Facile Mechanochemical Preparation of Polyamide-derivatives <italic style="font-style: italic">via</italic> Solid-state Benzoxazine-isocyanide Chemistry

Xu Sun; Wei Shi; Xin-Yu Zhou; Sheng Ding

doi:10.1007/s10118-021-2510-6

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Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry

ARTICLE | Updated：2020-10-14

- Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry
- Chinese Journal of Polymer Science Vol. 39, Issue 5, Pages: 573-584(2021)
- Affiliations：
  
  Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
- Author bio：
  
  shiwei80@swpu.edu.cn
- Funds：
- DOI：10.1007/s10118-021-2510-6
  CLC：
- Received：21 August 2020，
  
  Revised：2020-9-15，
  
  Accepted：17 September 2020，
  
  Online First：14 October 2020，
  
  Published：01 January 2021
- Accepted：
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Sun, X.; Shi, W.; Zhou, X. Y.; Ding, S. Facile mechanochemical preparation of polyamide-derivatives , via, solid-state benzoxazine-isocyanide chemistry. Chinese J. Polym. Sci. 2021, 39, 573–584

Xu Sun, Wei Shi, Xin-Yu Zhou, et al. Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry[J]. Chinese Journal of Polymer Science, 2021, 39(5): 573-584. DOI: 10.1007/s10118-021-2510-6.
Sun, X.; Shi, W.; Zhou, X. Y.; Ding, S. Facile mechanochemical preparation of polyamide-derivatives , via, solid-state benzoxazine-isocyanide chemistry. Chinese J. Polym. Sci. 2021, 39, 573–584 DOI： 10.1007/s10118-021-2510-6.

Xu Sun, Wei Shi, Xin-Yu Zhou, et al. Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry[J]. Chinese Journal of Polymer Science, 2021, 39(5): 573-584. DOI: 10.1007/s10118-021-2510-6. DOI：

摘要

Abstract

With the exploration of novel sustainable protocol for functional polyamides’ (PAs) construction as the starting point

herein

the small molecular model compound (M1-ssBIC) was prepared firstly by manual grinding of monofunctional benzoxazine (1a) and isocyanide (1b)

via

solid-state benzoxazine-isocyanide chemistry (ssBIC) to evaluate the feasibility of ssBIC. Linear PAs (P1-series polymers) were subsequently synthesized from biunctional benzoxazine (2a) and isocyanide (2b)

and the influence of the loading of catalyst (octylphosphonic acid) (OPA) on the polymerization was investigated. Afterwards

two kinds of cross-linked PAs were successfully constructed

via

ssBIC by using trifunctional benzoxazine (3a) and cross-linked polybenzoxazine (4a) as reaction substrates

respectively

thus verifying the adaptability of ssBIC. Structural characterization indicates that amide

phenolic hydroxyl and tertiary amine substructures

with metal-complexing capability

have been successfully integrated into the obtained PAs. A type of representative PA/silver composite (P3-AgNPs) was prepared subsequently

via

in situ

reduction treatment

and its application as recyclable reduction catalyst for organic pollutant

-nitrophenol (4-NP) was preliminarily investigated here to provide the example for possible downstream application of ssBIC. We think that this current work could provide a new pathway for the construction of functional PAs through facile and sustainable ssBIC protocol.

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references

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Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry

DOI：10.1007/s10118-021-2510-6

摘要

Abstract

关键词

Keywords

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