Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by <italic style="font-style: italic">in Situ</italic> Halogen Exchange

Dan-Ni Gao; Yu-Lai Zhao; Jing-Yu Cai; Lin-Xi Hou; Long-Qiang Xiao

doi:10.1007/s10118-021-2611-2

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Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by in Situ Halogen Exchange

ARTICLE | Updated：2021-07-20

- Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by in Situ Halogen Exchange
- Chinese Journal of Polymer Science Vol. 39, Issue 9, Pages: 1161-1168(2021)
- Affiliations：
  
  a.Department of Materials-Oriented Chemical Engineering, School of Chemical Engineering, Fuzhou University, Fuzhou 350116, China
  b.Qingyuan Innovation Laboratory, Quanzhou 362801, China
  c.Fujian Key Laboratory of Advanced Manufacturing Technology of Specialty Chemicals, Fuzhou University, Fuzhou 350116, China
- Author bio：
  
  lxhou@fzu.edu.cn (L.X.H.)
  xiaolq@fzu.edu.cn (L.Q.X.)
- Funds：
- DOI：10.1007/s10118-021-2611-2
  CLC：
- Received：27 April 2021，
  
  Revised：2021-5-18，
  
  Accepted：22 May 2021，
  
  Online First：20 July 2021，
  
  Published：18 July 2021
- Accepted：
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Gao, D. N.; Zhao, Y. L.; Cai, J. Y.; Hou, L. X.; Xiao, L. Q. Reversible chain transfer catalyzed polymerization with alkyl iodides generated from alkyl bromides by in situ halogen exchange. Chinese J. Polym. Sci. 2021, 39, 1161–1168

Dan-Ni Gao, Yu-Lai Zhao, Jing-Yu Cai, et al. Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by in Situ Halogen Exchange[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1161-1168. DOI: 10.1007/s10118-021-2611-2.
Gao, D. N.; Zhao, Y. L.; Cai, J. Y.; Hou, L. X.; Xiao, L. Q. Reversible chain transfer catalyzed polymerization with alkyl iodides generated from alkyl bromides by in situ halogen exchange. Chinese J. Polym. Sci. 2021, 39, 1161–1168 DOI： 10.1007/s10118-021-2611-2.

Dan-Ni Gao, Yu-Lai Zhao, Jing-Yu Cai, et al. Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by in Situ Halogen Exchange[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1161-1168. DOI: 10.1007/s10118-021-2611-2. DOI：

摘要

Abstract

Reversible chain transfer catalyzed polymerization (RTCP) is a practical and efficient process for the precise synthesis of polymers with special architecture by using simple phenols (2

6-trimethylphenol

TMP) or hydrocarbons (xanthene

XT) as efficient organocatalysts. Herein

alkyl iodide (R-I)

which was generated from

in situ

bromine-iodine transformation of alkyl bromide (R-Br) with sodium iodide (NaI)

was served as initiator to mediate RTCP with TMP or XT. MMA and other functional methacrylates

including GMA

DEAM

DMAEMA and BzMA

were successfully initiated by combining organocatalysts and azo initiators to yield polymers with low-polydispersity (

=1.1−1.5) and ideal monomer conversions (50%−90%) at moderate temperature. Moreover

3-armstar polymers were also obtained by this method. The high chain-end fidelity of the obtained poly(methyl methacrylate) with iodine as chain-end group (PMMA-I) was confirmed by chain-extension reaction. The environmentally friendly initiators and organocatalysts exhibit powerful polymerization properties toward RTCP

providing a significant method to synthesize functional polymers.

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Keywords

references

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Reversible Chain Transfer Catalyzed Polymerization with Alkyl Iodides Generated from Alkyl Bromides by in Situ Halogen Exchange

DOI：10.1007/s10118-021-2611-2

摘要

Abstract

关键词

Keywords

references