Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization

Jin-Ying Wang; Yuan-Yuan Ni; Jian-Nan Cheng; Li-Fen Zhang; Zhen-Ping Cheng

doi:10.1007/s10118-021-2602-3

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Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization

ARTICLE | Updated：2021-07-20

- Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization
- Chinese Journal of Polymer Science Vol. 39, Issue 9, Pages: 1155-1160(2021)
- Affiliations：
  
  State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  zhanglifen@suda.edu.cn (L.F.Z.)
  chengzhenping@suda.edu.cn (Z.P.C.)
- Funds：
- DOI：10.1007/s10118-021-2602-3
  CLC：
- Received：31 March 2021，
  
  Revised：2021-4-29，
  
  Accepted：04 May 2021，
  
  Online First：20 July 2021，
  
  Published：18 July 2021
- Accepted：
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Wang, J. Y.; Ni, Y. Y.; Cheng, J. N.; Zhang, L. F.; Cheng, Z. P. Molar mass dispersity control by iodine-mediated reversible-deactivation radical polymerization. Chinese J. Polym. Sci. 2021, 39, 1155–1160

Jin-Ying Wang, Yuan-Yuan Ni, Jian-Nan Cheng, et al. Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1155-1160.
Wang, J. Y.; Ni, Y. Y.; Cheng, J. N.; Zhang, L. F.; Cheng, Z. P. Molar mass dispersity control by iodine-mediated reversible-deactivation radical polymerization. Chinese J. Polym. Sci. 2021, 39, 1155–1160 DOI： 10.1007/s10118-021-2602-3.

Jin-Ying Wang, Yuan-Yuan Ni, Jian-Nan Cheng, et al. Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization[J]. Chinese Journal of Polymer Science, 2021, 39(9): 1155-1160. DOI： 10.1007/s10118-021-2602-3.

摘要

Abstract

Dispersity (

) of polymers has a great effect on the properties of polymeric materials

and therefore how to control

is very important but still a huge challenge in polymer synthesis

especially for reversible-deactivation radical polymerization (RDRP) strategy. Herein

we successfully developed a novel strategy to adjust

of polymers by visible light-controlled reversible complexation mediated living radical polymerization (RCMP) and combination of single-electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP) at room temperature. In RCMP system

2-iodo-2-methylpropionitrile (CP-I) and ethyl 2-iodo-2-phenylacetate (EIPA) were used as alkyl iodide initiators

by using methyl methacrylate (MMA) as the model monomer and

-butylacrylate (BA) as the end-capping reagent to regulate

of polymers. Subsequently

we successfully prepared the block copolymer PMMA-

-PBA with adjustable

by reactivating the polymer end-chains

via

SET-DTLRP in the presence of copper wire

fully demonstrating that it is a promising strategy that can keep the "living" feature of polymers while regulating their molar mass dispersities easily.

关键词

Keywords

references

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