Payne Effect and Weak Overshoot in Rubber Nanocomposites

Zhi-Yun Li; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-021-2643-7

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Payne Effect and Weak Overshoot in Rubber Nanocomposites

Papers | Updated：2021-11-04

- Payne Effect and Weak Overshoot in Rubber Nanocomposites
- Chinese Journal of Polymer Science Vol. 40, Issue 1, Pages: 85-92(2022)
- Affiliations：
  
  MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  s_yh0411@zju.edu.cn (Y.H.S.)
  zhengqiang@zju.edu.cn (Q.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U1908221, 51873190 and 51790503) and the Fundamental Research Funds for the Central Universities (No. 2020XZZX002-08).
- DOI：10.1007/s10118-021-2643-7
  CLC：
- Received：29 June 2021，
  
  Revised：2021-8-10，
  
  Accepted：24 August 2021，
  
  Online First：04 November 2021，
  
  Published：01 January 2022
- Accepted：
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Li, Z. Y.; Song, Y. H.; Zheng, Q. Payne effect and weak overshoot in rubber nanocomposites. Chinese J. Polym. Sci. 2022, 40, 85–92

Zhi-Yun Li, Yi-Hu Song, Qiang Zheng. Payne Effect and Weak Overshoot in Rubber Nanocomposites[J]. Chinese Journal of Polymer Science, 2022, 40(1): 85-92.
Li, Z. Y.; Song, Y. H.; Zheng, Q. Payne effect and weak overshoot in rubber nanocomposites. Chinese J. Polym. Sci. 2022, 40, 85–92 DOI： 10.1007/s10118-021-2643-7.

Zhi-Yun Li, Yi-Hu Song, Qiang Zheng. Payne Effect and Weak Overshoot in Rubber Nanocomposites[J]. Chinese Journal of Polymer Science, 2022, 40(1): 85-92. DOI： 10.1007/s10118-021-2643-7.

摘要

Abstract

Payne effect and its associated weak overshoot are of importance for understanding and regulating the softening of rubber nanocomposites under large amplitude oscillations. Herein

Payne effect in diverse filled vulcanizates is investigated for generalizing the common characteristics. Master curves of strain amplitude dependent storage modulus are created with respect to microscopic strain amplitude of the matrix

revealing a matrix-dominated elastic nonlinearity being independent of type and dispersity of filler

crosslinking density and sol fraction of matrix and filler-rubber interfacial interactions. However

carbonaceous fillers with higher affinity to the rubber matrices yield lower strain amplification and higher overshoot behavior in comparison with siliceous silica. The investigation would be illuminating for preparing rubber nanocomposites with optimized reinforcement and softening performances.

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Keywords

references

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