Scalable Reaction-spinning of Rigid-rod Upilex-S<sup>®</sup> Type Polyimide Fiber with an Ultrahigh <italic style="font-style: italic">T</italic><sub>g</sub>

Sen-Sen Zheng; Han Dong; Shi-Hua Wang; Jie Dong; Tao Guo; Xin Zhao; Qing-Hua Zhang

doi:10.1007/s10118-021-2508-0

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Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g

ARTICLE | Updated：2020-10-13

- Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g
- Chinese Journal of Polymer Science Vol. 39, Issue 5, Pages: 592-600(2021)
- Affiliations：
  
  a.Shanghai Collaborative Innovation Center for High Performance Fiber Composites, Engineering Research Center of Technical Textiles, Ministry of Education, Donghua University, Shanghai 201620, China
  b.Jiangsu Aoshen Hi-Tech Materials Co., Ltd., Lianyungang 222000, China
- Author bio：
  
  dj01@dhu.edu.cn (J.D.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
- DOI：10.1007/s10118-021-2508-0
  CLC：
- Received：26 August 2020，
  
  Revised：2020-9-8，
  
  Accepted：14 September 2020，
  
  Online First：13 October 2020，
  
  Published：01 January 2021
- Accepted：
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Zheng, S. S.; Dong, H.; Wang, S. H.; Dong, J.; Guo, T.; Zhao, X.; Zhang, Q. H. Scalable reaction-spinning of rigid-rod Upilex-S^® type polyimide fiber with an ultrahigh , T,_g. Chinese J. Polym. Sci. 2021, 39, 592–600 DOI: 10.1007/s10118-021-2508-0.

Sen-Sen Zheng, Han Dong, Shi-Hua Wang, et al. Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g[J]. Chinese Journal of Polymer Science, 2021, 39(5): 592-600. DOI: 10.1007/s10118-021-2508-0.
Zheng, S. S.; Dong, H.; Wang, S. H.; Dong, J.; Guo, T.; Zhao, X.; Zhang, Q. H. Scalable reaction-spinning of rigid-rod Upilex-S^® type polyimide fiber with an ultrahigh , T,_g. Chinese J. Polym. Sci. 2021, 39, 592–600 DOI: 10.1007/s10118-021-2508-0. DOI：

Sen-Sen Zheng, Han Dong, Shi-Hua Wang, et al. Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g[J]. Chinese Journal of Polymer Science, 2021, 39(5): 592-600. DOI: 10.1007/s10118-021-2508-0. DOI：

摘要

Abstract

In the family of polyimide (PI) materials

Upilex-S

film has been a shining star through the research PI materials due to its appealing merits. Unfortunately

the wholly rigid-rod backbone and easily formed skin-core micromorphology and microvoids of Upilex-S

type PI lead to the high difficulty in melt- and wet-spinning fabrication. Herein

we propose a facile and scalable method

reaction-spinning

to fabricate the Upilex-S

type PI fiber

in which the rapid solidification of spinning dope and partial imidization take place simultaneously. Thus

the stability and mechanical strength of as-spun fibers can be improved

and the microvoids in fibers can be greatly reduced in relative to the wet-spun fibers. The resultant Upilex-S

type PI fiber shows higher tensile strength and modulus than most commercial thermal-oxidative polymeric fibers with an ultrahigh glass transition temperature

of 478 °C. Moreover

the WAXS and SAXS results indicate that orthorhombic crystals are formed for Upilex-S

type PI fiber in the post hot-drawing process. Increasing the hot-drawing temperature results in a continuous crystallization and high orientation of PI chains in amorphous phase and perfects the existing lamellar structure

which make a great contribution to the improved mechanical property.

关键词

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references

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⁰

Scalable Reaction-spinning of Rigid-rod Upilex-S® Type Polyimide Fiber with an Ultrahigh Tg

DOI：10.1007/s10118-021-2508-0

摘要

Abstract

关键词

Keywords

references

Scalable Reaction-spinning of Rigid-rod Upilex-S^® Type Polyimide Fiber with an Ultrahigh T_g