A Triple Crosslinking Design toward Epoxy Vitrimers and Carbon Fiber Composites of High Performance and Multi-shape Memory

Hao Wang; Han-Chao Liu; Yao Zhang; Hu Xu; Bi-Qiang Jin; Zhen-Xing Cao; Hai-Tao Wu; Guang-Su Huang; Jin-Rong Wu

doi:10.1007/s10118-021-2538-7

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A Triple Crosslinking Design toward Epoxy Vitrimers and Carbon Fiber Composites of High Performance and Multi-shape Memory

ARTICLE | Updated：2021-01-05

- A Triple Crosslinking Design toward Epoxy Vitrimers and Carbon Fiber Composites of High Performance and Multi-shape Memory
- Chinese Journal of Polymer Science Vol. 39, Issue 6, Pages: 736-744(2021)
- Affiliations：
  
  a.State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
  b.Changzhou Architectural Research Institute Group CO. LTD, Changzhou 213001, China
- Author bio：
  
  wujinrong@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-021-2538-7
  CLC：
- Received：09 October 2020，
  
  Revised：2020-12-1，
  
  Accepted：03 December 2020，
  
  Online First：05 January 2021，
  
  Published：15 April 2021
- Accepted：
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Wang, H.; Liu, H. C.; Zhang, Y.; Xu, H.; Jin, B. Q.; Cao, Z. X.; Wu, H. T.; Huang, G. S.; Wu, J. R. A triple crosslinking design toward epoxy vitrimers and carbon fiber composites of high performance and multi-shape memory. Chinese J. Polym. Sci. 2021, 39, 736–744

Hao Wang, Han-Chao Liu, Yao Zhang, et al. A Triple Crosslinking Design toward Epoxy Vitrimers and Carbon Fiber Composites of High Performance and Multi-shape Memory[J]. Chinese Journal of Polymer Science, 2021, 39(6): 736-744.
Wang, H.; Liu, H. C.; Zhang, Y.; Xu, H.; Jin, B. Q.; Cao, Z. X.; Wu, H. T.; Huang, G. S.; Wu, J. R. A triple crosslinking design toward epoxy vitrimers and carbon fiber composites of high performance and multi-shape memory. Chinese J. Polym. Sci. 2021, 39, 736–744 DOI： 10.1007/s10118-021-2538-7.

Hao Wang, Han-Chao Liu, Yao Zhang, et al. A Triple Crosslinking Design toward Epoxy Vitrimers and Carbon Fiber Composites of High Performance and Multi-shape Memory[J]. Chinese Journal of Polymer Science, 2021, 39(6): 736-744. DOI： 10.1007/s10118-021-2538-7.

摘要

Abstract

It remains a challenge to use a simple approach to fabricate a multi-shape memory material with high mechanical performances. Here

we report a triple crosslinking design to construct a multi-shape memory epoxy vitrimer (MSMEV)

which exhibits high mechanical properties

multi-shape memory property and malleability. The triple crosslinking network is formed by reacting diglycidyl ether of bisphenol F (DGEBF) with 4-aminophenyl disulfide

-aminopropyltriethoxysilane (APTS) and poly(propylene glycol) bis(2-aminopropyl ether) (D2000). The triple crosslinking manifests triple functions: the disulfide bonds and the silyl ether linkages enable malleability of the epoxy network; the silyl ether linkages impart the network with high heterogeneity and broaden the glass transition region

leading to multi-shape memory property; a small amount of D2000 increases the modulus difference between the glassy and rubbery states

thereby improving the shape fixity ratio. Meanwhile

the high crosslinking density and rigid structure provide the MSMEV with high tensile strength and Young’s modulus. Moreover

integrating carbon fibers and MSMEV results in shape memory composites. The superior mechanical properties of the composites and the recyclability of carbon fiber derived from the dissolvability of MSMEV make the composites hold great promise as structural materials in varied applications.

关键词

Keywords

references

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