A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism

Xiu-Zhi Tian; Rui Yang; Jia-Jia Ma; Yong-Hao Ni; Hai-Bo Deng; Lei Dai; Jiao-Jun Tan; Mei-Yun Zhang; Xue Jiang

doi:10.1007/s10118-022-2703-7

Your Location：

Home >

Browse articles >

A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism

RESEARCH ARTICLE | Updated：2022-06-22

- A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism
- Chinese Journal of Polymer Science Vol. 40, Issue 7, Pages: 789-798(2022)
- Affiliations：
  
  a.College of Bioresource Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
  b.College of Textile Science and Engineering, Jiangnan University, Wuxi 214122, China
  c.Limerick Pulp & Paper Centre & Department of Chemical Engineering, University of New Brunswick, Fredericton, New Brunswick E3B5A3, Canada
- Author bio：
  
  jiangx@sust.edu.cn
- Funds：
- DOI：10.1007/s10118-022-2703-7
  CLC：
- Received：14 December 2021，
  
  Revised：2022-1-16，
  
  Accepted：24 January 2022，
  
  Online First：27 April 2022，
  
  Published：01 July 2022
- Accepted：
Scan QR Code
Tian, X. Z.; Yang, R.; Ma, J. J.; Ni, Y. H.; Deng, H. B.; Dai, L.; Tan, J. J.; Zhang, M. Y.; Jiang, X. A novel ternary composite of polyurethane/polyaniline/nanosilica with antistatic property and excellent mechanical strength: preparation and mechanism. Chinese J. Polym. Sci. 2022, 40, 789–798

Xiu-Zhi Tian, Rui Yang, Jia-Jia Ma, et al. A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism[J]. Chinese Journal of Polymer Science, 2022, 40(7): 789-798.
Tian, X. Z.; Yang, R.; Ma, J. J.; Ni, Y. H.; Deng, H. B.; Dai, L.; Tan, J. J.; Zhang, M. Y.; Jiang, X. A novel ternary composite of polyurethane/polyaniline/nanosilica with antistatic property and excellent mechanical strength: preparation and mechanism. Chinese J. Polym. Sci. 2022, 40, 789–798 DOI： 10.1007/s10118-022-2703-7.

Xiu-Zhi Tian, Rui Yang, Jia-Jia Ma, et al. A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism[J]. Chinese Journal of Polymer Science, 2022, 40(7): 789-798. DOI： 10.1007/s10118-022-2703-7.

摘要

Polyurethane/polyaniline/nanosilica composites were prepared. The electronic resistance of the polyurethane was decreased

while the strength of the polyurethane was increased. As a result

the antistatic and mechanic properties of polyurethane were improved with the doping of polyaniline and nanosilica.

Abstract

Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein

polyurethane was composited with polyaniline and nanosilica based on

in situ

synthesis of polymer and physical mixing of these fillers to reach desired antistatic and mechanical properties. Chemical

morphological and thermal properties of the polyurethane/polyaniline/nanosilica composites were studied. The electrical resistivity of the composite decreased from 1.1×10

MΩ to 7.6×10

MΩ as a result of the addition of 4% polyaniline. The tensile strength and elongation at break of the polyurethane composites improved by nearly 300% and 100%

respectively

when compared with those of the neat polyurethane. The electronic resistance of PU/PANI/NS ternary is low enough for its antistatic property and decreases with the increase of the added nanosilica

which is unexpectedly and rather significant. Our results would shed light on the development of antistatic PU with excellent mechanical performance.

关键词

Keywords

references

Ji, X.; Chen, D.; Shen, J.; Guo, S . Flexible and flame-retarding thermoplastic polyurethane-based electromagnetic interference shielding composites . Chem. Eng. J. , 2019 . 370 1341 - 1349 . DOI: 10.1016/j.cej.2019.03.293 http://doi.org/10.1016/j.cej.2019.03.293 .

Sasaki, S.; Tsujiei, Y.; Kawai, M.; Mitsumata, T . Electric conductivity and dielectric-breakdown behavior for polyurethane magnetic elastomers . J. Phys. Chem. B , 2017 . 121 1740 - 1747 . DOI: 10.1021/acs.jpcb.6b12875 http://doi.org/10.1021/acs.jpcb.6b12875 .

China National Textile and Apparel Council (CNTAC). in The development report of China textile industry in 2020−2021 . China Textiles Press, Beijing, 2021 .

Nozaki, S.; Hirai, T.; Higaki, Y.; Yoshinaga, K.; Kojio, K.; Takahara, A . Effect of chain architecture of polyol with secondary hydroxyl group on aggregation structure and mechanical properties of polyurethane elastomer . Polymer , 2017 . 116 423 - 428 . DOI: 10.1016/j.polymer.2017.03.031 http://doi.org/10.1016/j.polymer.2017.03.031 .

Park, K. W.; Dong, H. K.; Kim, H. J . Preparation and characterization of polyamide4 (PA4)-polyurethane (PU)-PA4 triblock copolymers . Polymer , 2014 . 38 9 - 15 . DOI: 10.7317/pk.2014.38.1.9 http://doi.org/10.7317/pk.2014.38.1.9 .

Chen, C.; Zhao, X.; Shi, C.; Chen, J . Synergistic effect between carbon nanoparticle and intumescent flame retardant on flammability and smoke suppression of copolymer thermoplastic polyurethane . J. Mater. Sci. , 2018 . 53 6053 - 6064 . DOI: 10.1007/s10853-017-1970-0 http://doi.org/10.1007/s10853-017-1970-0 .

Wu, K. H.; Feng, L. F.; Gu, X. P.; Zhang, C. L.; Shen, S . Thermally reversible cross-linkers to facilitate the improved reprocessability of poly(butyl methanol methacrylate) rubber with excellent thermal and mechanical properties . Ind. Eng. Chem. Res. , 2018 . 57 946 - 953 . DOI: 10.1021/acs.iecr.7b04421 http://doi.org/10.1021/acs.iecr.7b04421 .

Zou, H.; Wu, S.; Shen, J . Polymer/silica nanocomposites: preparation, characterization, properties, and applications . Chem. Rev. , 2008 . 108 3893 - 3957 . DOI: 10.1021/cr068035q http://doi.org/10.1021/cr068035q .

Ambilkar, S. C.; Bansod, N. D.; Kapgate, B . P.; Das, A.; Formanek, P.; Rajkumar, K.; Das, C. In situ zirconia: a superior reinforcing filler for high-performance nitrile rubber composites . ACS Omega , 2020 . 5 7751 - 7761 . DOI: 10.1021/acsomega.9b03495 http://doi.org/10.1021/acsomega.9b03495 .

Choi, S. M.; Han, S. S.; Shin, E. J . Highly stretchable conductive nanocomposite films using regenerated cellulose nanoparticles . ACS Appl. Polym. Mater. , 2020 . 2 4387 - 4398 . DOI: 10.1021/acsapm.0c00294 http://doi.org/10.1021/acsapm.0c00294 .

Feng, L. B.; Wang, Y. P.; Qiang, X. H.; Wang, S. H . Effect of silica nanoparticles on properties of waterborne polyurethanes . Chinese J. Polym. Sci. , 2012 . 30 845 - 852 . DOI: 10.1007/s10118-012-1175-6 http://doi.org/10.1007/s10118-012-1175-6 .

Yan, K.; Liu, C.; Ma, J . Dendritic fibrous nanosilica loaded chitosan for improving water vapor permeability and antibacterial properties of waterborne polyurethane acrylate membranes . J. Clean. Prod. , 2021 . 291 125922 DOI: 10.1016/j.jclepro.2021.125922 http://doi.org/10.1016/j.jclepro.2021.125922 .

Xie, W.; Pakdel, E.; Liu, D.; Sun, L.; Wang, X . Waste-hair-derived natural melanin/TiO 2 hybrids as highly efficient and stable UV-shielding fillers for polyurethane films . ACS Sustain. Chem. Eng. , 2020 . 8 1343 - 1352 . DOI: 10.1021/acssuschemeng.9b03514 http://doi.org/10.1021/acssuschemeng.9b03514 .

Zhang, H.; She, Y.; Zheng, X.; Cheng, H. Y.; Pu, J. W . Optical and mechanical properties of polyurethane/surface-modified nanocrystalline cellulose composites . Chinese J. Polym. Sci. , 2014 . 32 1363 - 1372 . DOI: 10.1007/s10118-014-1526-6 http://doi.org/10.1007/s10118-014-1526-6 .

Ali, A.; Xiao, Y.; Song, L.; Hua, J.; Rao, Q.; Shoaib, M.; Ul Amin, B.; Zhan, X.; Zhang, Q . Biodegradable polyurethane based clay composite and their anti-biofouling properties . Colloid. Surf. A: Physicochem. Eng. Aspects , 2021 . 625 126946 DOI: 10.1016/j.colsurfa.2021.126946 http://doi.org/10.1016/j.colsurfa.2021.126946 .

Adak, B.; Butola, B. S.; Joshi, M . Effect of organoclay-type and clay-polyurethane interaction chemistry for tuning the morphology, gas barrier and mechanical properties of clay/polyurethane nanocomposites . Appl. Clay Sci. , 2018 . 161 343 - 353 . DOI: 10.1016/j.clay.2018.04.030 http://doi.org/10.1016/j.clay.2018.04.030 .

Qu, M.; Wang, H.; Chen, Q.; Wu, L.; Tang, P.; Fan, M.; Guo, Y.; Fan, H.; Bin, Y . A thermally-electrically double-responsive polycaprolactone-thermoplastic polyurethane/multi-walled carbon nanotube fiber assisted with highly effective shape memory and strain sensing performance . Chem. Eng. J. , 2022 . 427 131648 DOI: 10.1016/j.cej.2021.131648 http://doi.org/10.1016/j.cej.2021.131648 .

Ardimas; Putson C. Muensit N. . High electromechanical performance of modified electrostrictive polyurethane three-phase composites . Compos. Sci. Technol. , 2018 . 158 164 - 174 . DOI: 10.1016/j.compscitech.2018.02.012 http://doi.org/10.1016/j.compscitech.2018.02.012 .

Cao, B. H.; Chen, W.; Wei, W. Y.; Chen, Y. L.; Yuan, Y . Carbon dots intensified mechanochemiluminescence from waterborne polyurethanes as tunable force sensing materials . Chinese J. Polym. Sci. , 2021 . 39 1403 - 1411 . DOI: 10.1007/s10118-021-2601-4 http://doi.org/10.1007/s10118-021-2601-4 .

Nezakati, T.; Seifalian, A.; Tan, A.; Seifalian, A. M . Conductive polymers: opportunities and challenges in biomedical applications . Chem. Rev. , 2018 . 118 6766 - 6843 . DOI: 10.1021/acs.chemrev.6b00275 http://doi.org/10.1021/acs.chemrev.6b00275 .

Wang, F.; Feng, L.; Huang, Y.; Shen, W.; Ma, H . Effect of the gradient distribution of multiwalled carbon nanotubes on the bond strength and corrosion resistance of waterborne polyurethane conductive nanocomposites . Prog. Org. Coat. , 2020 . 140 105507 DOI: 10.1016/j.porgcoat.2019.105507 http://doi.org/10.1016/j.porgcoat.2019.105507 .

Liu, L.; Yu, P.; Wu, M.; Wu, Q.; Liu, J.; Yang, J.; Zhang, J . Poly(tannin urethane)-stabilized multiwalled carbon nanotube aqueous dispersion for antistatic coating . Ind. Eng. Chem. Res. , 2021 . 60 12353 - 12361 . .

Vieira, L. S.; dos Anjos, E. G. R.; Verginio, G. E. A.; Oyama, I. C.; Braga, N. F.; da Silva, T. F.; Montagna, L. S.; Rezende, M. C.; Passador, F. R . Carbon-based materials as antistatic agents for the production of antistatic packaging: a review . J. Mater. Sci.: Mater. Electron. , 2021 . 32 3929 - 3947 . DOI: 10.1007/s10854-020-05178-6 http://doi.org/10.1007/s10854-020-05178-6 .

Yadav, R.; Tirumali, M.; Wang, X.; Naebe, M.; Kandasubramanian, B . Polymer composite for antistatic application in aerospace . Def. Technol. , 2020 . 16 107 - 118 . DOI: 10.1016/j.dt.2019.04.008 http://doi.org/10.1016/j.dt.2019.04.008 .

Al-Attabi, N . Y.; Kaur, G.; Adhikari, R.; Cass, P.; Bown, M.; Evans, M. Preparation and characterization of highly conductive polyurethane composites containing graphene and gold nanoparticles . J. Mater. Sci. , 2017 . 52 11774 - 11784 . DOI: 10.1007/s10853-017-1335-8 http://doi.org/10.1007/s10853-017-1335-8 .

Jaaoh, D.; Putson, C.; Muensit, N . Enhanced strain response and energy harvesting capabilities of electrostrictive polyurethane composites filled with conducting polyaniline . Compos. Sci. Technol. , 2016 . 122 97 - 103 . DOI: 10.1016/j.compscitech.2015.11.020 http://doi.org/10.1016/j.compscitech.2015.11.020 .

Nawaka, K.; Putson, C . Enhanced electric field induced strain in electrostrictive polyurethane composites fibers with polyaniline (emeraldine salt) spider-web network . Compos. Sci. Technol. , 2020 . 198 108293 DOI: 10.1016/j.compscitech.2020.108293 http://doi.org/10.1016/j.compscitech.2020.108293 .

Hu, Y.; Liu, X.; Tian, L.; Zhao, T.; Wang, H.; Liang, X.; Zhou, F.; Zhu, P.; Li, G.; Sun, R.; Wong, C. P . Multidimensional ternary hybrids with synergistically enhanced electrical performance for conductive nanocomposites and prosthetic electronic skin . ACS Appl. Mater. Interfaces , 2018 . 10 38493 - 38505 . DOI: 10.1021/acsami.8b14932 http://doi.org/10.1021/acsami.8b14932 .

Li, M.; Li, H.; Zhong, W.; Zhao, Q.; Wang, D . Stretchable conductive polypyrrole/polyurethane (PPY/PU) strain sensor with netlike microcracks for human breath detection . ACS Appl. Mater. Interfaces , 2014 . 6 1313 - 1319 . DOI: 10.1021/am4053305 http://doi.org/10.1021/am4053305 .

Liow, K. S.; Sipaut, C. S.; Jafarzadeh, M . Polypyrrole- and polyaniline-surface modified nanosilica as quasi-solid state electrolyte ingredients for dye-sensitized solar cells . J. Mater. Sci.: Mater. Electron. , 2018 . 29 21097 - 21108 . DOI: 10.1007/s10854-018-0258-8 http://doi.org/10.1007/s10854-018-0258-8 .

Liow, K. S.; Sipaut, C. S.; Ung, M. C.; Dayou, J . Effect of incorporating different polyaniline-surface modified nanosilica content into polyurethane-based quasi-solid-state electrolyte for dye-sensitized solar cells . J. Appl. Polym. Sci. , 2020 . 137 e49147 DOI: 10.1002/app.49147 http://doi.org/10.1002/app.49147 .

Luo, J; Wang, X.; Li, J.; Zhao, X.; Wang, F . Conductive hybrid film from polyaniline and polyurethane-silica . Polymer , 2007 . 48 4368 - 4374 . DOI: 10.1016/j.polymer.2007.05.062 http://doi.org/10.1016/j.polymer.2007.05.062 .

Liu, B. T.; Syu, J. R.; Wang, D. H . Conductive polyurethane composites containing polyaniline-coated nano-silica . J. Colloid Interface Sci. , 2013 . 393 138 - 142 . DOI: 10.1016/j.jcis.2012.11.028 http://doi.org/10.1016/j.jcis.2012.11.028 .

Wang, Y.; Li, T.; Wang, X.; Ma, P.; Bai, H.; Dong, W . Superior performance of polyurethane based on natural melanin nanoparticle . Biomacromolecules , 2016 . 17 3782 - 3789 . DOI: 10.1021/acs.biomac.6b01298 http://doi.org/10.1021/acs.biomac.6b01298 .

Pei, A.; Malho, J . M.; Ruokolainen, J.; Zhou, Q.; Berglund, L.A. Strong nanocomposite reinforcement effects in polyurethane elastomer with low volume fraction of cellulose nanocrystals . Macromolecules , 2011 . 44 4422 - 4427 . DOI: 10.1021/ma200318k http://doi.org/10.1021/ma200318k .

Tien, Y. I.; Wei, K. H . Hydrogen bonding and mechanical properties in segmented montmorillonite/polyurethane nanocomposites of different hard segment ratios . Polymer , 2001 . 42 3213 - 3221 . DOI: 10.1016/S0032-3861(00)00729-1 http://doi.org/10.1016/S0032-3861(00)00729-1 .

Kojio, K.; Nakamura, S.; Furukawa, M . Effect of side methyl groups of polymer glycol on elongation-induced crystallization behavior of polyurethane elastomers . Polymer , 2004 . 45 8147 - 8152 . DOI: 10.1016/j.polymer.2004.09.061 http://doi.org/10.1016/j.polymer.2004.09.061 .

Wei, Z.; Liu, Z.; Fu, X.; Wang, Y.; Yuan, A.; Lei, J . Effect of crystalline structure on water resistance of waterborne polyurethane . Eur. Polym. J. , 2021 . 157 110647 DOI: 10.1016/j.eurpolymj.2021.110647 http://doi.org/10.1016/j.eurpolymj.2021.110647 .

He, Y.; Zhang, X.; Runt, J . The role of diisocyanate structure on microphase separation of solution polymerized polyureas . Polymer , 2014 . 55 906 - 913 . DOI: 10.1016/j.polymer.2014.01.001 http://doi.org/10.1016/j.polymer.2014.01.001 .

Li, F.; Ma, Y.; Chen, L.; Li, H.; Zhou, H.; Chen, J . In-situ polymerization of polyurethane/aniline oligomer functionalized graphene oxide composite coatings with enhanced mechanical, tribological and corrosion protection properties . Chem. Eng. J. , 2021 . 425 130006 DOI: 10.1016/j.cej.2021.130006 http://doi.org/10.1016/j.cej.2021.130006 .

Gui, H.; Guan, G.; Zhang, T.; Guo, Q . Microphase-separated, hierarchical macroporous polyurethane from a nonaqueous emulsion-templated reactive block copolymer . Chem. Eng. J. , 2019 . 365 369 - 377 . DOI: 10.1016/j.cej.2019.02.015 http://doi.org/10.1016/j.cej.2019.02.015 .

Tian, C.; Fu, S. Y.; Meng, Q. J.; Lucia, L. A . New insights into the material chemistry of polycaprolactone-grafted cellulose nanofibrils/polyurethane nanocomposites . Cellulose , 2016 . 23 2457 - 2473 . DOI: 10.1007/s10570-016-0980-4 http://doi.org/10.1007/s10570-016-0980-4 .

Tian, Y.; Zhang, X.; Geng, H. Z.; Yang, H. J.; Li, C.; Da, S. X . Carbon nanotube/polyurethane films with high transparency, low sheet resistance and strong adhesion for antistatic application . RSC Adv. , 2017 . 7 53018 - 53024 . DOI: 10.1039/c7ra10092b http://doi.org/10.1039/c7ra10092b .

Views

187

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Processing-integrated Machine Learning Models for Predicting and Optimizing Mechanical Properties of Polyimides

Synergistic Bioinspired Interface and Segregated Graphene Oxide Networks Enabling Enhanced Mechanical Strength and Chemical Resistance in Natural Rubber Latex Composites

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Related Author

Wei-Long Hu

Hao-Ke Qiu

En-Zhe Jing

Wan-Chen Zhao

Hai-Yang Huo

Zhao-Yan Sun

Xiao-Da Pan

Yun-Kui Song

Related Institution

School of Applied Chemistry and Engineering, University of Science and Technology of China

State Key Laboratory of Polymer Physics and Chemistry & Key Laboratory of Polymer Science and Technology, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

Jilin Provincial International Cooperation Key Laboratory for Polymer Processing Physics

Hubei Key Laboratory for New Textile Materials and Applications, College of Materials Science and Engineering, Wuhan Textile University

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology

⁰