Strain Softening of Styrene-Isoprene-Styrene Copolymers under Large Amplitude Oscillatory Shear for Clarifying Payne Effect in Rubbers and Their Nanocomposites

Xin-Peng Fan; Yi-Hu Song; Qiang Zheng; Wan-Jie Wang

doi:10.1007/s10118-022-2832-z

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Strain Softening of Styrene-Isoprene-Styrene Copolymers under Large Amplitude Oscillatory Shear for Clarifying Payne Effect in Rubbers and Their Nanocomposites

RESEARCH ARTICLE | Updated：2022-12-19

- Strain Softening of Styrene-Isoprene-Styrene Copolymers under Large Amplitude Oscillatory Shear for Clarifying Payne Effect in Rubbers and Their Nanocomposites
- Chinese Journal of Polymer Science Vol. 41, Issue 1, Pages: 153-165(2023)
- Affiliations：
  
  a.MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.Shanxi-Zheda Institute of New Materials and Chemical Engineering, Taiyuan 030000, China
  c.College of Materials Science and Engineering, Henan Key Laboratory of Advanced Nylon Materials and Application, Zhengzhou University, Zhengzhou 450001, China
- Author bio：
  
  s_yh0411@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-022-2832-z
  CLC：
- Received：03 May 2022，
  
  Revised：2022-6-22，
  
  Accepted：11 July 2022，
  
  Online First：08 October 2022，
  
  Published：01 January 2023
- Accepted：
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Fan, X. P.; Song, Y. H.; Zheng, Q.; Wang, W. J. Strain softening of styrene-isoprene-styrene copolymers under large amplitude oscillatory shear for clarifying Payne effect in rubbers and their nanocomposites. Chinese J. Polym. Sci. 2023, 41, 153–165

Xin-Peng Fan, Yi-Hu Song, Qiang Zheng, et al. Strain Softening of Styrene-Isoprene-Styrene Copolymers under Large Amplitude Oscillatory Shear for Clarifying Payne Effect in Rubbers and Their Nanocomposites[J]. Chinese Journal of Polymer Science, 2023, 41(1): 153-165.
Fan, X. P.; Song, Y. H.; Zheng, Q.; Wang, W. J. Strain softening of styrene-isoprene-styrene copolymers under large amplitude oscillatory shear for clarifying Payne effect in rubbers and their nanocomposites. Chinese J. Polym. Sci. 2023, 41, 153–165 DOI： 10.1007/s10118-022-2832-z.

Xin-Peng Fan, Yi-Hu Song, Qiang Zheng, et al. Strain Softening of Styrene-Isoprene-Styrene Copolymers under Large Amplitude Oscillatory Shear for Clarifying Payne Effect in Rubbers and Their Nanocomposites[J]. Chinese Journal of Polymer Science, 2023, 41(1): 153-165. DOI： 10.1007/s10118-022-2832-z.

摘要

A model study was performed to investigate the Payne effect of rubbers by using styrene-isoprene-styrene (SIS) copolymers. It was found that the normalized critical softening stress scales with density of elastic active strands (EANS) for copolymers rubbers and rubber nanocomposites.

Abstract

To illustrate mechanisms of Payne effect in rubbers and their nanocomposites experiencing large amplitude oscillatory shear (LAOS)

comparison studies were performed in styrene-isoprene-styrene (SIS) copolymers and their selectively crosslinked materials at temperatures below and above glass transition temperature of the polystyrene (PS) phase. It was found that under periodic dynamic shear

the strain softening is reversible when the polyisoprene (PI) phase

either crosslinked or not

is restricted by hard PS domains but it shows hysteresis once the PS domains disassociate. The strain softening can happen at the time scale of intrinsic Rouse relaxation of elastically active network strands. Critical stress of strain softening scales with number density of elastically active network strands

a simple relation being verified not only in the selectively crosslinked SIS copolymers but also in PI gum vulcanizates and carbon black filled PI compounds. Payne effect is traditionally used to term strain softening of highly filled rubber vulcanizates under LAOS deformation while evidenced herein is that the Payne effect of highly filled rubber vulcanizates shares the mechanism being common to the strain softening of SIS copolymers.

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references

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