Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds

An Zhao; Xuan-Yu Shi; Shi-Hao Sun; Hai-Mo Zhang; Min Zuo; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-020-2462-2

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Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds

ARTICLE | Updated：2020-07-13

- Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds
- Chinese Journal of Polymer Science Vol. 39, Issue 1, Pages: 81-90(2021)
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  kezuomin@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-020-2462-2
  CLC：
- Received：10 April 2020，
  
  Revised：2020-5-6，
  
  Accepted：25 May 2020，
  
  Online First：13 July 2020，
  
  Published：01 January 2021
- Accepted：
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Zhao, A.; Shi, X. Y.; Sun, S. H.; Zhang, H. M.; Zuo, M.; Song, Y. H.; Zheng, Q. Insights into the Payne effect of carbon black filled styrene-butadiene rubber compounds. Chinese J. Polym. Sci. 2021, 39, 81–90

An Zhao, Xuan-Yu Shi, Shi-Hao Sun, et al. Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds[J]. Chinese Journal of Polymer Science, 2021, 39(1): 81-90.
Zhao, A.; Shi, X. Y.; Sun, S. H.; Zhang, H. M.; Zuo, M.; Song, Y. H.; Zheng, Q. Insights into the Payne effect of carbon black filled styrene-butadiene rubber compounds. Chinese J. Polym. Sci. 2021, 39, 81–90 DOI： 10.1007/s10118-020-2462-2.

An Zhao, Xuan-Yu Shi, Shi-Hao Sun, et al. Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds[J]. Chinese Journal of Polymer Science, 2021, 39(1): 81-90. DOI： 10.1007/s10118-020-2462-2.

摘要

Abstract

As a widely used reinforcing filler of rubber

carbon black (CB) often enhances the nonlinear Payne effect and its mechanism still remains controversial. We adopt simultaneous measurement of rheological and electrical behaviors for styrene-butadiene rubber (SBR)/CB compounds and CB gel (CBG) during large deformation/recovery to investigate the contribution of conductive CB network evolution to the Payne effect of the compounds. In the highly filled compounds

the frequency dependence of their strain softening behavior is much more remarkable than that of their CB network breakdown during loading

while during unloading the unrecoverable filler network hardly affects the complete recovery of modulus

both revealing that their Payne effect should be dominated by the disentanglement of SBR matrix. Furthermore

the bound rubber adjacent to CB particles can accelerate the reconstruction of continuous CB network and improve the reversibility of Payne effect. This may provide new insights into the effect of filler network

bound rubber

and free rubber on the Payne effect of CB filled SBR compounds.

关键词

Keywords

references

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