Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-<italic style="font-style: italic">ran</italic>-propylene fumarate)

Xue-Wei Wei; Xin-Xin Zhao; Yi Li; Xiao-Yu Meng; Qiong Zhou; Hai-Mu Ye

doi:10.1007/s10118-022-2717-1

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Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-ran-propylene fumarate)

RESEARCH ARTICLE | Updated：2022-05-24

- Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-ran-propylene fumarate)
- Chinese Journal of Polymer Science Vol. 40, Issue 6, Pages: 602-610(2022)
- Affiliations：
  
  Department of Materials Science and Engineering, College of New Energy and Materials, China University of Petroleum, Beijing 102249, China
- Author bio：
  
  yehaimu@cup.edu.cn
- Funds：
- DOI：10.1007/s10118-022-2717-1
  CLC：
- Received：22 December 2021，
  
  Revised：2022-1-26，
  
  Accepted：07 February 2022，
  
  Online First：20 April 2022，
  
  Published：01 June 2022
- Accepted：
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Wei, X. W.; Zhao, X. X.; Li, Y.; Meng, X. Y.; Zhou, Q.; Ye, H. M. Distinctive polymorphism-like isodimorphism in poly(propylene succinate-ran-propylene fumarate). Chinese J. Polym. Sci. 2022, 40, 602–610

Xue-Wei Wei, Xin-Xin Zhao, Yi Li, et al. Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-ran-propylene fumarate)[J]. Chinese Journal of Polymer Science, 2022, 40(6): 602-610. DOI: 10.1007/s10118-022-2717-1.
Wei, X. W.; Zhao, X. X.; Li, Y.; Meng, X. Y.; Zhou, Q.; Ye, H. M. Distinctive polymorphism-like isodimorphism in poly(propylene succinate-ran-propylene fumarate). Chinese J. Polym. Sci. 2022, 40, 602–610 DOI： 10.1007/s10118-022-2717-1.

Xue-Wei Wei, Xin-Xin Zhao, Yi Li, et al. Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-ran-propylene fumarate)[J]. Chinese Journal of Polymer Science, 2022, 40(6): 602-610. DOI: 10.1007/s10118-022-2717-1. DOI：

摘要

In this study we have discovered a novel co-crystallization manner of random copolymer of poly(propylene succinate-ran-propylene fumarate)

which is belonging to crystallographic isodimorphism but intriguingly displays isomorphic thermal properties. The copolymers combine the advantages of both isodimorphism and isomorphism

leading to new performance design of polymer materials.

Abstract

Co-crystallization of different monomeric units fundamentally contributes to the versatile and tunable performance of random copolymers. At present

the crystallization manners of random binary copolymers have been divided into three categories: isomorphism

isodimorphism and comonomer exclusion. Each category

however

has its own advantages and disadvantages. Therefore

it is challenging to design and prepare random copolymer sharing the advantages of isomorphism and isodimorphism through a new co-crystallization manner beyond the ones already exist. On the basis of previous study on poly(alkylene succinate-

ran

-alkylene fumarate) whose co-crystallization can be extensively and finely regulated by simply varying the chemical structure of alkylene

random copolymers of poly(propylene succinate-

ran

-propylene fumarate) (PPSF) are synthesized using 1

3-propanediol as the diol source. The thermal properties and crystal structure of PPSF are investigated

and

intriguingly

it is proved that PPSF is an isodimorphism system while displays similar composition-dependent thermal properties and crystallinity as isomorphism. That is

PPSF exhibits a novel co-crystallization behavior that has rarely been discovered

which would combine the advantages of both isomorphism and isodimorphism. Consequently

PPSF could be termed as a new-type

special composition-dependent polymorphism. Besides

the altering of PPS-like to PPF-like crystal structure of PPSF when changing chain composition has been proved to originate from the shift of dominant inter-segment interaction from van der Waals forces to strong hydrogen-bonding interaction. This work enriches the co-crystallization manner of random copolymers

leading to more diverse performance design of polymer materials.

关键词

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references

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⁰

Distinctive Polymorphism-like Isodimorphism in Poly(propylene succinate-ran-propylene fumarate)

DOI：10.1007/s10118-022-2717-1

摘要

Abstract

关键词

Keywords

references