Yttrium-catalyzed <italic style="font-style: italic">cis</italic>-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene

Jian-Ming Huang; Chang-Guang Yao; Shi-Hui Li; Dong-Mei Cui

doi:10.1007/s10118-021-2505-3

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Yttrium-catalyzed cis-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene

ARTICLE | Updated：2020-10-16

- Yttrium-catalyzed cis-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene
- Chinese Journal of Polymer Science Vol. 39, Issue 3, Pages: 309-315(2021)
- Affiliations：
  
  a.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  shihui-li@ciac.ac.cn (S.H.L.)
  dmcui@ciac.ac.cn (D.M.C.)
- Funds：
- DOI：10.1007/s10118-021-2505-3
  CLC：
- Received：08 July 2020，
  
  Revised：2020-8-6，
  
  Accepted：21 August 2020，
  
  Online First：16 October 2020，
  
  Published：02 January 2021
- Accepted：
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Huang, J. M.; Yao, C. G.; Li, S. H.; Cui, D. M. Yttrium-catalyzed , cis,-1,4-selective polymerization of 2-(4-halophenyl)-1,3-butadienes and their copolymerization with isoprene. Chinese J. Polym. Sci. 2021, 39, 309–315

Jian-Ming Huang, Chang-Guang Yao, Shi-Hui Li, et al. Yttrium-catalyzed cis-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene[J]. Chinese Journal of Polymer Science, 2021, 39(3): 309-315. DOI: 10.1007/s10118-021-2505-3.
Huang, J. M.; Yao, C. G.; Li, S. H.; Cui, D. M. Yttrium-catalyzed , cis,-1,4-selective polymerization of 2-(4-halophenyl)-1,3-butadienes and their copolymerization with isoprene. Chinese J. Polym. Sci. 2021, 39, 309–315 DOI： 10.1007/s10118-021-2505-3.

Jian-Ming Huang, Chang-Guang Yao, Shi-Hui Li, et al. Yttrium-catalyzed cis-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene[J]. Chinese Journal of Polymer Science, 2021, 39(3): 309-315. DOI: 10.1007/s10118-021-2505-3. DOI：

摘要

Abstract

Polymerization of 2-(4-halophenyl)-1

3-butadiene (2-XPB) and their copolymerization with isoprene using a yttrium catalyst have been examined. The

-diketiminato yttrium bis(alkyl) complex (

) activated by [Ph

C][B(C

)

] and Al

shows high

cis

-1

4-selectivity (

98%) for the polymerization of 2-XPB (2-XPB = 2-FPB

2-ClPB and 2-BrPB) to afford halogenated plastic poly(dienes) with glass transition temperatures of 30–55 °C. Moreover

the copolymerization of 2-XPB with isoprene (IP) has also been achieved by this catalyst

and the insertion ratios of 2-XPB can be facilely tuned in a full range of 0%–100% simply by changing the 2-XPB-to-IP ratio. Quantitative hydrogenation of

cis

-1

4-poly(2-XPB) results in perfect alternating ethylene-halostyrene copolymers

and an alternating copolymer of 4-vinylbenzoic acid with ethylene is obtained by a consecutive reaction of ethylene-4-bromostyrene copolymer with

BuLi

and HCl.

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references

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Yttrium-catalyzed cis-1,4-Selective Polymerization of 2-(4-Halophenyl)-1,3-butadienes and Their Copolymerization with Isoprene

DOI：10.1007/s10118-021-2505-3

摘要

Abstract

关键词

Keywords

references