A Fast and Room-temperature Self-healing Thermal Conductive Polymer Composite

De-Wei Yue; Hong-Qin Wang; Han-Qing Tao; Peng Zheng; Cheng-Hui Li; Jing-Lin Zuo

doi:10.1007/s10118-021-2620-1

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A Fast and Room-temperature Self-healing Thermal Conductive Polymer Composite

ARTICLE | Updated：2021-07-25

- A Fast and Room-temperature Self-healing Thermal Conductive Polymer Composite
- Chinese Journal of Polymer Science Vol. 39, Issue 10, Pages: 1328-1336(2021)
- Affiliations：
  
  State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
- Author bio：
  
  chli@nju.edu.cn
- Funds：
- DOI：10.1007/s10118-021-2620-1
  CLC：
- Received：09 May 2021，
  
  Accepted：14 June 2021，
  
  Online First：25 July 2021，
  
  Published：20 August 2021
- Accepted：
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Yue, D. W.; Wang, H. Q.; Tao, H. Q.; Zheng, P.; Li, C. H.; Zuo, J. L. A fast and room-temperature self-healing thermal conductive polymer composite. Chinese J. Polym. Sci. 2021, 39, 1328–1336

De-Wei Yue, Hong-Qin Wang, Han-Qing Tao, et al. A Fast and Room-temperature Self-healing Thermal Conductive Polymer Composite[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1328-1336.
Yue, D. W.; Wang, H. Q.; Tao, H. Q.; Zheng, P.; Li, C. H.; Zuo, J. L. A fast and room-temperature self-healing thermal conductive polymer composite. Chinese J. Polym. Sci. 2021, 39, 1328–1336 DOI： 10.1007/s10118-021-2620-1.

De-Wei Yue, Hong-Qin Wang, Han-Qing Tao, et al. A Fast and Room-temperature Self-healing Thermal Conductive Polymer Composite[J]. Chinese Journal of Polymer Science, 2021, 39(10): 1328-1336. DOI： 10.1007/s10118-021-2620-1.

摘要

Abstract

Thermal conducting materials may be damaged during long-term use

resulting in the increase of thermal resistance and therefore inefficient heat dissipation. The introduction of self-healing ability may solve this problem

but the realization of fast and room-temperature self-healing in thermal conducting composites is quite challenging. Herein

we choose a flexible poly(dimethylsiloxane) polymer material (

PDMS-COOH

) as the matrix and graphene nanosheets as the thermal conductive filler to prepare a new kind of thermal conductive polymer composite (

PDMS-COOH-CG

) that can quickly self-heal at room temperature. The thermal conductivity of

PDMS-COOH-CG

with 10% of graphene content is 0.48 W·m

−1

·K

−1

which is 16 times that of

PDMS-COOH

(0.03 W·m

−1

·K

−1

). At room temperature

self-healing efficiency of

PDMS-COOH-CG

based on tensile strength can be 53.8% for 30 s and 84.6% for 24 h. Dynamic infrared thermal imaging dipicted that after 2 min of self-healing at room temperature

the thermal conduction temperature near the damage was basically restored to the level of the pristine sample.

关键词

Keywords

references

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