A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly

Wen-Zhang Fang; Li Peng; Ying-Jun Liu; Fang Wang; Zhen Xu; Chao Gao

doi:10.1007/s10118-021-2515-1

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A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly

REVIEW | Updated：2020-11-26

- A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly
- Chinese Journal of Polymer Science Vol. 39, Issue 3, Pages: 267-308(2021)
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Chao Gao received his Ph.D. degree from Shanghai Jiao Tong University (SJTU) in 2001. He was appointed as an Associate Professor at SJTU in 2002. He did postdoctoral research at the University of Sussex with Prof. Sir Harry Kroto and AvH research at the Bayreuth University with Prof. Axel H. E. Müller. He joined the Department of Polymer Science and Engineering, Zhejiang University, in 2008 and was promoted as a Qiushi Distinguished Professor in 2014. He leads a Nanopolymer group working on graphene chemistry, macroscopic assembly, and energy storage
- Funds：
- DOI：10.1007/s10118-021-2515-1
  CLC：
- Received：28 August 2020，
  
  Revised：2020-9-29，
  
  Accepted：05 October 2020，
  
  Online First：26 November 2020，
  
  Published：02 January 2021
- Accepted：
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Fang, W. Z.; Peng, L.; Liu, Y. J.; Wang, F.; Xu, Z.; Gao, C. A review on graphene oxide two-dimensional macromolecules: from single molecules to macro-assembly. Chinese J. Polym. Sci. 2021, 39, 267–308

Wen-Zhang Fang, Li Peng, Ying-Jun Liu, et al. A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly[J]. Chinese Journal of Polymer Science, 2021, 39(3): 267-308.
Fang, W. Z.; Peng, L.; Liu, Y. J.; Wang, F.; Xu, Z.; Gao, C. A review on graphene oxide two-dimensional macromolecules: from single molecules to macro-assembly. Chinese J. Polym. Sci. 2021, 39, 267–308 DOI： 10.1007/s10118-021-2515-1.

Wen-Zhang Fang, Li Peng, Ying-Jun Liu, et al. A Review on Graphene Oxide Two-dimensional Macromolecules: from Single Molecules to Macro-assembly[J]. Chinese Journal of Polymer Science, 2021, 39(3): 267-308. DOI： 10.1007/s10118-021-2515-1.

摘要

Abstract

Graphene oxide (GO)

which consists of two-dimensional (2D) sp

carbon hexagonal networks and oxygen-contained functional groups

has laid the foundation of mass production and applications of graphene materials. Made by chemical oxidation of graphite

GO is highly dispersible or even solubilized in water and polar organic solvents

which resolves the hard problem of graphene processing and opens a door to wet-processing of graphene. Despite its defects

GO is easy to functionalize

dope

punch holes

cut into pieces

conduct chemical reduction

form lyotropic liquid crystal

and assemble into macroscopic materials with tunable structures and properties as a living building block. GO sheet has been viewed as a single molecule

a particle

as well as a soft polymer material. An overview on GO as a 2D macromolecule is essential for studying its intrinsic properties and guiding the development of relevant subjects. This review mainly focuses on recent advances of GO sheets

from single macromolecular behavior to macro-assembled graphene material properties. The first part of this review offers a brief introduction to the synthesis of GO molecules. Then the chemical structure and physical properties of GO are presented

as well as its polarity in solvent and rheology behavior. Several key parameters governing the ultimate stability of GO colloidal behavior

including size

pH and the presence of cation in aqueous dispersions

are highlighted. Furthermore

the discovery of GO liquid crystal and functionalization of GO molecules have built solid new foundations of preparing highly ordered

architecture-tunable

macro-assembled graphene materials

including 1D graphene fibers

2D graphene films

and 3D graphene architectures. The GO-based composites are also viewed and the interactions between these target materials and GO are carefully discussed. Finally

an outlook is provided in this field

where GO is regarded as macromolecules

pointing out the challenges and opportunities that exist in the field. We hope that this review will be beneficial to the understanding of GO in terms of chemical structure

molecular properties

macro-assembly and potential applications

and encourage further development to extend its investigations from basic research to practical applications.

关键词

Keywords

references

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