Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings

Rong Ling; Shao-Hua Wu; Chun-Cheng Li; Yao-Nan Xiao; Jia-Jian Liu; Bo Zhang

doi:10.1007/s10118-022-2834-x

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Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings

RESEARCH ARTICLE | Updated：2023-01-06

- Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings
- Chinese Journal of Polymer Science Vol. 41, Issue 2, Pages: 306-314(2023)
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing 100190, China
  b.University of the Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  wushaohua12@iccas.ac.cn (S.H.W.)
  lichch@iccas.ac.cn (C.C.L.)
- Funds：
- DOI：10.1007/s10118-022-2834-x
  CLC：
- Received：09 May 2022，
  
  Revised：2022-6-22，
  
  Accepted：29 June 2022，
  
  Online First：08 October 2022，
  
  Published：01 February 2023
- Accepted：
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Ling, R.; Wu, S. H.; Li, C. C.; Xiao, Y. N.; Liu, J. J.; Zhang, B. Environmentally friendly sizing strategy for PBO fiber-reinforced composites through building carbon nanosphere coatings. Chinese J. Polym. Sci. 2023, 41, 306–314

Rong Ling, Shao-Hua Wu, Chun-Cheng Li, et al. Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings[J]. Chinese Journal of Polymer Science, 2023, 41(2): 306-314.
Ling, R.; Wu, S. H.; Li, C. C.; Xiao, Y. N.; Liu, J. J.; Zhang, B. Environmentally friendly sizing strategy for PBO fiber-reinforced composites through building carbon nanosphere coatings. Chinese J. Polym. Sci. 2023, 41, 306–314 DOI： 10.1007/s10118-022-2834-x.

Rong Ling, Shao-Hua Wu, Chun-Cheng Li, et al. Environmentally Friendly Sizing Strategy for PBO Fiber-reinforced Composites through Building Carbon Nanosphere Coatings[J]. Chinese Journal of Polymer Science, 2023, 41(2): 306-314. DOI： 10.1007/s10118-022-2834-x.

摘要

A functional carbon nanosphere coating with high activity was constructed on the surface of PBO fibers by treatment with an environmentally friendly and industrially scalable waterborne sizing agent. The sized PBO fibers not only show significantly improved interfacial properties

but also retain the excellent mechanical properties.

Abstract

Sizing treatment has shown great potential in improving the interfacial properties of poly(

-phenylene benzodioxazole) (PBO) fiber-reinforced composites

but is severely limited due to the use of flammable and explosive organic solvents. Herein

a new high-efficiency waterborne sizing agent has been developed by using functionalized carbon nanospheres (CNSs) as a nano-reinforcement. Due to abundant oxygen-containing groups

the CNSs greatly improves the surface activity

wettability

and roughness of the PBO fibers. As a result

the interfacial shear strength of the CNSs sized fiber-reinforced composite increases by 79.6% compared with that of the pristine fiber-reinforced composite. Moreover

the excellent mechanical and thermal properties of the PBO fibers remain almost unchanged after sizing treatment. Thus

this work provides an environmentally friendly and scalable method for constructing a strong interface between the PBO fibers and the matrix resins

which makes sense in promoting the application of PBO fiber-reinforced composites in aerospace and military industries.

关键词

Keywords

references

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