Self-nucleation of Patterned Polymer Thin Films Defined by Soft Lithography

Ze-Qian Wang; Yi-Meng Wang; Xing-Yu Wang; Bing-Hua Wang; Jing-Bo Chen; Chang-Yu Shen; Bin Zhang

doi:10.1007/s10118-022-2709-1

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Self-nucleation of Patterned Polymer Thin Films Defined by Soft Lithography

RESEARCH ARTICLE | Updated：2022-05-24

- Self-nucleation of Patterned Polymer Thin Films Defined by Soft Lithography
- Chinese Journal of Polymer Science Vol. 40, Issue 6, Pages: 651-657(2022)
- Affiliations：
  
  School of Materials Science & Engineering, Zhengzhou University, Zhengzhou 450002, China
- Author bio：
  
  chenjb@zzu.edu.cn (J.B.C.)
  binzhang@zzu.edu.cn (B.Z.)
- Funds：
- DOI：10.1007/s10118-022-2709-1
  CLC：
- Received：30 December 2021，
  
  Revised：2022-1-25，
  
  Accepted：04 February 2022，
  
  Online First：20 April 2022，
  
  Published：01 June 2022
- Accepted：
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Wang, Z. Q.; Wang, Y. M.; Wang, X. Y.; Wang, B. H.; Chen, J. B.; Shen, C. Y.; Zhang, B. Self-nucleation of patterned polymer thin films defined by soft lithography. Chinese J. Polym. Sci. 2022, 40, 651–657

Ze-Qian Wang, Yi-Meng Wang, Xing-Yu Wang, et al. Self-nucleation of Patterned Polymer Thin Films Defined by Soft Lithography[J]. Chinese Journal of Polymer Science, 2022, 40(6): 651-657.
Wang, Z. Q.; Wang, Y. M.; Wang, X. Y.; Wang, B. H.; Chen, J. B.; Shen, C. Y.; Zhang, B. Self-nucleation of patterned polymer thin films defined by soft lithography. Chinese J. Polym. Sci. 2022, 40, 651–657 DOI： 10.1007/s10118-022-2709-1.

Ze-Qian Wang, Yi-Meng Wang, Xing-Yu Wang, et al. Self-nucleation of Patterned Polymer Thin Films Defined by Soft Lithography[J]. Chinese Journal of Polymer Science, 2022, 40(6): 651-657. DOI： 10.1007/s10118-022-2709-1.

摘要

The periodic arrays of PEO-

-P2VP isolated single crystals of uniform size with simultaneously controllable number density and spatial distribution of nuclei were prepared by self-nucleation of patterned dendritic crystals.

Abstract

The nucleation of crystals is often a determining step in the phase transition of materials

but it remains a challenge to control the density and specific location of nuclei simultaneously. Here we fabricated the isolated single crystals of uniform size with controlled number density and spatial distribution by self-nucleation of patterned dendritic crystals. Imprint lithography creates the periodic void space on the surface of poly(ethylene oxide)-

-poly(2-vinyl pyridine) (PEO-

-P2VP) block copolymer thin films and provides spatial redistribution of polymers

leading to the preferential nucleation and subsequent oriented growth of dendrites in the periodic arrays of imprinted lines. The morphology and thermal stability of the patterned crystals can be adjusted by tuning embossing conditions (

e. g.

temperature and pressure). Furthermore

in the self-nucleation technique

the annealing temperature and heating rate are used as the feedback parameters to map the number density and spatial distribution of regrown single crystals. Such PEO-

-P2VP crystalline pattern can be used as a versatile template for large-area manufacturing of selective metal patterns for electronic devices and other applications.

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Keywords

references

Binsbergen, F. L . Orientation-induced nucleation in polymer crystallization . Nature , 1966 . 211 516 - 517 . DOI: 10.1038/211516a0 http://doi.org/10.1038/211516a0 .

Mercier, J. P . Nucleation in polymer crystallization: a physical or a chemical mechanism . Polym. Eng. Sci. , 1990 . 30 270 - 278 . DOI: 10.1002/pen.760300504 http://doi.org/10.1002/pen.760300504 .

Xu, J.; Reiter, G.; Alamo, R. G . Concepts of nucleation in polymer crystallization . Crystals , 2021 . 11 304 DOI: 10.3390/cryst11030304 http://doi.org/10.3390/cryst11030304 .

Hu, W . The physics of polymer chain-folding . Phys. Rep. , 2018 . 747 1 - 50 . DOI: 10.1016/j.physrep.2018.04.004 http://doi.org/10.1016/j.physrep.2018.04.004 .

Wang, B.; He, K.; Lu, Y.; Zhou, Y.; Chen, J.; Shen, C.; Chen, J.; Men, Y.; Zhang, B . Nucleation mechanism for form II to I polymorphic transformation in polybutene-1 . Macromolecules , 2020 . 53 6476 - 6485 . DOI: 10.1021/acs.macromol.0c00885 http://doi.org/10.1021/acs.macromol.0c00885 .

Qiao, Y.; Wang, Q.; Men, Y . Kinetics of nucleation and growth of form II to I polymorphic transition in polybutene-1 as revealed by stepwise annealing . Macromolecules , 2016 . 49 5126 - 5136 . DOI: 10.1021/acs.macromol.6b00862 http://doi.org/10.1021/acs.macromol.6b00862 .

Schick, C.; Androsch, R.; Schmelzer, J. W. P . Homogeneous crystal nucleation in polymers . J. Phys.: Condens. Matter , 2017 . 29 453002 DOI: 10.1088/1361-648X/aa7fe0 http://doi.org/10.1088/1361-648X/aa7fe0 .

Lu, Y.; Lyu, D.; Cavallo, D.; Men, Y . Enhanced beta to alpha recrystallization in beta isotactic polypropylene with different thermal histories . Polym. Cryst. , 2019 . 2 e10040 DOI: 10.1002/pcr2.10040 http://doi.org/10.1002/pcr2.10040 .

Hou, C.; Wan, R.; Sun, X.; Ren, Z.; Li, H.; Yan, S . The development of an abnormal isotactic polypropylene spherulite: morphology and kinetics . Polym. Cryst. , 2020 . 3 e10157 DOI: 10.1002/pcr2.10157 http://doi.org/10.1002/pcr2.10157 .

Binsbergen, F. L . Natural and artificial heterogeneous nucleation in polymer crystallization . J. Polym. Sci., Polym. Symp. , 1977 . 59 11 - 29 . DOI: 10.1002/polc.5070590104 http://doi.org/10.1002/polc.5070590104 .

Li, L.; Xin, R.; Li, H.; Sun, X.; Ren, Z.; Huang, Q.; Yan, S . Tacticity-dependent epitaxial crystallization of poly(L-lactic acid) on an oriented polyethylene substrate . Macromolecules , 2020 . 53 8487 - 8493 . DOI: 10.1021/acs.macromol.0c01456 http://doi.org/10.1021/acs.macromol.0c01456 .

Li, L.; Hu, J.; Li, Y.; Huang, Q.; Sun, X.; Yan, S . Evidence for the soft and hard epitaxies of poly(L-lactic acid) on an oriented polyethylene substrate and their dependence on the crystallization temperature . Macromolecules , 2020 . 53 1745 - 1751 . DOI: 10.1021/acs.macromol.9b02598 http://doi.org/10.1021/acs.macromol.9b02598 .

Liu, Z.; Zheng, G.; Shi, H.; Liu, C.; Mi, L.; Li, Q.; Liu, X . Simultaneous enhancement of toughness and strength of stretched i PP film via tiny amount of β -nucleating agent under “shear-free” melt-extrusion . Chinese J. Polym. Sci. , 2021 . 39 1481 - 1488 . DOI: 10.1007/s10118-021-2589-9 http://doi.org/10.1007/s10118-021-2589-9 .

Blundell, D. J.; Keller, A.; Kovacs, A. J . A new self-nucleation phenomenon and its application to the growing of polymer crystals from solution . J. Polym. Sci., Part B: Polym. Lett. , 1966 . 4 481 - 486 . DOI: 10.1002/pol.1966.110040709 http://doi.org/10.1002/pol.1966.110040709 .

Reiter, G . Some unique features of polymer crystallisation . Chem. Soc. Rev. , 2014 . 43 2055 - 2065 . DOI: 10.1039/C3CS60306G http://doi.org/10.1039/C3CS60306G .

Zhou, T; Yang, H.; Ning, N.; Xiang, Y; Du, R; Fu, Q . Partial melting and recrystallization of isotactic polypropylene . Chinese J. Polym. Sci. , 2010 . 28 77 - 83 . DOI: 10.1007/s10118-010-8217-8 http://doi.org/10.1007/s10118-010-8217-8 .

Sangroniz, L.; Cavallo, D.; Müller, A. J . Self-Nucleation effects on polymer crystallization . Macromolecules , 2020 . 53 4581 - 4604 . DOI: 10.1021/acs.macromol.0c00223 http://doi.org/10.1021/acs.macromol.0c00223 .

Chen, E.; Weng, X.; Zhang, A.; Mann, I.; Harris, F. W.; Cheng, S. Z. D.; Stein, R.; Hsiao, B. S.; Yeh, F . Primary nucleation in polymer crystallization . Macromol. Rapid Commun. , 2001 . 22 611 - 615 . DOI: 10.1002/1521-3927(20010501)22:8<611::AID-MARC611>3.0.CO;2-J http://doi.org/10.1002/1521-3927(20010501)22:8<611::AID-MARC611>3.0.CO;2-J .

Fillon, B.; Thierry, A.; Wittmann, J. C.; Lotz, B. Self-nucleation and recrystallization of polymers . Isotactic polypropylene, β phase: β - α conversion and β - α growth transitions . J. Polym. Sci., Part B: Polym. Phys. , 1993 . 31 1407 - 1424 . DOI: 10.1002/polb.1993.090311015 http://doi.org/10.1002/polb.1993.090311015 .

Jiang, J.; Zhuravlev, E.; Hu, W.; Schick, C.; Zhou, D . The effect of self-nucleation on isothermal crystallization kinetics of poly(butylene succinate) (PBS) investigated by differential fast scanning calorimetry . Chinese J. Polym. Sci. , 2017 . 35 1009 - 1019 . DOI: 10.1007/s10118-017-1942-5 http://doi.org/10.1007/s10118-017-1942-5 .

Xu, J.; Ma, Y.; Hu, W.; Rehahn, M.; Reiter, G . Cloning polymer single crystals through self-seeding . Nat. Mater. , 2009 . 8 348 - 353 . DOI: 10.1038/nmat2405 http://doi.org/10.1038/nmat2405 .

Wang, B.; Tang, S.; Wang, Y.; Shen, C.; Reiter, R.; Reiter, G.; Chen, J.; Zhang, B . Systematic control of self-seeding crystallization patterns of poly(ethylene oxide) in thin films . Macromolecules , 2018 . 51 1626 - 1635 . DOI: 10.1021/acs.macromol.7b02445 http://doi.org/10.1021/acs.macromol.7b02445 .

Cui, K.; Ma, Z.; Tian, N.; Su, F.; Liu, D.; Li, L . Multiscale and multistep ordering of flow-induced nucleation of polymers . Chem. Rev. , 2018 . 118 1840 - 1886 . DOI: 10.1021/acs.chemrev.7b00500 http://doi.org/10.1021/acs.chemrev.7b00500 .

Zhang, B.; Chen, J.; Ji, F.; Zhang, X.; Zheng, G.; Shen, C . Effects of melt structure on shear-induced β -cylindrites of isotactic polypropylene . Polymer , 2012 . 53 1791 - 1800 . DOI: 10.1016/j.polymer.2012.02.023 http://doi.org/10.1016/j.polymer.2012.02.023 .

Zhang, B.; Chen, J.; Zhang, X.; Shen, C . Formation of β -cylindrites under supercooled extrusion of isotactic polypropylene at low shear stress . Polymer , 2011 . 52 2075 - 2084 . DOI: 10.1016/j.polymer.2011.03.001 http://doi.org/10.1016/j.polymer.2011.03.001 .

Zhang, B.; Chen, J.; Cui, J.; Zhang, H.; Ji, F.; Zheng, G.; Heck, B.; Reiter, G.; Shen, C . Effect of shear stress on crystallization of isotactic polypropylene from a structured melt . Macromolecules , 2012 . 45 8933 - 8937 . DOI: 10.1021/ma3014756 http://doi.org/10.1021/ma3014756 .

Chen, J.; Wang, B.; Sun, T.; Xu, J.; Chen, J.; Zhang, B . Transformation from form II to form I accelerated by oriented lamellae in polybutene-1 . Polymer , 2019 . 185 121966 DOI: 10.1016/j.polymer.2019.121966 http://doi.org/10.1016/j.polymer.2019.121966 .

Lu, Y.; Li, H.; Wei, H.; Wang, B.; Shen, C.; Zhang, B.; Chen, J . Influence of melt structure on form II to I phase transition of polybutene-1 under shear flow . Polymer , 2020 . 199 122562 DOI: 10.1016/j.polymer.2020.122562 http://doi.org/10.1016/j.polymer.2020.122562 .

Zhang, B.; Chen, J.; Freyberg, P.; Reiter, R.; Mülhaupt, R.; Xu, J.; Reiter, G . High-temperature stability of dewetting-induced thin polyethylene filaments . Macromolecules , 2015 . 48 1518 - 1523 . DOI: 10.1021/ma502345p http://doi.org/10.1021/ma502345p .

Zhang, H.; Wang, B.; Wang, G.; Shen, C.; Chen, J.; Reiter, G.; Zhang, B . Dewetting-induced alignment and ordering of cylindrical mesophases in thin block copolymer films . Macromolecules , 2020 . 53 9631 - 9640 . DOI: 10.1021/acs.macromol.0c01233 http://doi.org/10.1021/acs.macromol.0c01233 .

Nie, Y.; Zhao, Y.; Matsuba, G.; Hu, W . Shish-kebab crystallites initiated by shear fracture in bulk polymers . Macromolecules , 2018 . 51 480 - 487 . DOI: 10.1021/acs.macromol.7b02357 http://doi.org/10.1021/acs.macromol.7b02357 .

Nie, C.; Peng, F.; Xu, T.; Sheng, J.; Chen, W.; Li, L . A unified thermodynamic model of flow-induced crystallization of polymer . Chinese J. Polym. Sci. , 2021 . 39 1489 - 1495 . DOI: 10.1007/s10118-021-2622-z http://doi.org/10.1007/s10118-021-2622-z .

Li, H.; Yan, S . Surface-induced polymer crystallization and the resultant structures and morphologies . Macromolecules , 2011 . 44 417 - 428 . DOI: 10.1021/ma1023457 http://doi.org/10.1021/ma1023457 .

Cheng, S.; Hu, W.; Ma, Y.; Yan, S . Epitaxial polymer crystal growth influenced by partial melting of the fiber in the single-polymer composites . Polymer , 2007 . 48 4264 - 4270 . DOI: 10.1016/j.polymer.2007.05.030 http://doi.org/10.1016/j.polymer.2007.05.030 .

Hu, W.; Frenkel, D.; Mathot, V . Simulation of shish-kebab crystallite induced by a single prealigned macromolecule . Macromolecules , 2002 . 35 7172 - 7174 . DOI: 10.1021/ma0255581 http://doi.org/10.1021/ma0255581 .

Palacios, J. K.; Zhang, H.; Zhang, B.; Hadjichristidis, N.; Müller, A. J . Direct identification of three crystalline phases in PEO- b -PCL- b -PLLA triblock terpolymer by In situ hot-stage atomic force microscopy . Polymer , 2020 . 205 122863 DOI: 10.1016/j.polymer.2020.122863 http://doi.org/10.1016/j.polymer.2020.122863 .

Wang, H.; Keum, J . K.; Hiltner, A.; Baer, E. Confined crystallization of PEO in nanolayered films impacting structure and oxygen permeability . Macromolecules , 2009 . 42 7055 - 7066 . DOI: 10.1021/ma901379f http://doi.org/10.1021/ma901379f .

Wang, H.; Keum, J . K.; Hiltner, A.; Baer, E.; Freeman, B.; Rozanski, A.; Galeski, A. Confined crystallization of polyethylene oxide in nanolayer assemblies . Science , 2009 . 323 757 - 760 . DOI: 10.1126/science.1164601 http://doi.org/10.1126/science.1164601 .

Ma, M.; Guo, Y . Physical properties of polymers under soft and hard nanoconfinement: a review . Chinese J. Polym. Sci. , 2020 . 38 565 - 578 . DOI: 10.1007/s10118-020-2380-3 http://doi.org/10.1007/s10118-020-2380-3 .

Huang, H.; Yi, G.; Zu, X.; Zhong, B.; Luo, H . Patterning of triblock copolymer film and its application for surface-enhanced Raman scattering . Chinese J. Polym. Sci. , 2017 . 35 623 - 630 . DOI: 10.1007/s10118-017-1914-9 http://doi.org/10.1007/s10118-017-1914-9 .

Chou, S. Y.; Krauss, P. R.; Renstrom, P. J . Imprint lithography with 25-nanometer resolution . Science , 1996 . 272 85 - 87 . DOI: 10.1126/science.272.5258.85 http://doi.org/10.1126/science.272.5258.85 .

Chou, S. Y.; Krauss, P . R.; Zhang, W.; Guo, L.; Zhuang, L. Sub-10 nm imprint lithography and applications . J. Vac. Sci. Technol., B: Microelectron. Nanometer Struct.-Process., Meas., Phenom. , 1997 . 15 2897 - 2904 . DOI: 10.1116/1.589752 http://doi.org/10.1116/1.589752 .

Guo, L. J . Nanoimprint lithography: methods and material requirements . Adv. Mater. , 2007 . 19 495 - 513 . DOI: 10.1002/adma.200600882 http://doi.org/10.1002/adma.200600882 .

Chou, S. Y.; Krauss, P. R.; Renstrom, P. J . Imprint of sub-25 nm vias and trenches in polymers . Appl. Phys. Lett. , 1995 . 67 3114 - 3116 . DOI: 10.1063/1.114851 http://doi.org/10.1063/1.114851 .

Peng, L.; Deng, Y.; Yi, P.; Lai, X . Micro hot embossing of thermoplastic polymers: a review . J. Micromech. Microeng. , 2013 . 24 013001 .

Okerberg, B. C.; Soles, C. L.; Douglas, J. F.; Ro, H. W.; Karim, A.; Hines, D. R . Crystallization of poly(ethylene oxide) patterned by nanoimprint lithography . Macromolecules , 2007 . 40 2968 - 2970 . DOI: 10.1021/ma070293h http://doi.org/10.1021/ma070293h .

Hu, Z.; Baralia, G.; Bayot, V.; Gohy, J. F.; Jonas, A. M . Nanoscale control of polymer crystallization by nanoimprint lithography . Nano Lett. , 2005 . 5 1738 - 1743 . DOI: 10.1021/nl051097w http://doi.org/10.1021/nl051097w .

Yang, H.; Xu, L.; Li, X.; Zhang, X . One simple route to fabricate gold nanowire network films by using P2VP- b -PEO diblock copolymers as templates . Mater. Chem. Phys. , 2009 . 114 525 - 529 . DOI: 10.1016/j.matchemphys.2008.11.040 http://doi.org/10.1016/j.matchemphys.2008.11.040 .

Cheng, S. Z. D.; Zhang, A.; Chen, J.; Heberer, D. P. Nonintegral and integral folding crystal growth in low-molecular mass poly(ethylene oxide) fractions. I . Isothermal lamellar thickening and thinning . J. Polym. Sci., Part B: Polym. Phys. , 1991 . 29 287 - 297 . .

Kang, J. H.; Kim, K. S.; Kim, K. W . Molecular dynamics study on the effects of stamp shape, adhesive energy, and temperature on the nanoimprint lithography process . Appl. Surf. Sci. , 2010 . 257 1562 - 1572 . DOI: 10.1016/j.apsusc.2010.08.096 http://doi.org/10.1016/j.apsusc.2010.08.096 .

Yang, Y.; Mielczarek, K.; Zakhidov, A.; Hu, W . Large molecular weight polymer solar cells with strong chain alignment created by nanoimprint lithography . ACS Appl. Mater. Interfaces , 2016 . 8 7300 - 7307 . DOI: 10.1021/acsami.6b00192 http://doi.org/10.1021/acsami.6b00192 .

Aryal, M.; Trivedi, K.; Hu, W . Nano-confinement induced chain alignment in ordered P3HT nanostructures defined by nanoimprint lithography . ACS Nano , 2009 . 3 3085 - 3090 . DOI: 10.1021/nn900831m http://doi.org/10.1021/nn900831m .

Yang, Y.; Mielczarek, K.; Aryal, M.; Zakhidov, A.; Hu, W . Nanoimprinted polymer solar cell . ACS Nano , 2012 . 6 2877 - 2892 . DOI: 10.1021/nn3001388 http://doi.org/10.1021/nn3001388 .

Reiter, G.; Botiz, I.; Graveleau, L.; Grozev, N.; Albrecht, K.; Mourran, A.; Möller, M. Morphologies of polymer crystals in thin films. In Progress in understanding of polymer crystallization , Springer, Berlin Heidelberg New York, 2007 , p. 179−200.

Taguchi, K.; Miyaji, H.; Izumi, K.; Hoshino, A.; Miyamoto, Y.; Kokawa, R . Crystal growth of isotactic plystyrene in ultrathin films: film thickness dependence . J. Macromol. Sci., Part B , 2002 . 41 1033 - 1042 . DOI: 10.1081/MB-120013081 http://doi.org/10.1081/MB-120013081 .

Wang, B.; Wang, G.; He, S.; Sun, T.; Chen, J.; Shen, C.; Zhang, B . Self-nucleation of β -form isotactic polypropylene lamellar crystals in thin films . Macromolecules , 2021 . 54 11404 - 11411 . DOI: 10.1021/acs.macromol.1c02057 http://doi.org/10.1021/acs.macromol.1c02057 .

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