Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability

Zhen-Hua Xie; Zi-Xin Huang; Ze-Ping Zhang; Min-Zhi Rong; Ming-Qiu Zhang

doi:10.1007/s10118-022-2820-3

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Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability

RESEARCH ARTICLE | Updated：2022-12-19

- Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability
- Chinese Journal of Polymer Science Vol. 41, Issue 1, Pages: 95-107(2023)
- Affiliations：
  
  a.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, GD HPPC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China
  b.Institute of High Energy Physics, Chinese Academy of Sciences (CAS), Beijing 100049, China
  c.Spallation Neutron Source Science Center, Dongguan 523803, China
- Author bio：
  
  zhangzp8@mail.sysu.edu.cn (Z.P.Z.)
  cesrmz@mail.sysu.edu.cn (M.Z.R.)
  ceszmq@mail.sysu.edu.cn (M.Q.Z.)
- Funds：
- DOI：10.1007/s10118-022-2820-3
  CLC：
- Received：18 April 2022，
  
  Revised：2022-5-17，
  
  Accepted：02 June 2022，
  
  Online First：26 September 2022，
  
  Published：01 January 2023
- Accepted：
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Xie, Z. H.; Huang, Z. X.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Imparting pulley effect and self-healability to cathode binder of Li-S battery for improvement of the cycling stability. Chinese J. Polym. Sci. 2023, 41, 95–107

Zhen-Hua Xie, Zi-Xin Huang, Ze-Ping Zhang, et al. Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability[J]. Chinese Journal of Polymer Science, 2023, 41(1): 95-107.
Xie, Z. H.; Huang, Z. X.; Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Imparting pulley effect and self-healability to cathode binder of Li-S battery for improvement of the cycling stability. Chinese J. Polym. Sci. 2023, 41, 95–107 DOI： 10.1007/s10118-022-2820-3.

Zhen-Hua Xie, Zi-Xin Huang, Ze-Ping Zhang, et al. Imparting Pulley Effect and Self-healability to Cathode Binder of Li-S Battery for Improvement of the Cycling Stability[J]. Chinese Journal of Polymer Science, 2023, 41(1): 95-107. DOI： 10.1007/s10118-022-2820-3.

摘要

Polyacrylic acid crosslinked by cationic hydroxypropyl polyrotaxane

via

dynamically reversible boronic ester bonds is used as a novel binder in sulfur cathode. The self-healable binder can effectively maintain structural integrity of the sulfur cathode and suppress the shuttle effect

and hence endows the sulfur cathode with superior electrochemical properties.

Abstract

To construct structurally stable sulfur cathode of Li-S battery with improved cycling performance

poly(acrylic acid) (PAA) crosslinked by cationic hydroxypropyl polyrotaxane (HPRN

)

via

dynamically reversible boronic ester bonds is synthesized and serves as the cathode binder. The smart polymer networks offer multifunction including buffering the volume change of the cathode during charge/discharge through the pulley effect of polyrotaxanes (PR)

suppressing the shuttle effect by adsorption of polysulfide using the plentiful carboxyl

hydroxyl and quaternary ammonium cationic groups

and self-healing the micro-damages to ensure stable conduction pathways of the electrode. As a result

the Li-S batteries based on this novel multifunctional binder and simple commercial sulfur/carbon composites cathode exhibit excellent specific capacity and cycling stability. In particular

the specific capacity decay per cycle of the cell is only 0.064% along with high Coulombic efficiency after 550 cycles at 1.0 C

which is superior to most of the reported binders. Even under high sulfur loading

moreover

the cathode can deliver superior areal capacity and cycling stability. This proposed binder provides a new way for the design of high-stability sulfur cathodes.

关键词

Keywords

references

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