolecules , 2014 . 47 3814 - 3822 . DOI: 10.1021/ma500830v http://doi.org/10.1021/ma500830v .
Lu, P.; Boydston, A. J . Integration of metal-free ring-opening metathesis polymerization and organocatalyzed ring-opening polymerization through a bifunctional initiator . Polym. Chem. , 2019 . 10 2975 - 2979 . DOI: 10.1039/C8PY01417E http://doi.org/10.1039/C8PY01417E .
Jiang, Z. Q.; Xue, Y. X.; Chen, J. L.; Yu, Z. P.; Liu, N.; Yin, J.; Zhu, Y. Y.; Wu, Z. Q . One-pot synthesis of brush copolymers bearing stereoregular helical polyisocyanides as side chains through tandem catalysis . Macromolecules , 2014 . 48 81 - 89 . DOI: 10.1021/ma502283f http://doi.org/10.1021/ma502283f .
Kakuchi, R . The dawn of polymer chemistry based on multicomponent reactions . Polym. J. , 2019 . 51 945 - 953 . DOI: 10.1038/s41428-019-0209-0 http://doi.org/10.1038/s41428-019-0209-0 .
Kubo, T.; Easterling, C. P.; Olson, R. A.; Sumerlin, B. S . Synthesis of multifunctional homopolymers via sequential post-polymerization reactions . Polym. Chem. , 2018 . 9 4605 - 4610 . DOI: 10.1039/C8PY01055B http://doi.org/10.1039/C8PY01055B .
Lee, D. C.; Lamm, R. J.; Prossnitz, A. N.; Boydston, A. J.; Pun, S. H . Dual polymerizations: untapped potential for biomaterials . Adv. Healthc. Mater. , 2019 . 8 e1800861 DOI: 10.1002/adhm.201800861 http://doi.org/10.1002/adhm.201800861 .
Phan, H.; Kortsen, K.; Englezou, G.; Couturaud, B.; Nedoma, A. J.; Pearce, A. K.; Taresco, V . Functional initiators for the ring-opening polymerization of polyesters and polycarbonates: an overview . J. Polym. Sci. , 2020 . 58 1911 - 1923 . DOI: 10.1002/pol.20200313 http://doi.org/10.1002/pol.20200313 .
Robert, C.; Thomas, C. M . Tandem catalysis: a new approach to polymers . Chem. Soc. Rev. , 2013 . 42 9392 - 9402 . DOI: 10.1039/c3cs60287g http://doi.org/10.1039/c3cs60287g .
Xia, L.; Zhang, Z.; You, Y. Z . Synthesis of sequence-controlled polymers via sequential multicomponent reactions and interconvertible hybrid copolymerizations . Polym. J. , 2019 . 52 33 - 43 . DOI: 10.1038/s41428-019-0266-4 http://doi.org/10.1038/s41428-019-0266-4 .
Wang, Y.; Ren, R.; Ling, J.; Sun, W.; Shen, Z . One-pot “grafting-from” synthesis of amphiphilic bottlebrush block copolymers containing PLA and PVP side chains via tandem ROP and RAFT polymerization . Polymer , 2018 . 138 378 - 386 . DOI: 10.1016/j.polymer.2018.01.071 http://doi.org/10.1016/j.polymer.2018.01.071 .
Yildirim, I.; Sungur, P.; Crecelius-Vitz, A. C.; Yildirim, T.; Kalden, D.; Hoeppener, S.; Westerhausen, M.; Weber, C.; Schubert, U. S . One-pot synthesis of PLA- b -PHEA via sequential ROP and RAFT polymerizations . Polym. Chem. , 2017 . 8 6086 - 6098 . DOI: 10.1039/C7PY01176H http://doi.org/10.1039/C7PY01176H .
Dong, H.; Zhu, Y.; Li, Z.; Xu, J.; Liu, J.; Xu, S.; Wang, H.; Gao, Y.; Guo, K . Dual switching in both RAFT and ROP for generation of asymmetric A 2 A 1 B 1 B 2 type tetrablock quaterpolymers . Macromolecules , 2017 . 50 9295 - 9306 . DOI: 10.1021/acs.macromol.7b01784 http://doi.org/10.1021/acs.macromol.7b01784 .
Diaz, C.; Tomković, T.; Goonesinghe, C.; Hatzikiriakos, S. G.; Mehrkhodavandi, P . One-pot synthesis of oxygenated block copolymers by polymerization of epoxides and lactide using cationic indium complexes . Macromolecules , 2020 . 53 8819 - 8828 . DOI: 10.1021/acs.macromol.0c01276 http://doi.org/10.1021/acs.macromol.0c01276 .
Fu, C.; Xu, J.; Kokotovic, M.; Boyer, C . One-pot synthesis of block copolymers by orthogonal ring-opening polymerization and PET-RAFT polymerization at ambient temperature . ACS Macro Lett. , 2016 . 5 444 - 449 . DOI: 10.1021/acsmacrolett.6b00121 http://doi.org/10.1021/acsmacrolett.6b00121 .
Ma, Y.; Kottisch, V.; McLoughlin, E. A.; Rouse, Z. W.; Supej, M. J.; Baker, S. P.; Fors, B. P . Photoswitching cationic and radical polymerizations: spatiotemporal control of thermoset properties . J. Am. Chem. Soc. , 2021 . 143 21200 - 21205 . DOI: 10.1021/jacs.1c09523 http://doi.org/10.1021/jacs.1c09523 .
Kottisch, V.; Michaudel, Q.; Fors, B. P . Photocontrolled interconversion of cationic and radical polymerizations . J. Am. Chem. Soc. , 2017 . 139 10665 - 10668 . DOI: 10.1021/jacs.7b06661 http://doi.org/10.1021/jacs.7b06661 .
Nikolaev, A.; Lu, Z.; Chakraborty, A.; Sepunaru, L.; de Alaniz, J. R . Interconvertible living radical and cationic polymerization using a dual photoelectrochemical catalyst . J. Am. Chem. Soc. , 2021 . 143 12278 - 12285 . DOI: 10.1021/jacs.1c05431 http://doi.org/10.1021/jacs.1c05431 .
Mecerreyes, D.; Moineau, G.; Dubois, P.; Jérôme, R.; Hedrick, J. L.; Hawker, C. J.; Malmström, E. E.; Trollsas, M . Simultaneous dual living polymerizations: a novel one-step approach to block and graft copolymers . Angew. Chem. Int. Ed. , 1998 . 37 1274 - 1276 . DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1274::AID-ANIE1274>3.0.CO;2-J http://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1274::AID-ANIE1274>3.0.CO;2-J .
Xu, B.; Feng, C.; Huang, X . A versatile platform for precise synthesis of asymmetric molecular brush in one shot . Nat. Commun. , 2017 . 8 333 - 340 . DOI: 10.1038/s41467-017-00365-2 http://doi.org/10.1038/s41467-017-00365-2 .
Zhang, W.; Shen, S.; Zhang, Z.; Huang, Y.; Weng, Y.; Chen, G . Using one photoredox catalyst to simultaneously mediate two different polymerizations for photo-triggered multi-component orthogonal polymerizations . Macromol. Rapid Commun. , 2020 . 41 2000373 DOI: 10.1002/marc.202000373 http://doi.org/10.1002/marc.202000373 .
Xue, W.; Wang, J.; Wen, M.; Chen, G.; Zhang, W . Integration of CuAAC polymerization and controlled radical polymerization into electron transfer mediated "click-radical" concurrent polymerization . Macromol. Rapid Commun. , 2017 . 38 1600733 DOI: 10.1002/marc.201600733 http://doi.org/10.1002/marc.201600733 .
Durmaz, H.; Dag, A.; Altintas, O.; Erdogan, T.; Hizal, G.; Tunca, U . One-pot synthesis of ABC type triblock copolymers via in situ click [3+2] and Diels-Alder [4+2] reactions . Macromolecules , 2006 . 40 191 - 198 . DOI: 10.1021/ma061819l http://doi.org/10.1021/ma061819l .
Ren, N.; Zhu, X. Y . Hybrid polymerization of ring-opening metathesis and cross-metathesis for polyolefins with tunable architectures . Macromolecules , 2018 . 51 9555 - 9561 . DOI: 10.1021/acs.macromol.8b02135 http://doi.org/10.1021/acs.macromol.8b02135 .
Ren, N.; Zhu, X. Y . Synthesis of hyperbranched polyolefins and polyethylenes via ADMET of monomers bearing non-selective olefins . Polym. Chem. , 2019 . 10 6174 - 6182 . DOI: 10.1039/C9PY01499C http://doi.org/10.1039/C9PY01499C .
Huo, M.; Tong, G. S.; Zhang, C. Y.; Zhu, X. Y . Hybrid polymerization of reversible complexation mediated polymerization (RCMP) and reversible addition-fragmentation chain-transfer (RAFT) polymerization . Macromolecules , 2020 . 53 9345 - 9352 . DOI: 10.1021/acs.macromol.0c01872 http://doi.org/10.1021/acs.macromol.0c01872 .
Chen, G.; Xia, L.; Wang, F.; Zhang, Z.; You, Y. Z . Recent progress in the construction of polymers with advanced chain structures via hybrid, switchable, and cascade chain-growth polymerizations . Polym. Chem. , 2021 . 12 3740 - 3752 . DOI: 10.1039/D1PY00274K http://doi.org/10.1039/D1PY00274K .
Ren, N.; Ge, M. Q.; Tong, G. S.; Zhu, X. Y . Advancing from unimechanism polymerization to multimechanism polymerization: binary polymerization . Sci. China Chem. , 2022 . 65 602 - 610 . DOI: 10.1007/s11426-021-1167-2 http://doi.org/10.1007/s11426-021-1167-2 .
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