Structural Changes and Electrodynamic Effects in Polymers under Fast Uniaxial Compression

Aleksey. I. Aleksandrov; Ivan A. Aleksandrov; Vitaliy G. Shevchenko; Aleksandr N. Ozerin

doi:10.1007/s10118-021-2511-5

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Structural Changes and Electrodynamic Effects in Polymers under Fast Uniaxial Compression

ARTICLE | Updated：2020-10-13

- Structural Changes and Electrodynamic Effects in Polymers under Fast Uniaxial Compression
- Chinese Journal of Polymer Science Vol. 39, Issue 5, Pages: 601-609(2021)
- Affiliations：
  
  N.S.Enikolopov Institute of Synthetic Polymeric Materials RAS 117393 Moscow, Profsoyuznaya, 70 Russian Federation
- Author bio：
  
  shev@ispm.ru
- Funds：
- DOI：10.1007/s10118-021-2511-5
  CLC：
- Received：01 August 2020，
  
  Revised：2020-9-1，
  
  Accepted：21 September 2020，
  
  Online First：13 October 2020，
  
  Published：01 January 2021
- Accepted：
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Aleksandrov, A. I.; Aleksandrov, I. A.; Shevchenko, V. G.; Ozerin, A. N. Structural changes and electrodynamic effects in polymers under fast uniaxial compression. Chinese J. Polym. Sci. 2021, 39, 601–609

Aleksey. I. Aleksandrov, Ivan A. Aleksandrov, Vitaliy G. Shevchenko, et al. Structural Changes and Electrodynamic Effects in Polymers under Fast Uniaxial Compression[J]. Chinese Journal of Polymer Science, 2021, 39(5): 601-609.
Aleksandrov, A. I.; Aleksandrov, I. A.; Shevchenko, V. G.; Ozerin, A. N. Structural changes and electrodynamic effects in polymers under fast uniaxial compression. Chinese J. Polym. Sci. 2021, 39, 601–609 DOI： 10.1007/s10118-021-2511-5.

Aleksey. I. Aleksandrov, Ivan A. Aleksandrov, Vitaliy G. Shevchenko, et al. Structural Changes and Electrodynamic Effects in Polymers under Fast Uniaxial Compression[J]. Chinese Journal of Polymer Science, 2021, 39(5): 601-609. DOI： 10.1007/s10118-021-2511-5.

摘要

Abstract

Rheological explosion in polymers under uniaxial compression in an open volume occurs at the end of continuous rapid plastic deformation after several stages of creep. Two types of polymers were chosen for this study: brittle glassy amorphous polystyrene and thermoplastic semi-crystalline polypropylene. Electric pulses were detected during explosion

and their spectra were analyzed with two models. X-ray diffraction methods were used to investigate changes in the structure and morphology of polymers during deformation and rheological explosion. The pores appear in polymer in this process

and their shape and size distribution were derived from X-ray experiments. The main reason for the formation of pores in polymer samples in rheological explosion experiments is the intense microshifts in the polymer volume under the action of high applied pressure.

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references

Bridgman, P. W. . Effects of high shearing stress combined with high hydrostatic pressure . Phys. Rev. , 1935 . 48 825 - 847 . DOI: 10.1103/PhysRev.48.825 http://doi.org/10.1103/PhysRev.48.825 .

Bridgman, P. W. . Flow in heavily stressed metals . J. Appl. Phys. , 1937 . 8 328 - 336 . DOI: 10.1063/1.1710301 http://doi.org/10.1063/1.1710301 .

Meade, C.; Jeanloz, R. . Acoustic emissions and shear instabilities during phase transformations in Si and Ge at ultrahigh pressures . Nature , 1989 . 339 616 - 618 . DOI: 10.1038/339616a0 http://doi.org/10.1038/339616a0 .

Holzhausen, G. R.; Johnson, A. M. . The concept of residual stress in rock . Tectonophysics , 1979 . 58 237 - 267 . DOI: 10.1016/0040-1951(79)90311-1 http://doi.org/10.1016/0040-1951(79)90311-1 .

Sleep, N. H.; Blanpied, M. L. . Creep, compaction and the weak rheology of major faults . Nature , 1992 . 359 687 - 692 . DOI: 10.1038/359687a0 http://doi.org/10.1038/359687a0 .

Kanel, G. I.; Fortov, V. E.; Razorenov, S. V. . Shock waves in condensed-state physics . Phys.-Usp. , 2007 . 50 771 - 792 . DOI: 10.1070/PU2007v050n08ABEH006327 http://doi.org/10.1070/PU2007v050n08ABEH006327 .

Aleksandrov, A. I.; Alexandrov, I. A.; Prokof’ev, A. I.; Bubnov, N. N. . Pulse mechanochemistry of organoelement compounds . Russ. Chem. Bull. , 1999 . 48 1599 - 1614 . DOI: 10.1007/BF02494801 http://doi.org/10.1007/BF02494801 .

Aleksandrov, I. A.; Gritsenko, O. T.; Getmanova, E. V.; Obolonkova, E. S.; Serenko, O. A.; Shevchenko, V. G.; Aleksandrov, A. I. Muzafarov, A. M. . Behavior of polystyrene-based nano- and microcomposites under fast compression . Tech. Phys. , 2011 . 56 491 - 495 . DOI: 10.1134/S1063784211040025 http://doi.org/10.1134/S1063784211040025 .

Aleksandrov, I. A.; Gritsenko, O. T.; Perov, N. S.; Getmanova, E. V.; Obolonkova, E. S.; Serenko, O. A.; Shevchenko, V. G.; Aleksandrov, A. I.; Muzafarov, A. M. . Fracture of polystyrene- and molecular silica sol-based nanocomposites during fast compression . Tech. Phys. , 2013 . 58 88 - 93 . DOI: 10.1134/S1063784213010027 http://doi.org/10.1134/S1063784213010027 .

Aleksandrov, A. I.; Alexandrov, I. A.; Prokof’ev, A. I. . Radio-frequency superradiance at the rheological explosion of a paramagnetic polymer composite containing manganese complexes . JETP Lett. , 2013 . 97 546 - 548 . DOI: 10.1134/S0021364013090038 http://doi.org/10.1134/S0021364013090038 .

Aleksandrov, A. I.; Aleksandrov, I. A.; Zezin, S. B.; Degtyarev, E. N.; Dubinskiy, A. A.; Abramchuk, S. S.; Prokof’ev, A. I. . Radio-frequency superradiance induced by the rheological explosion of polymer composites containing paramagnetic cobalt complexes . Russ. J. Phys. Chem. B , 2016 . 10 69 - 76 . DOI: 10.1134/S1990793116010139 http://doi.org/10.1134/S1990793116010139 .

Aleksandrov, A. I.; Shevchenko, V. G.; Aleksandrov, I. A. . Generation of superradiance by pulsed mechanical action . Tech. Phys. Lett. , 2020 . 46 346 - 349 . DOI: 10.1134/S1063785020040021 http://doi.org/10.1134/S1063785020040021 .

Aleksandrov, A. I.; Aleksandrov, I. A.; Shevchenko, V. G. . Multiferroic based on metal-organic dimers with the Dzyaloshinskii-Moriya effect . JETP Lett. , 2016 . 104 568 - 572 . DOI: 10.1134/S0021364016200066 http://doi.org/10.1134/S0021364016200066 .

Aleksandrov, A. I.; Shevchenko, V. G.; Aleksandrov, I. A. . A polymer composite based on organometallic cobalt dimers with Dzyaloshinskii-Moriya effect . Polym. Sci. Ser. A , 2018 . 60 74 - 80 . DOI: 10.1134/S0965545X18010017 http://doi.org/10.1134/S0965545X18010017 .

Nielsen, L. E.; Landel, R. F. Mechanical properties of polymers and composites, 2 nd ed. Marcel Dekker, Inc., NY, 1994 , p. 112.

Petoukhov, M. V.; Franke, D.; Shkumatov, A. V.; Tria, G.; Kikhney, A. G.; Gajda, M.; Gorba, C.; Mertens, H. D. T., Konarev, P. V.; Svergun, D. I. . New developments in the ATSAS program package for small-angle scattering data analysis . J. Appl. Cryst. , 2012 . 45 342 - 350 . DOI: 10.1107/S0021889812007662 http://doi.org/10.1107/S0021889812007662 .

Tikhonov, A. E.; Arsenin, V. Y. Solutions of ill-posed problems. John Wiley & amp; Sons, New York, 1977 , pp. 258.

Wertz, J. E. Bolton, J. R. Electron spin resonance. Chapman and Hall, New York, 1986 , pp. 500.

Lorentz, H. A. . Theorien physikalischer Erscheinungen . Physikalische Zeitschrift. , 1899 . 498 514 - 591 . .

Kremer F. Broadband dielectric spectroscopy, Springer-Verlag, Berlin Heidelberg. 2003 , pp. 60−98.

Volynskii, A. L.; Bakeev, N. F. Structural self-organization of amorphous polymers (in Russian). Fizmatlit, Moscow, 2005 .

Bendler, J. T. . Conformational origin of glassy-state relaxation and ductility in aromatic polycarbonates . Comput. Theor. Polym. Sci. , 1998 . 8 83 - 92 . DOI: 10.1016/S1089-3156(98)00019-1 http://doi.org/10.1016/S1089-3156(98)00019-1 .

Othmezouri-Decerf J. . Investigation of the low temperature ageing kinetics of glassy polycarbonate by mechanical damping spectroscopy . J. Mater. Sci. , 1999 . 34 2351 - 2359 . DOI: 10.1023/A:1004594111987 http://doi.org/10.1023/A:1004594111987 .

Feigin, L. A.; Svergun, D. I. Structure analysis by small-angle X-ray and neutron scattering. New York: Plenum Press, 1987 , pp. 335.

Ozerin, A. N.; Kurkin, T. S.; Ozerina, L. A.; Dolmatov, V. Y. . X-ray diffraction study of the structure of detonation nanodiamonds . Crystallogr. Rep. , 2008 . 53 60 - 67 . DOI: 10.1134/S1063774508010070 http://doi.org/10.1134/S1063774508010070 .

Shtykova, E. V. . Shape determination of polydisperse and polymorphic nanoobjects from small-angle X-ray scattering data (computer simulation) . Nanotechnologies in Russia, , 2015 . 10 408 - 419 . DOI: 10.1134/S1995078015030155 http://doi.org/10.1134/S1995078015030155 .

De Rosa, C.; Auriemma, F. Diffraction analysis of ordered and disordered crystals. New Jersey: John Wiley & amp; Sons, Inc., 2014 , pp. 480.

Buchachenko, A. L. . Microwave stimulation of dislocations and the magnetic control of the earthquake core . Phys.-Usp. , 2019 . 62 46 - 53 . DOI: 10.3367/UFNe.2018.03.038301 http://doi.org/10.3367/UFNe.2018.03.038301 .

Morgunov, R. B. . Spin micromechanics in the physics of plasticity . Phys.-Usp. , 2004 . 47 125 - 148 . DOI: 10.1070/PU2004v047n02ABEH001683 http://doi.org/10.1070/PU2004v047n02ABEH001683 .

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