Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials

Bo-Han Cao; Wu Chen; Wan-Yuan Wei; Yu-Lan Chen; Yuan Yuan

doi:10.1007/s10118-021-2601-4

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Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials

ARTICLE | Updated：2021-07-01

- Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials
- Chinese Journal of Polymer Science Vol. 39, Issue 11, Pages: 1403-1411(2021)
- Affiliations：
  
  Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, China
- Author bio：
  
  yulan.chen@tju.edu.cn (Y.L.C.)
  yyuan@tju.edu.cn (Y.Y.)
- Funds：
- DOI：10.1007/s10118-021-2601-4
  CLC：
- Received：25 March 2021，
  
  Revised：2021-4-29，
  
  Accepted：04 May 2021，
  
  Online First：01 July 2021，
  
  Published：18 September 2021
- Accepted：
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Cao, B. H.; Chen, W.; Wei, W. Y.; Chen, Y. L.; Yuan, Y. Carbon dots intensified mechanochemiluminescence from waterborne polyurethanes as tunable force sensing materials. Chinese J. Polym. Sci. 2021, 39, 1403–1411

Bo-Han Cao, Wu Chen, Wan-Yuan Wei, et al. Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials[J]. Chinese Journal of Polymer Science, 2021, 39(11): 1403-1411.
Cao, B. H.; Chen, W.; Wei, W. Y.; Chen, Y. L.; Yuan, Y. Carbon dots intensified mechanochemiluminescence from waterborne polyurethanes as tunable force sensing materials. Chinese J. Polym. Sci. 2021, 39, 1403–1411 DOI： 10.1007/s10118-021-2601-4.

Bo-Han Cao, Wu Chen, Wan-Yuan Wei, et al. Carbon Dots Intensified Mechanochemiluminescence from Waterborne Polyurethanes as Tunable Force Sensing Materials[J]. Chinese Journal of Polymer Science, 2021, 39(11): 1403-1411. DOI： 10.1007/s10118-021-2601-4.

摘要

Abstract

2-Dioxetane is a well-known chemiluminescent mechanophore allowing real-time monitoring of polymer chain scission

but usually suffers from fluorescence quenching in polar environments. Herein

a series of mechanochemiluminescent waterborne polyurethanes/carbon dots composites (

WPU-CDs

) have been synthesized by incorporating fluorescent

s to promote the energy transfer process in different environments. The resulting bulk

WPU

and in particular

their swollen films filled with a large amount of polar solvents (water and ionic liquid) emit intense mechanochemiluminescence. Thus force-induced covalent bond scission and stress distribution within these different

WPU-CDs

films can be sensitively visualized. Furthermore

the ionic liquid containing films exhibited both electrical and luminescent signal changes under stretching

which offer a new kind of force sensor responsive at a broad detecting strain range and for multi-mode strain analysis. This study is expected to stimulate new research endeavors in mechanistic insight on waterborne polyurethanes and the corresponding stretchable sensing devices.

关键词

Keywords

references

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