Cationic CO<sub>2</sub>-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance

Hong-Ming Zhang; Guang-Ping Han; Wan-Li Cheng; Shun-Jie Liu; Xian-Hong Wang

doi:10.1007/s10118-022-2738-9

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Cationic CO₂-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance

RESEARCH ARTICLE | Updated：2022-09-23

- Cationic CO₂-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance
- Chinese Journal of Polymer Science Vol. 40, Issue 10, Pages: 1183-1192(2022)
- Affiliations：
  
  a.Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China
  b.Key Laboratory of Polymer Ecomaterial, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  nefucwl@nefu.edu.cn (W.L.C.)
  xhwang@ciac.ac.cn (X.H.W.)
- Funds：
- DOI：10.1007/s10118-022-2738-9
  CLC：
- Received：20 February 2022，
  
  Revised：2022-4-29，
  
  Accepted：08 May 2022，
  
  Online First：20 July 2022，
  
  Published：01 October 2022
- Accepted：
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Zhang, H. M.; Han, G. P.; Cheng, W. L.; Liu, S. J.; Wang, X. H. Cationic CO₂-based waterborne polyurethane with high solid content and excellent ageing resistance. Chinese J. Polym. Sci. 2022, 40, 1183–1192 DOI: 10.1007/s10118-022-2738-9.

Hong-Ming Zhang, Guang-Ping Han, Wan-Li Cheng, et al. Cationic CO₂-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1183-1192. DOI: 10.1007/s10118-022-2738-9.
Zhang, H. M.; Han, G. P.; Cheng, W. L.; Liu, S. J.; Wang, X. H. Cationic CO₂-based waterborne polyurethane with high solid content and excellent ageing resistance. Chinese J. Polym. Sci. 2022, 40, 1183–1192 DOI: 10.1007/s10118-022-2738-9. DOI：

Hong-Ming Zhang, Guang-Ping Han, Wan-Li Cheng, et al. Cationic CO₂-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance[J]. Chinese Journal of Polymer Science, 2022, 40(10): 1183-1192. DOI: 10.1007/s10118-022-2738-9. DOI：

摘要

High solid content (52%) CO

-based cationic waterborne polyurethane (CO

-CWPUs) is prepared using CO

as raw material. Compared with polybutylene adipate glycol based cationic waterborne polyurethane (PBA-CWPU)

-CWPU shows outstanding water/hydrolysis/oxidation ageing resistances

due to its synergistic effect from carbonate and ether groups of main chain structure.

Abstract

High solid content CO

-based cationic waterborne polyurethanes (CWPUs) were prepared using CO

-polyols as soft segment and

-methyl diethanolamine (MDEA) as hydrophilic group. The resulting stable aqueous dispersion displayed a high solid content of 52% with a low MDEA loading of 3.52 wt%. This novel structural CWPU can provide excellent adhesive strength

whose T-peel strength could reach 173.48 N/5cm

20% higher than that of ester-based cationic waterborne polyurethane (87.55 N/5cm). The CO

-based CWPU film showed only 2 wt% swelling percentage after 240 min immersion in water

and no change was observed during its immersion in 5 wt% sodium hydroxide solution. The tensile strength of CO

-WPUs dropped slowly to 91.2% after 480 min immersion in a 5 wt% sodium hydroxide solution

whereas that of ester-based CWPUs dropped quickly to 32% after 240 min and their mechanical properties were lost after 360 min immersion. Meanwhile

the retention of the tensile strength of the CO

-CWPUs was 81.5% even after 720 min immersion in 10 wt% H

solution

while it was only

. 38% for the ester-based CWPUs. These results indicated that the cationic CO

-based CWPU may be promising waterborne adhesive with outstanding ageing resistance due to its synergistic effect from carbonate and ether groups of CO

-polyol structure.

关键词

Keywords

references

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Cationic CO2-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance

DOI：10.1007/s10118-022-2738-9

摘要

Abstract

关键词

Keywords

references

Cationic CO₂-based Waterborne Polyurethane with High Solid Content and Excellent Ageing Resistance