

FOLLOWUS
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China
yangfengscu@126.com
Received:14 October 2020,
Revised:2020-11-10,
Accepted:29 November 2020,
Online First:06 January 2021,
Published:01 January 2021
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Zhang, D. X.; Ding, L.; Yang, F.; Lan, F.; Cao, Y.; Xiang, M. Comparison of the structural evolution of , β, polypropylene during the sequential and simultaneous biaxial stretching process. Chinese J. Polym. Sci. 2021, 39, 620–631
Dao-Xin Zhang, Lei Ding, Feng Yang, et al. Comparison of the Structural Evolution of
Zhang, D. X.; Ding, L.; Yang, F.; Lan, F.; Cao, Y.; Xiang, M. Comparison of the structural evolution of , β, polypropylene during the sequential and simultaneous biaxial stretching process. Chinese J. Polym. Sci. 2021, 39, 620–631 DOI: 10.1007/s10118-021-2534-y.
Dao-Xin Zhang, Lei Ding, Feng Yang, et al. Comparison of the Structural Evolution of
In this work
the lamellar structural evolution and microvoids variations of
β
polypropylene (
β
-PP) during the processing of two different stretching methods
sequential biaxial stretching and simultaneous biaxial stretching
were investigated in detail. It was found that different stretching methods led to significantly different lamellae deformation modes
and the microporous membranes obtained from the simultaneous biaxial stretching exhibited better mechanical properties. For the sequential biaxial stretching
abundant coarse fibers originated from the tight accumulation of the lamellae parallel to the longitudinal stretching direction
whereas the lamellae perpendicular to the stretching direction were easily deformed and separated. Those coarse fibers were difficult to be separated to form micropores during the subsequent transverse stretching process
resulting in a poor micropores distribution. However
for the simultaneous biaxial stretching
the
β
crystal had the same deformation mode
that is
the lamellae distributed in different directions were all destroyed
forming abundant microvoids and little coarse fibers.
Costa, C. M.; Lee, Y. H.; Kim, J. H.; Lee, S. Y.; Lanceros-Méndez, S. . Recent advances on separator membranes for lithium-ion battery applications: from porous membranes to solid electrolytes . Energy Storage Mater. , 2019 . 22 346 - 375 . DOI: 10.1016/j.ensm.2019.07.024 http://doi.org/10.1016/j.ensm.2019.07.024 .
Li, Y.; Pan, G.; Wang, J.; Zhang, Y.; Shi, H.; Yu, H.; Liu, Y. . Tailoring the polyamide active layer of thin-film composite forward osmosis membranes with combined cosolvents during interfacial polymerization . Ind. Eng. Chem. Res. , 2020 . 59 8230 - 8242 . DOI: 10.1021/acs.iecr.0c00682 http://doi.org/10.1021/acs.iecr.0c00682 .
Pan, L.; Wang, H.; Wu, C.; Liao, C.; Li, L. . Tannic-acid-coated polypropylene membrane as a separator for lithium-ion batteries . ACS Appl. Mater. Interfaces , 2015 . 7 16003 - 16010 . DOI: 10.1021/acsami.5b04245 http://doi.org/10.1021/acsami.5b04245 .
Park, S. H.; Kwon, S. J.; Shin, M. G.; Park, M. S.; Lee, J. S.; Park, C. H.; Park, H.; Lee, J. H. . Polyethylene-supported high performance reverse osmosis membranes with enhanced mechanical and chemical durability . Desalination , 2018 . 436 28 - 38 . DOI: 10.1016/j.desal.2018.02.007 http://doi.org/10.1016/j.desal.2018.02.007 .
Zhu, X.; Tang, X.; Luo, X.; Cheng, X.; Xu, D.; Gan, Z.; Wang, W.; Bai, L.; Li, G.; Liang, H. . Toward enhancing the separation and antifouling performance of thin-film composite nanofiltration membranes: a novel carbonate-based preoccupation strategy . J. Colloid Interface Sci. , 2020 . 571 155 - 165 . DOI: 10.1016/j.jcis.2020.03.044 http://doi.org/10.1016/j.jcis.2020.03.044 .
Lu, W.; Yuan, Z.; Zhao, Y.; Zhang, H.; Zhang, H.; Li, X. . Porous membranes in secondary battery technologies . Chem. Soc. Rev. , 2017 . 46 2199 - 2236 . DOI: 10.1039/C6CS00823B http://doi.org/10.1039/C6CS00823B .
Chu, F.; Kimura, Y. . Structure and gas permeability of microporous films prepared by biaxial drawing of β -form polypropylene . Polymer , 1996 . 37 573 - 579 . DOI: 10.1016/0032-3861(96)83143-0 http://doi.org/10.1016/0032-3861(96)83143-0 .
Luo, B.; Li, Z.; Zhang, J.; Wang, X. . Formation of anisotropic microporous isotactic polypropylene ( i PP) membrane via thermally induced phase separation . Desalination , 2008 . 233 19 - 31 . DOI: 10.1016/j.desal.2007.09.023 http://doi.org/10.1016/j.desal.2007.09.023 .
Wu, T.; Xiang, M.; Cao, Y.; Kang, J.; Yang, F. . Pore formation mechanism of β nucleated polypropylene stretched membranes . RSC Adv. , 2014 . 4 36689 - 36701 . DOI: 10.1039/C4RA03589E http://doi.org/10.1039/C4RA03589E .
Wu, G. G.; Chen, W. B.; Ding, C.; Xu, L. Y.; Liu, Z. Y.; Yang, W.; Yang, M. B. . Pore formation mechanism of oriented β polypropylene cast films during stretching and optimization of stretching methods: in situ SAXS and WAXD studies . Polymer , 2019 . 163 86 - 95 . DOI: 10.1016/j.polymer.2018.12.051 http://doi.org/10.1016/j.polymer.2018.12.051 .
Li, J. X.; Cheung, W. L.; Chan, C. M. . On deformation mechanisms of β -polypropylene 2. Changes of lamellar structure caused by tensile load . Polymer , 1999 . 40 2089 - 2102 . DOI: 10.1016/S0032-3861(98)00412-1 http://doi.org/10.1016/S0032-3861(98)00412-1 .
Xu, R. J.; Chen, X. D.; Xie, J. Y.; Cai, Q.; Lei, C. H. . Influence of melt-draw ratio on the crystalline structure and properties of polypropylene cast film and stretched microporous membrane . Ind. Eng. Chem. Res. , 2015 . 54 2991 - 2999 . DOI: 10.1021/acs.iecr.5b00215 http://doi.org/10.1021/acs.iecr.5b00215 .
Zeng, F.; Xu, R.; Ye, L.; Xiong, B.; Kang, J.; Xiang, M.; Li, L.; Sheng, X.; Hao, Z. . Effects of heat setting on the morphology and performance of polypropylene separator for lithium ion batteries . Ind. Eng. Chem. Res. , 2019 . 58 2217 - 2224 . DOI: 10.1021/acs.iecr.8b05782 http://doi.org/10.1021/acs.iecr.8b05782 .
Lee, H.; Yanilmaz, M.; Toprakci, O.; Fu, K.; Zhang, X. . A review of recent developments in membrane separators for rechargeable lithium-ion batteries . Energy Environ. Sci. , 2014 . 7 3857 - 3886 . DOI: 10.1039/C4EE01432D http://doi.org/10.1039/C4EE01432D .
Wu, G. G.; Ding, C.; Chen, W. B.; Zhang, Y.; Yang, W.; Yang, M. B. . Effect of the content of β form crystals on biaxially stretched polypropylene microporous membranes and the tuning of pore structures . Polymer , 2019 . 175 177 - 185 . DOI: 10.1016/j.polymer.2019.05.003 http://doi.org/10.1016/j.polymer.2019.05.003 .
Zhang, D.; Ding, L.; Yang, F.; Lan, F.; Cao, Y.; Xiang, M. . Effect of annealing on the microvoid formation and evolution during biaxial stretching of β nucleated isotactic polypropylene . Polym-plast. Tech. Mater. , 2020 . 59 1595 - 1607 . DOI: 10.1080/25740881.2020.1758136 http://doi.org/10.1080/25740881.2020.1758136 .
Zhang, C.; Liu, G.; Song, Y.; Zhao, Y.; Wang, D. . Structural evolution of β - i PP during uniaxial stretching studied by in situ WAXS and SAXS . Polymer , 2014 . 55 6915 - 6923 . DOI: 10.1016/j.polymer.2014.10.049 http://doi.org/10.1016/j.polymer.2014.10.049 .
Xiande, C.; Ruijie, X.; Jiayi, X.; Yuanfei, L.; Caihong, L.; Liangbin, L. . The study of room-temperature stretching of annealed polypropylene cast film with row-nucleated crystalline structure . Polymer , 2016 . 94 31 - 42 . DOI: 10.1016/j.polymer.2016.04.054 http://doi.org/10.1016/j.polymer.2016.04.054 .
Wu, G. G.; Xu, L. Y.; Chen, W. B.; Ding, C.; Liu, Z. Y.; Yang, W.; Yang, M. B. . Oriented polypropylene cast films consisted of β -transcrystals induced by the nucleating agent self-assembly and its homogeneous membranes with high porosity . Polymer , 2018 . 151 136 - 144 . DOI: 10.1016/j.polymer.2018.07.066 http://doi.org/10.1016/j.polymer.2018.07.066 .
Sadeghi, F.; Ajji, A.; Carreau, P. J. . Analysis of microporous membranes obtained from polypropylene films by stretching . J. Membr. Sci. , 2007 . 292 62 - 71 . DOI: 10.1016/j.memsci.2007.01.023 http://doi.org/10.1016/j.memsci.2007.01.023 .
Lyu, D.; Chen, R.; Lu, Y.; Men, Y. . Subsequent but independent cavitation processes in isotactic polypropylene during stretching at small- and large-strain regimes . Ind. Eng. Chem. Res. , 2018 . 57 8927 - 8937 . DOI: 10.1021/acs.iecr.8b01650 http://doi.org/10.1021/acs.iecr.8b01650 .
Lin, Y.; Chen, W.; Meng, L.; Wang, D.; Li, L. . Recent advances in post-stretching processing of polymer films with in situ synchrotron radiation X-ray scattering . Soft Matter , 2020 . 16 3599 - 3612 . DOI: 10.1039/C9SM02554E http://doi.org/10.1039/C9SM02554E .
Li, S.; Zheng, G.; Jia, Z.; Zhang, Z.; Liu, C.; Chen, J.; Li, Q.; Shen, C.; Peng, X. . Effect of stretching on β -phase content of isotactic polypropylene melt containing β -nucleating agent . J. Macromol. Sci. B , 2011 . 51 828 - 838 . .
Offord, G. T.; Armstrong, S. R.; Freeman, B. D.; Baer, E.; Hiltner, A.; Swinnea, J. S.; Paul, D. R. . Porosity enhancement in β nucleated isotactic polypropylene stretched films by thermal annealing . Polymer , 2013 . 54 2577 - 2589 . DOI: 10.1016/j.polymer.2013.03.026 http://doi.org/10.1016/j.polymer.2013.03.026 .
Wu, T.; Xiang, M.; Cao, Y.; Yang, F. . Influence of annealing on stress-strain behaviors and performances of β nucleated polypropylene stretched membranes . J. Polym. Res. , 2014 . 21 598 .
Yang, S.; Gu, J.; Yin, Y. . A biaxial stretched β -isotactic polypropylene microporous membrane for lithium-ion batteries . J. Appl. Polym. Sci. , 2018 . 135 45825 .
Yang, F.; Wu, T.; Xiang, M.; Cao, Y. . Deformation and pore formation mechanism of β nucleated polypropylene with different supermolecular structures . Eur. Polym. J. , 2017 . 91 134 - 148 . DOI: 10.1016/j.eurpolymj.2017.03.059 http://doi.org/10.1016/j.eurpolymj.2017.03.059 .
Ding, L.; Ge, Q.; Xu, G.; Wu, T.; Yang, F.; Xiang, M. . Influence of oriented β -lamellae on deformation and pore formation in β -nucleated polypropylene . J. Polym. Sci., Part B: Polym. Phys. , 2017 . 55 1745 - 1759 . DOI: 10.1002/polb.24423 http://doi.org/10.1002/polb.24423 .
Zhu, Y.; Zhao, Y.; Fu, Q. . Toward uniform pore-size distribution and high porosity of isotactic polypropylene microporous membrane by adding a small amount of ultrafine full-vulcanized powder rubber . Polymer , 2016 . 103 405 - 414 . DOI: 10.1016/j.polymer.2016.09.023 http://doi.org/10.1016/j.polymer.2016.09.023 .
Bao, R.; Ding, Z.; Zhong, G.; Yang, W.; Xie, B.; Yang, M. . Deformation-induced morphology evolution during uniaxial stretching of isotactic polypropylene: effect of temperature . Colloid Polym. Sci. , 2012 . 290 261 - 274 . .
Bao, R. Y.; Ding, Z. T.; Liu, Z. Y.; Yang, W.; Xie, B. H.; Yang, M. B. . Deformation-induced structure evolution of oriented β -polypropylene during uniaxial stretching . Polymer , 2013 . 54 1259 - 1268 . DOI: 10.1016/j.polymer.2012.12.050 http://doi.org/10.1016/j.polymer.2012.12.050 .
Kurihara, H.; Kitade, S.; Ichino, K.; Akiba, I.; Sakurai, K. . Elongation induced β - to α -crystalline transformation and microvoid formation in isotactic polypropylene as revealed by time-resolved WAXS/SAXS . Polym. J. , 2018 . 51 199 - 209 . .
Chen, Q.; Wang, Z.; Zhang, S.; Cao, Y.; Chen, J. . Structure evolution and deformation behavior of polyethylene film during biaxial stretching . ACS Omega , 2020 . 5 655 - 666 . DOI: 10.1021/acsomega.9b03250 http://doi.org/10.1021/acsomega.9b03250 .
Jariyasakoolroj, P.; Tashiro, K.; Wang, H.; Yamamoto, H.; Chinsirikul, W.; Kerddonfag, N.; Chirachanchai, S. . Isotropically small crystalline lamellae induced by high biaxial-stretching rate as a key microstructure for super-tough polylactide film . Polymer , 2015 . 68 234 - 245 . DOI: 10.1016/j.polymer.2015.05.006 http://doi.org/10.1016/j.polymer.2015.05.006 .
Zhang, D.; Ding, L.; Yang, F.; Lan, F.; Cao, Y.; Xiang, M. . Structural evolution of β - i PP with different supermolecular structures during the simultaneous biaxial stretching process . Polym. J. , 2021 . 53 331 - 344 . DOI: 10.1038/s41428-020-00430-6 http://doi.org/10.1038/s41428-020-00430-6 .
Chen, Z.; Kang, W.; Kang, J.; Chen, J.; Yang, F.; Cao, Y.; Xiang, M. . Non-isothermal crystallization behavior and melting behavior of Ziegler-Natta isotactic polypropylene with different stereo-defect distribution nucleated with bi-component β -nucleation agent . Polym. Bull. , 2015 . 72 3283 - 3303 . DOI: 10.1007/s00289-015-1466-5 http://doi.org/10.1007/s00289-015-1466-5 .
Chen, X.; Lv, F.; Su, F.; Ji, Y.; Meng, L.; Wan, C.; Lin, Y.; Li, X.; Li, L. . Deformation mechanism of i PP under uniaxial stretching over a wide temperature range: an in situ synchrotron radiation SAXS/WAXS study . Polymer , 2017 . 118 12 - 21 . DOI: 10.1016/j.polymer.2017.04.054 http://doi.org/10.1016/j.polymer.2017.04.054 .
Bai, H.; Wang, Y.; Zhang, Z.; Han, L.; Li, Y.; Liu, L.; Zhou, Z.; Men, Y. . Influence of annealing on microstructure and mechanical properties of isotactic polypropylene with β -phase nucleating agent . Macromolecules , 2009 . 42 6647 - 6655 . DOI: 10.1021/ma9001269 http://doi.org/10.1021/ma9001269 .
Xiong, B.; Kang, J.; Chen, R.; Men, Y. . Initiation of cavitation upon drawing of pre-oriented polypropylene film: in situ SAXS and WAXD studies . Polymer , 2017 . 128 57 - 64 . DOI: 10.1016/j.polymer.2017.09.017 http://doi.org/10.1016/j.polymer.2017.09.017 .
Jones, A. T.; Aizlewood, J. M.; Beckett, D. R. . Crystalline forms of isotactic polypropylene . Makromol. Chem. , 1964 . 75 134 - 158 . DOI: 10.1002/macp.1964.020750113 http://doi.org/10.1002/macp.1964.020750113 .
Hermans, P. H.; Platzek, P. . Beitrge zur Kenntnis des Deformationsmechanismus und der Feinstruktur der Hydratzellulose . Kolloid-Zeitschrift , 1939 . 88 68 - 72 . DOI: 10.1007/BF01518890 http://doi.org/10.1007/BF01518890 .
Lu, X.; Li, X. . Preparation of polyvinylidene fluoride membrane via a thermally induced phase separation using a mixed diluent . J. Appl. Polym. Sci. , 2009 . 114 1213 - 1219 . DOI: 10.1002/app.30184 http://doi.org/10.1002/app.30184 .
Chen, Q.; Chen, D.; Kang, J.; Cao, Y.; Chen, J. . Structure evolution of polyethylene in sequential biaxial stretching along the first tensile direction . Ind. Eng. Chem. Res. , 2019 . 58 12419 - 12430 . DOI: 10.1021/acs.iecr.9b01733 http://doi.org/10.1021/acs.iecr.9b01733 .
Fischer, S.; Diesner, T.; Rieger, B.; Marti, O. . Simulating and evaluating small-angle X-ray scattering of micro-voids in polypropylene during mechanical deformation . J. Appl. Crystallogr. , 2010 . 43 603 - 610 . DOI: 10.1107/S0021889810006163 http://doi.org/10.1107/S0021889810006163 .
Thomas, C.; Ferreiro, V.; Coulon, G.; Seguela, R. . In situ AFM investigation of crazing in polybutene spherulites under tensile drawing . Polymer , 2007 . 48 6041 - 6048 . DOI: 10.1016/j.polymer.2007.07.062 http://doi.org/10.1016/j.polymer.2007.07.062 .
Sun, W.; Chen, T.; Chen, C.; Li, J. . A study on membrane morphology by digital image processing . J. Membr. Sci. , 2007 . 305 93 - 102 . DOI: 10.1016/j.memsci.2007.07.040 http://doi.org/10.1016/j.memsci.2007.07.040 .
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