Construction of Ionic Porous Organic Polymers (iPOPs) <italic style="font-style: italic">via</italic> Pyrylium Mediated Transformation

Shi-Yue Zhang; Wei-Tao Gong; Wei-Dong Qu; Xiao-Rong Deng; Kai-Xun Dong; Shu-Guang Zhang; Gui-Ling Ning

doi:10.1007/s10118-020-2436-4

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Construction of Ionic Porous Organic Polymers (iPOPs) via Pyrylium Mediated Transformation

ARTICLE | Updated：2020-06-12

- Construction of Ionic Porous Organic Polymers (iPOPs) via Pyrylium Mediated Transformation
- Chinese Journal of Polymer Science Vol. 38, Issue 9, Pages: 958-964(2020)
- Affiliations：
  
  a.State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
  b.Engineering Laboratory of Boric and Magnesic Functional Material Preparative and Applied Technology, Dalian 116024, China
- Author bio：
  
  wtgong@dlut.edu.cn (W.T.G)
  ninggl@dlut.edu.cn (G.L.N)
- Funds：
- DOI：10.1007/s10118-020-2436-4
  CLC：
- Received：02 January 2020，
  
  Revised：2020-3-21，
  
  Accepted：30 March 2020，
  
  Online First：12 June 2020，
  
  Published：2020-09
- Accepted：
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Zhang, S. Y.; Gong, W. T.; Qu, W. D.; Deng, X. R.; Dong, K. X.; Zhang, S. G.; Ning, G. L. Construction of ionic porous organic polymers (iPOPs) , via, pyrylium mediated transformation. Chinese J. Polym. Sci. 2020, 38, 958–964

Shi-Yue Zhang, Wei-Tao Gong, Wei-Dong Qu, et al. Construction of Ionic Porous Organic Polymers (iPOPs) via Pyrylium Mediated Transformation[J]. Chinese Journal of Polymer Science, 2020, 38(9): 958-964. DOI: 10.1007/s10118-020-2436-4.
Zhang, S. Y.; Gong, W. T.; Qu, W. D.; Deng, X. R.; Dong, K. X.; Zhang, S. G.; Ning, G. L. Construction of ionic porous organic polymers (iPOPs) , via, pyrylium mediated transformation. Chinese J. Polym. Sci. 2020, 38, 958–964 DOI： 10.1007/s10118-020-2436-4.

Shi-Yue Zhang, Wei-Tao Gong, Wei-Dong Qu, et al. Construction of Ionic Porous Organic Polymers (iPOPs) via Pyrylium Mediated Transformation[J]. Chinese Journal of Polymer Science, 2020, 38(9): 958-964. DOI: 10.1007/s10118-020-2436-4. DOI：

摘要

Abstract

Two new ionic porous organic polymers (iPOPs) with different counter anions were successfully fabricated

via

well-known pyrylium mediated transformation into pyridinium.

C solid-state NMR

XPS

and FTIR were analyzed and confirmed the formation of pyridinium in the network. Containing charged and aromatic networks

both iPOPs exhibit a high affinity towards toxic hexavalent chromium Cr(VI) ions. What is more

it has been demonstrated that both CO

adsorption and Cr(VI) removal properties can be tuned by simply varying counter anions.

关键词

Keywords

references

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Construction of Ionic Porous Organic Polymers (iPOPs) via Pyrylium Mediated Transformation

DOI：10.1007/s10118-020-2436-4

摘要

Abstract

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Keywords

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