

FOLLOWUS
Ministry of Education, Key Laboratory of Macromolecular Synthesis and Functionalization, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
xuzk@zju.edu.cn
Received:11 September 2021,
Revised:2021-9-30,
Accepted:18 October 2021,
Online First:01 January 2022,
Published:01 February 2022
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Guo, B.-B.; Zhu, C.-Y.; Xu, Z.-K. Surface and interface engineering for advanced nanofiltration membranes. Chinese J. Polym. Sci. 2022, 40, 124–137
Bian-Bian Guo, Cheng-Ye Zhu, Zhi-Kang Xu. Surface and Interface Engineering for Advanced Nanofiltration Membranes[J]. Chinese Journal of Polymer Science, 2022, 40(2): 124-137.
Guo, B.-B.; Zhu, C.-Y.; Xu, Z.-K. Surface and interface engineering for advanced nanofiltration membranes. Chinese J. Polym. Sci. 2022, 40, 124–137 DOI: 10.1007/s10118-022-2654-z.
Bian-Bian Guo, Cheng-Ye Zhu, Zhi-Kang Xu. Surface and Interface Engineering for Advanced Nanofiltration Membranes[J]. Chinese Journal of Polymer Science, 2022, 40(2): 124-137. DOI: 10.1007/s10118-022-2654-z.
Nanofiltration has been attracting great attention in alleviating the global water crisis because of its high efficiency
mild operation
and strong adaptability. Over decades
it remains a challenge to break the upper limit of performance and establish the formation-structure-property relationship for nanofiltration membranes. This feature article summarizes our recent progress in the preparation of high-performance thin-film composite (TFC) nanofiltration membranes
focusing on the mussel-inspired deposition method and the optimized interfacial polymerization (IP). By accelerating the oxidation of polydopamine and equilibrating the rate of aggregation and deposition processes
the mussel-inspired deposition method realizes the rapid and uniform formation of selective coatings or nanofilms. Diverse deposition systems endow the selective layer with rich chemical structures and easy post-functionalization
highlighting its potential in water treatment. As for optimizing the conventional IP
the rapid polycondensation of amine and acid chloride groups is slowed down to enable the controllability of IP at the water-organic interface. The homogeneity and integrity of the TFC membranes are improved by constructing a uniform reaction platform and introducing a viscous medium to control the amine diffusion
which facilitates the water permeability and promotes the separation efficiency. We have proposed a series of practical strategies for improving TFC membranes and might provide more inspiration for other nanofiltration techniques.
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