Safety-enhanced Polymer Electrolytes with High Ambient-temperature Lithium-ion Conductivity Based on ABA Triblock Copolymers

Dong Liu; Fan Wu; Zhi-Hao Shen; Xing-He Fan

doi:10.1007/s10118-021-2648-2

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Safety-enhanced Polymer Electrolytes with High Ambient-temperature Lithium-ion Conductivity Based on ABA Triblock Copolymers

Papers | Updated：2021-11-04

- Safety-enhanced Polymer Electrolytes with High Ambient-temperature Lithium-ion Conductivity Based on ABA Triblock Copolymers
- Chinese Journal of Polymer Science Vol. 40, Issue 1, Pages: 21-28(2022)
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  zshen@pku.edu.cn (Z.H.S.)
  fanxh@pku.edu.cn (X.H.F.)
- Funds：
  
  This work was financially supported by the National Key R&D Program of China (No. 2018YFB0703702) and the National Natural Science Foundation of China (Nos. 21774001, 51725301 and 51921002). The authors gratefully acknowledge Synchrotron X-ray Beamline 1W2A in Beijing Synchrotron Radiation Facility (BSRF) and Synchrotron X-ray Beamline BL16B1 in Shanghai Synchrotron Radiation Facility (SSRF) for the assistance with the SAXS experiments.
- DOI：10.1007/s10118-021-2648-2
  CLC：
- Received：14 July 2021，
  
  Revised：2021-8-25，
  
  Accepted：02 September 2021，
  
  Online First：04 November 2021，
  
  Published：01 January 2022
- Accepted：
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Liu, D.; Wu, F.; Shen, Z. H.; Fan, X. H. Safety-enhanced polymer electrolytes with high ambient-temperature lithium-ion conductivity based on ABA triblock copolymers. Chinese J. Polym. Sci. 2022, 40, 21–28

Dong Liu, Fan Wu, Zhi-Hao Shen, et al. Safety-enhanced Polymer Electrolytes with High Ambient-temperature Lithium-ion Conductivity Based on ABA Triblock Copolymers[J]. Chinese Journal of Polymer Science, 2022, 40(1): 21-28.
Liu, D.; Wu, F.; Shen, Z. H.; Fan, X. H. Safety-enhanced polymer electrolytes with high ambient-temperature lithium-ion conductivity based on ABA triblock copolymers. Chinese J. Polym. Sci. 2022, 40, 21–28 DOI： 10.1007/s10118-021-2648-2.

Dong Liu, Fan Wu, Zhi-Hao Shen, et al. Safety-enhanced Polymer Electrolytes with High Ambient-temperature Lithium-ion Conductivity Based on ABA Triblock Copolymers[J]. Chinese Journal of Polymer Science, 2022, 40(1): 21-28. DOI： 10.1007/s10118-021-2648-2.

摘要

Abstract

Liquid electrolytes used in lithium-ion batteries suffer from leakage

flammability

and lithium dendrites

making polymer electrolyte a potential alternative. Herein

a series of ABA triblock copolymers (ABA-

) containing a mesogen-jacketed liquid crystalline polymer (MJLCP) with a polynorbornene backbone as segment A and a second polynorbornene-based polymer having poly(ethylene oxide) (PEO) side chains as segment B were synthesized through tandem ring-opening metathesis polymerizations. The block copolymers can self-assemble into ordered morphologies at 200 °C. After doping of lithium salts and ionic liquid (IL)

ABA-

self-assembles into cylindrical structures. The MJLCP segments with a high glass transition temperature and a stable liquid crystalline phase serve as physical crosslinking points

which significantly improve the mechanical performance of the polymer electrolytes. The ionic conductivity of ABA-

/lithium salt/IL is as high as 10

−3

S·cm

−1

at ambient temperature owing to the high IL uptake and the continuous phase of conducting PEO domains. The relationship between ionic conductivity and temperature fits the Vogel-Tamman-Fulcher (VTF) equation. In addition

the electrolyte films are flame retardant owing to the addition of IL. The polymer electrolytes with good safety and high ambient-temperature ionic conductivity developed in this work are potentially useful in solid lithium-ion batteries.

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references

Larcher, D.; Tarascon, J. M . Towards greener and more sustainable batteries for electrical energy storage . Nat. Chem. , 2014 . 7 19 DOI: 10.1038/nchem.2085 http://doi.org/10.1038/nchem.2085 .

Young, W. S.; Kuan, W. F.; Epps, I., Thomas H . Block copolymer electrolytes for rechargeable lithium batteries . J. Polym. Sci., Part B: Polym. Phys. , 2014 . 52 1 - 16 . DOI: 10.1002/polb.23404 http://doi.org/10.1002/polb.23404 .

Watanabe, T.; Inafune, Y.; Tanaka, M.; Mochizuki, Y.; Matsumoto, F.; Kawakami, H . Development of all-solid-state battery based on lithium ion conductive polymer nanofiber framework . J. Power Sources , 2019 . 423 255 - 262 . DOI: 10.1016/j.jpowsour.2019.03.066 http://doi.org/10.1016/j.jpowsour.2019.03.066 .

Mong Anh, L.; Kim, D . Solid electrolyte membrane prepared from poly(arylene ether sulfone)- g -poly(ethylene glycol) for lithium secondary battery . ACS Appl. Energy Mater. , 2019 . 2 2585 - 2595 . DOI: 10.1021/acsaem.8b02212 http://doi.org/10.1021/acsaem.8b02212 .

Zhang, X.; Li, L.; Fan, E.; Xue, Q.; Bian, Y.; Wu, F.; Chen, R . Toward sustainable and systematic recycling of spent rechargeable batteries . Chem. Soc. Rev. , 2018 . 47 7239 - 7302 . DOI: 10.1039/C8CS00297E http://doi.org/10.1039/C8CS00297E .

Sun, B.; Asfaw, H. D.; Rehnlund, D.; Mindemark, J.; Nyholm, L.; Edström, K.; Brandell, D . Toward solid-state 3D-microbatteries using functionalized polycarbonate-based polymer electrolytes . ACS Appl. Mater. Interfaces , 2018 . 10 2407 - 2413 . DOI: 10.1021/acsami.7b13788 http://doi.org/10.1021/acsami.7b13788 .

Ping, J.; Pan, H.; Hou, P. P.; Zhang, M. Y.; Wang, X.; Wang, C.; Chen, J.; Wu, D.; Shen, Z.; Fan, X. H . Solid polymer electrolytes with excellent high-temperature properties based on brush block copolymers having rigid side chains . ACS Appl. Mater. Interfaces , 2017 . 9 6130 - 6137 . DOI: 10.1021/acsami.6b15893 http://doi.org/10.1021/acsami.6b15893 .

Long, L.; Wang, S.; Xiao, M.; Meng, Y . Polymer electrolytes for lithium polymer batteries . J. Mater. Chem. A , 2016 . 4 10038 - 10069 . DOI: 10.1039/C6TA02621D http://doi.org/10.1039/C6TA02621D .

Xue, Z.; He, D.; Xie, X . Poly(ethylene oxide)-based electrolytes for lithium-ion batteries . J. Mater. Chem. A , 2015 . 3 19218 - 19253 . DOI: 10.1039/C5TA03471J http://doi.org/10.1039/C5TA03471J .

Wang, Y.; Zhong, W. H . Development of electrolytes towards achieving safe and high-performance energy-storage devices: a review . ChemElectroChem , 2015 . 2 22 - 36 . DOI: 10.1002/celc.201402277 http://doi.org/10.1002/celc.201402277 .

Kim, S.; Seo, M . Control of porosity in hierarchically porous polymers derived from hyper-crosslinked block polymer precursors . J. Polym. Sci., Part A: Polym. Chem. , 2018 . 56 900 - 913 . DOI: 10.1002/pola.28966 http://doi.org/10.1002/pola.28966 .

Fenton, D. E.; Parker, J. M.; Wright, P. V . Complexes of alkali metal ions with poly(ethylene oxide) . Polymer , 1973 . 14 589 DOI: 10.1016/0032-3861(73)90146-8 http://doi.org/10.1016/0032-3861(73)90146-8 .

Meyer, W. H . Polymer electrolytes for lithium-ion batteries . Adv. Mater. , 1998 . 10 439 - 448 . DOI: 10.1002/(sici)1521-4095(199804)10:6<439::aid-adma439>3.0.co;2-i http://doi.org/10.1002/(sici)1521-4095(199804)10:6<439::aid-adma439>3.0.co;2-i .

Gadjourova, Z.; Andreev, Y. G.; Tunstall, D. P.; Bruce, P. G . Ionic conductivity in crystalline polymer electrolytes . Nature , 2001 . 412 520 - 523 . DOI: 10.1038/35087538 http://doi.org/10.1038/35087538 .

Kishimoto, K.; Yoshio, M.; Mukai, T.; Yoshizawa, M.; Ohno, H.; Kato, T . Nanostructured anisotropic ion-conductive films . J. Am. Chem. Soc. , 2003 . 125 3196 - 3197 . DOI: 10.1021/ja029750u http://doi.org/10.1021/ja029750u .

Guo, M.; Zhang, M.; He, D.; Hu, J.; Wang, X.; Gong, C.; Xie, X.; Xue, Z . Comb-like solid polymer electrolyte based on polyethylene glycol-grafted sulfonated polyether ether ketone . Electrochim. Acta , 2017 . 255 396 - 404 . DOI: 10.1016/j.electacta.2017.10.033 http://doi.org/10.1016/j.electacta.2017.10.033 .

Chakraborty, S.; Jiang, X.; Hoffman, Z. J.; Sethi, G. K.; Zhu, C.; Balsara, N. P.; Villaluenga, I . Reversible changes in the grain structure and conductivity in a block copolymer electrolyte . Macromolecules , 2020 . 53 5455 - 5464 . DOI: 10.1021/acs.macromol.0c00466 http://doi.org/10.1021/acs.macromol.0c00466 .

Ji, X.; Cao, M.; Fu, X.; Liang, R.; Le, A. N.; Zhang, Q.; Zhong, M . Efficient room-temperature solid-state lithium ion conductors enabled by mixed-graft block copolymer architectures . Giant , 2020 . 3 100027 DOI: 10.1016/j.giant.2020.100027 http://doi.org/10.1016/j.giant.2020.100027 .

Phan, T. N. T.; Issa, S.; Gigmes, D . Poly(ethylene oxide)-based block copolymer electrolytes for lithium metal batteries . Polym. Int. , 2019 . 68 7 - 13 . DOI: 10.1002/pi.5677 http://doi.org/10.1002/pi.5677 .

Villaluenga, I.; Chen, X. C.; Devaux, D.; Hallinan, D. T.; Balsara, N. P . Nanoparticle-driven assembly of highly conducting hybrid block copolymer electrolytes . Macromolecules , 2015 . 48 358 - 364 . DOI: 10.1021/ma502234y http://doi.org/10.1021/ma502234y .

Jo, G.; Jeon, H.; Park, M. J . Synthesis of polymer electrolytes based on poly(ethylene oxide) and an anion-stabilizing hard polymer for enhancing conductivity and cation transport . ACS Macro Lett. , 2015 . 4 225 - 230 . DOI: 10.1021/mz500717j http://doi.org/10.1021/mz500717j .

Young, W.-S.; Albert, J. N. L.; Schantz, A. B.; Epps, T. H . Mixed-salt effects on the ionic conductivity of lithium-doped peo-containing block copolymers . Macromolecules , 2011 . 44 8116 - 8123 . DOI: 10.1021/ma2013157 http://doi.org/10.1021/ma2013157 .

Chopade, S. A.; Au, J. G.; Li, Z.; Schmidt, P. W.; Hillmyer, M. A.; Lodge, T. P . Robust polymer electrolyte membranes with high ambient-temperature lithium-ion conductivity via polymerization-induced microphase separation . ACS Appl. Mater. Interfaces , 2017 . 9 14561 - 14565 . DOI: 10.1021/acsami.7b02514 http://doi.org/10.1021/acsami.7b02514 .

Yan, Y.; Kong, Q. R.; Sun, C. C.; Yuan, J. J.; Huang, Z.; Fang, L. F.; Zhu, B. K.; Song, Y. Z . Copolymer-assisted polypropylene separator for fast and uniform lithium ion transport in lithium-ion batteries . Chinese J. Polym. Sci. , 2020 . 38 1313 - 1324 . DOI: 10.1007/s10118-020-2455-1 http://doi.org/10.1007/s10118-020-2455-1 .

Liu, D.; Tang, Z.; Luo, L.; Yang, W.; Liu, Y.; Shen, Z.; Fan, X. H . Self-healing solid polymer electrolyte with high ion conductivity and super stretchability for all-solid zinc-ion batteries . ACS Appl. Mater. Interfaces , 2021 . 13 36320 - 36329 . DOI: 10.1021/acsami.1c09200 http://doi.org/10.1021/acsami.1c09200 .

Wanakule, N. S.; Panday, A.; Mullin, S. A.; Gann, E.; Hexemer, A.; Balsara, N. P . Ionic conductivity of block copolymer electrolytes in the vicinity of order-disorder and order-order transitions . Macromolecules , 2009 . 42 5642 - 5651 . DOI: 10.1021/ma900401a http://doi.org/10.1021/ma900401a .

Cheng, S.; Smith, D. M.; Li, C. Y . How does nanoscale crystalline structure affect ion transport in solid polymer electrolytes? . Macromolecules , 2014 . 47 3978 - 3986 . DOI: 10.1021/ma500734q http://doi.org/10.1021/ma500734q .

Sethi, G. K.; Chakraborty, S.; Zhu, C.; Schaible, E.; Villaluenga, I.; Balsara, N. P . Effect of crystallization of the polyhedral oligomeric silsesquioxane block on self-assembly in hybrid organic-inorganic block copolymers with salt . Giant , 2021 . 6 100055 DOI: 10.1016/j.giant.2021.100055 http://doi.org/10.1016/j.giant.2021.100055 .

Wu, F.; Luo, L.; Tang, Z.; Liu, D.; Shen, Z.; Fan, X. H . Block copolymer electrolytes with excellent properties in a wide temperature range . ACS Appl. Energy Mater. , 2020 . 3 6536 - 6543 . DOI: 10.1021/acsaem.0c00737 http://doi.org/10.1021/acsaem.0c00737 .

Lopez, J.; Sun, Y.; Mackanic, D. G.; Lee, M.; Foudeh, A. M.; Song, M. S.; Cui, Y.; Bao, Z . A dual-crosslinking design for resilient lithium-ion conductors . Adv. Mater. , 2018 . 30 1804142 DOI: 10.1002/adma.201804142 http://doi.org/10.1002/adma.201804142 .

Mackanic, D. G.; Michaels, W.; Lee, M.; Feng, D.; Lopez, J.; Qin, J.; Cui, Y.; Bao, Z . Crosslinked poly(tetrahydrofuran) as a loosely coordinating polymer electrolyte . Adv. Energy Mater. , 2018 . 8 1800703 DOI: 10.1002/aenm.201800703 http://doi.org/10.1002/aenm.201800703 .

Kim, G. T.; Appetecchi, G. B.; Carewska, M.; Joost, M.; Balducci, A.; Winter, M.; Passerini, S . UV cross-linked, lithium-conducting ternary polymer electrolytes containing ionic liquids . J. Power Sources , 2010 . 195 6130 - 6137 . DOI: 10.1016/j.jpowsour.2009.10.079 http://doi.org/10.1016/j.jpowsour.2009.10.079 .

Choudhury, S.; Mangal, R.; Agrawal, A.; Archer, L. A . A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles . Nat. Commun. , 2015 . 6 10101 DOI: 10.1038/ncomms10101 http://doi.org/10.1038/ncomms10101 .

Zhang, Y. D.; Fan, X. H.; Shen, Z.; Zhou, Q. F . Thermoreversible ion gel with tunable modulus self-assembled by a liquid crystalline triblock copolymer in ionic liquid . Macromolecules , 2015 . 48 4927 - 4935 . DOI: 10.1021/acs.macromol.5b01103 http://doi.org/10.1021/acs.macromol.5b01103 .

Tang, Z.; Lyu, X.; Luo, L.; Shen, Z.; Fan, X. H . White-light-emitting AIE/Eu 3+ -doped ion gel with multistimuli-responsive properties . ACS Appl. Mater. Interfaces , 2020 . 45420 - 45428 . DOI: 10.1021/acsami.0c15656 http://doi.org/10.1021/acsami.0c15656 .

Vatankhah-Varnosfaderani, M.; Keith, A. N.; Cong, Y.; Liang, H.; Rosenthal, M.; Sztucki, M.; Clair, C.; Magonov, S.; Ivanov, D. A.; Dobrynin, A. V.; Sheiko, S. S . Chameleon-like elastomers with molecularly encoded strain-adaptive stiffening and coloration . Science , 2018 . 359 1509 - 1513 . DOI: 10.1126/science.aar5308 http://doi.org/10.1126/science.aar5308 .

Keith, A. N.; Vatankhah-Varnosfaderani, M.; Clair, C.; Fahimipour, F.; Dashtimoghadam, E.; Lallam, A.; Sztucki, M.; Ivanov, D. A.; Liang, H.; Dobrynin, A. V.; Sheiko, S. S . Bottlebrush bridge between soft gels and firm tissues . ACS Central Sci. , 2020 . 6 413 - 419 . DOI: 10.1021/acscentsci.9b01216 http://doi.org/10.1021/acscentsci.9b01216 .

Liang, H.; Wang, Z.; Dobrynin, A. V . Strain-adaptive self-assembled networks of linear-bottlebrush-linear copolymers . Macromolecules , 2019 . 52 8617 - 8624 . DOI: 10.1021/acs.macromol.9b01859 http://doi.org/10.1021/acs.macromol.9b01859 .

Cong, Y.; Vatankhah-Varnosfaderani, M.; Karimkhani, V.; Keith, A. N.; Leibfarth, F. A.; Martinez, M. R.; Matyjaszewski, K.; Sheiko, S. S . Understanding the synthesis of linear-bottlebrush-linear block copolymers: toward plastomers with well-defined mechanical properties . Macromolecules , 2020 . 53 8324 - 8332 . DOI: 10.1021/acs.macromol.0c01083 http://doi.org/10.1021/acs.macromol.0c01083 .

Tang, Z.; Lyu, X.; Xiao, A.; Shen, Z.; Fan, X . High-performance double-network ion gels with fast thermal healing capability via dynamic covalent bonds . Chem. Mater. , 2018 . 30 7752 - 7759 . DOI: 10.1021/acs.chemmater.8b03104 http://doi.org/10.1021/acs.chemmater.8b03104 .

Feng, L.; Wang, K.; Zhang, X.; Sun, X.; Li, C.; Ge, X.; Ma, Y . Flexible solid-state supercapacitors with enhanced performance from hierarchically graphene nanocomposite electrodes and ionic liquid incorporated gel polymer electrolyte . Adv. Funct. Mater. , 2018 . 28 1704463 DOI: 10.1002/adfm.201704463 http://doi.org/10.1002/adfm.201704463 .

Gwee, L.; Choi, J. H.; Winey, K. I.; Elabd, Y. A . Block copolymer/ionic liquid films: the effect of ionic liquid composition on morphology and ion conduction . Polymer , 2010 . 51 5516 - 5524 . DOI: 10.1016/j.polymer.2010.09.026 http://doi.org/10.1016/j.polymer.2010.09.026 .

Shin, J. H.; Henderson, W. A.; Passerini, S . Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes. . Electrochem. Commun. , 2003 . 5 1016 - 1020 . DOI: 10.1016/j.elecom.2003.09.017 http://doi.org/10.1016/j.elecom.2003.09.017 .

Tafur, J. P.; Fernández Romero, A. J. Electrical and spectroscopic characterization of PVDF-HFP and TFSI—ionic liquids-based gel polymer electrolyte membranes . Influence of ZnTf 2 salt . J. Membr. Sci. , 2014 . 469 499 - 506 . DOI: 10.1016/j.memsci.2014.07.007 http://doi.org/10.1016/j.memsci.2014.07.007 .

Tsao, C. H.; Su, H. M.; Huang, H. T.; Kuo, P. L.; Teng, H . Immobilized cation functional gel polymer electrolytes with high lithium transference number for lithium ion batteries . J. Membr. Sci. , 2018 . 572 382 - 389 . DOI: 10.1016/j.memsci.2018.11.033 http://doi.org/10.1016/j.memsci.2018.11.033 .

Zhang, D. Z.; Ren, Y. Y.; Hu, Y.; Li, L.; Yan, F . Ionic liquid/poly(ionic liquid)-based semi-solid state electrolytes for lithium-ion batteries . Chinese J. Polym. Sci. , 2020 . 38 506 - 513 . DOI: 10.1007/s10118-020-2390-1 http://doi.org/10.1007/s10118-020-2390-1 .

Li, Z.; Wu, Z.; Mo, G.; Xing, X.; Liu, P . A small-angle X-ray scattering station at beijing synchrotron radiation facility . Instrum. Sci. Technol. , 2014 . 42 128 - 141 . DOI: 10.1080/10739149.2013.845845 http://doi.org/10.1080/10739149.2013.845845 .

Varlas, S.; Lawrenson, S. B.; Arkinstall, L. A.; O’Reilly, R. K.; Foster, J. C . Self-assembled nanostructures from amphiphilic block copolymers prepared via ring-opening metathesis polymerization (ROMP) . Prog. Polym. Sci. , 2020 . 107 101278 DOI: 10.1016/j.progpolymsci.2020.101278 http://doi.org/10.1016/j.progpolymsci.2020.101278 .

Xu, Y.; Zhang, S.; Liang, T.; Yao, Z.; Wang, X.; Gu, C.; Xia, X.; Tu, J . Porous polyamide skeleton-reinforced solid-state electrolyte: enhanced flexibility, safety, and electrochemical performance . ACS Appl. Mater. Interfaces , 2021 . DOI: 10.1021/acsami.1c00084 http://doi.org/10.1021/acsami.1c00084 .

Jia, H.; Onishi, H.; Wagner, R.; Winter, M.; Cekic-Laskovic, I . An intrinsically safe gel polymer electrolyte comprising flame retarding polymer matrix for lithium ion battery application . ACS Appl. Mater. Interfaces , 2018 . 10 42348 - 42355 . DOI: 10.1021/acsami.8b15505 http://doi.org/10.1021/acsami.8b15505 .

Olmedo-Martínez, J. L.; Meabe, L.; Riva, R.; Guzmán-González, G.; Porcarelli, L.; Forsyth, M.; Mugica, A.; Calafel, I.; Müller, A. J.; Lecomte, P.; Jérôme, C.; Mecerreyes, D . Flame retardant polyphosphoester copolymers as solid polymer electrolyte for lithium batteries . Polym. Chem. , 2021 . 12 3441 - 3450 . DOI: 10.1039/D1PY00344E http://doi.org/10.1039/D1PY00344E .

Simone, P. M.; Lodge, T. P . Phase behavior and ionic conductivity of concentrated solutions of polystyrene-poly(ethylene oxide) diblock copolymers in an ionic liquid . ACS Appl. Mater. Interfaces , 2009 . 1 2812 - 2820 . DOI: 10.1021/am900555f http://doi.org/10.1021/am900555f .

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