Controllable Synthesis of a Well-defined Polypropylene grafted Silica Nanoparticles and Its Effect on Crystallization Behavior of Polypropylene

Wei-Long Ju; Shao-Fan Li; Yun-Lan Su; Du-Jin Wang

doi:10.1007/s10118-022-2756-7

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Controllable Synthesis of a Well-defined Polypropylene grafted Silica Nanoparticles and Its Effect on Crystallization Behavior of Polypropylene

RESEARCH ARTICLE | Updated：2022-10-25

- Controllable Synthesis of a Well-defined Polypropylene grafted Silica Nanoparticles and Its Effect on Crystallization Behavior of Polypropylene
- Chinese Journal of Polymer Science Vol. 40, Issue 11, Pages: 1411-1421(2022)
- Affiliations：
  
  a.Key Laboratory of Engineering Plastics, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  ylsu@iccas.ac.cn
- Funds：
- DOI：10.1007/s10118-022-2756-7
  CLC：
- Received：28 February 2022，
  
  Revised：2022-3-31，
  
  Accepted：07 April 2022，
  
  Online First：20 July 2022，
  
  Published：01 November 2022
- Accepted：
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Ju, W. L.; Li, S. F.; Su, Y. L.; Wang, D. J. Controllable synthesis of a well-defined polypropylene grafted silica nanoparticles and its effect on crystallization behavior of polypropylene. Chinese J. Polym. Sci. 2022, 40, 1411–1421

Wei-Long Ju, Shao-Fan Li, Yun-Lan Su, et al. Controllable Synthesis of a Well-defined Polypropylene grafted Silica Nanoparticles and Its Effect on Crystallization Behavior of Polypropylene[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1411-1421.
Ju, W. L.; Li, S. F.; Su, Y. L.; Wang, D. J. Controllable synthesis of a well-defined polypropylene grafted silica nanoparticles and its effect on crystallization behavior of polypropylene. Chinese J. Polym. Sci. 2022, 40, 1411–1421 DOI： 10.1007/s10118-022-2756-7.

Wei-Long Ju, Shao-Fan Li, Yun-Lan Su, et al. Controllable Synthesis of a Well-defined Polypropylene grafted Silica Nanoparticles and Its Effect on Crystallization Behavior of Polypropylene[J]. Chinese Journal of Polymer Science, 2022, 40(11): 1411-1421. DOI： 10.1007/s10118-022-2756-7.

摘要

Well-defined polypropylene grafted silica nanoparticles (PP-g-SiO

) with controlled grafting density were prepared by “grafting-to” method

which were dispersed in PP matrix to prepare nanocomposites via solution blending. The PP-g-SiO

with high molecular weight of grafted chains provided a great number of heterogeneous nucleation sites

which significantly improved the crystallization abilities of nanocomposites.

Abstract

Well-defined polypropylene grafted silica nanoparticles (PP-

-SiO

) were prepared through the reaction of maleic anhydride grafted polypropylene (PP-

-MAH) with amino-functionalized silica (SiO

-NH

) by the 'grafting-to' method. The grafting density of PP-

-SiO

is found to be controlled by the concentration of silane coupling agent 3-[2-(2-aminoethylamino) ethyl amino] propyl trimethoxy silane (TAMS). The maximum grafting density of grafted PP-

-MAH chains with molecular weight of 9100 g/mol could reach 0.34 chains/nm

when the critical concentration of TAMS was 0.0194 mol/L. The critical concentration of TAMS can be explained by the maximum amounts of primary amino groups

which can totally react with PP-

-MAH on the surface of SiO

-NH

when the silane monolayer is formed. The synthesized PP-

-SiO

with different molecular weights was mixed with PP by solution mixing to form a series of nanocomposites. The crystallization temperature (

) of nanocomposites increased significantly with the particle loading. The PP-

-SiO

with high molecular weight of grafted chains exhibits a high nucleation ability at 1 wt% nanoparticle loading in PP/PP-

-SiO

nanocomposites. In summary

we provide an effective method to synthesize the well-defined PP-

-SiO

with controlled grafting density

which shows excellent nucleation ability.

关键词

Keywords

references

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