Enhancement of <italic style="font-style: italic">β</italic>-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters

Lu Jin; Yan Zheng; Ze-Kun Liu; Jia-Shen Li; Yang-Pei-Qi Yi; Yang-Yang Fan; Lu-Lu Xu; Yi Li

doi:10.1007/s10118-020-2428-4

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Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters

ARTICLE | Updated：2020-06-18

- Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters
- Chinese Journal of Polymer Science Vol. 38, Issue 11, Pages: 1239-1247(2020)
- Affiliations：
  
  a.Department of Materials, School of Natural Sciences, The University of Manchester, Manchester M13 9PL, U.K.
  b.School of Fashion, Zhongyuan University of Technology, Zhengzhou 450007, China
- Author bio：
  
  henry.yili@manchester.ac.uk
- Funds：
- DOI：10.1007/s10118-020-2428-4
  CLC：
- Received：02 January 2020，
  
  Revised：2020-3-13，
  
  Accepted：17 March 2020，
  
  Online First：18 June 2020，
  
  Published：14 August 2020
- Accepted：
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Jin, L.; Zheng, Y.; Liu, Z. K.; Li, J. S.; Yi, Y. P. Q.; Fan, Y. Y.; Xu, L. L.; Li, Y. Enhancement of , β,-phase crystal content of poly(vinylidene fluoride) nanofiber web by graphene and electrospinning parameters. Chinese J. Polym. Sci. 2020, 38, 1239–1247

Lu Jin, Yan Zheng, Ze-Kun Liu, et al. Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1239-1247. DOI: 10.1007/s10118-020-2428-4.
Jin, L.; Zheng, Y.; Liu, Z. K.; Li, J. S.; Yi, Y. P. Q.; Fan, Y. Y.; Xu, L. L.; Li, Y. Enhancement of , β,-phase crystal content of poly(vinylidene fluoride) nanofiber web by graphene and electrospinning parameters. Chinese J. Polym. Sci. 2020, 38, 1239–1247 DOI： 10.1007/s10118-020-2428-4.

Lu Jin, Yan Zheng, Ze-Kun Liu, et al. Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1239-1247. DOI: 10.1007/s10118-020-2428-4. DOI：

摘要

Abstract

Electrospun poly(vinylidene fluoride) (PVDF) nanofiber web has been widely utilized as a functional material in various flexible sensors and generators due to its high piezoelectricity

ease processability

and low cost. Among all the crystalline phases of PVDF

-phase is a key property for PVDF nanofiber web

because the content of

-phase is directly proportional to piezoelectric performance of PVDF nanofiber web. Herein

the impact of graphene content (GC)

tip-to-collector distance (TCD)

and rotational speed of collector (RSC)

as well as their interactions on the

-phase formation of PVDF nanofiber web is systematically investigated

via

design of experimental method. The fraction of each crystalline phase of PVDF nanofiber web is calculated by FTIR spectra

and the crystallinity is determined by XRD patterns. The influences of GC

TCD

and RSC on both

-phase fraction and crystallinity of PVDF nanofiber are analyzed using Minitab program. The results show that GC

TCD

and RSC all have significant effect on the

-phase content of PVDF nanofiber web

and GC is the most significant one. In addition

an optimal electrospinning condition (GC = 1 wt%

TCD = 4 cm

and RSC = 2000 r·min

–1

) to fabricate high

-phase crystallinity of PVDF nanofiber web is drawn

under which the crystallinity can reach 41.7%. The contributions in this study could provide guidance for future research on fabricating high performance PVDF nanofiber web based sensors or generators.

关键词

Keywords

references

Li, Z.; Zhu, M.; Shen, J.; Qiu, Q.; Yu, J.; Ding, B. . All-fiber structured electronic skin with high elasticity and breathability . Adv. Funct. Mater. , 2020 . 30 1 - 9 . .

Li, Z.; Shen, J.; Abdalla, I.; Yu, J.; Ding, B. . Nanofibrous membrane constructed wearable triboelectric nanogenerator for high performance biomechanical energy harvesting . Nano Energy , 2017 . 36 341 - 348 . DOI: 10.1016/j.nanoen.2017.04.035 http://doi.org/10.1016/j.nanoen.2017.04.035 .

Zhu, M.; Lou, M.; Abdalla, I.; Yu, J.; Li, Z.; Ding, B. . Highly shape adaptive fiber based electronic skin for sensitive joint motion monitoring and tactile sensing . Nano Energy , 2020 . 69 104429 DOI: 10.1016/j.nanoen.2019.104429 http://doi.org/10.1016/j.nanoen.2019.104429 .

Fuh, Y. K.; Wang, B. S.; Tsai, C. Y. . Self-powered pressure sensor with fully encapsulated 3D printed wavy substrate and highly-aligned piezoelectric fibers array . Sci. Rep. , 2017 . 7 1 - 7 . DOI: 10.1038/s41598-016-0028-x http://doi.org/10.1038/s41598-016-0028-x .

Lou, M.; Abdalla, I.; Zhu, M.; Yu, J.; Li, Z.; Ding, B. . Hierarchically rough structured and self-powered pressure sensor textile for motion sensing and pulse monitoring . ACS Appl. Mater. Interfaces , 2020 . 12 1597 - 1605 . DOI: 10.1021/acsami.9b19238 http://doi.org/10.1021/acsami.9b19238 .

Maity, K.; Mandal, D. . All-organic high-performance piezoelectric nanogenerator with multilayer assembled electrospun nanofiber mats for self-powered multifunctional sensors . ACS Appl. Mater. Interfaces , 2018 . 10 18257 - 18269 . DOI: 10.1021/acsami.8b01862 http://doi.org/10.1021/acsami.8b01862 .

Huang, L.; Lu, C.; Wang, F.; Wang, L. . Preparation of PVDF/graphene ferroelectric composite films by in situ reduction with hydrobromic acids and their properties . RSC Adv. , 2014 . 4 45220 - 45229 . DOI: 10.1039/C4RA07379G http://doi.org/10.1039/C4RA07379G .

Hu, Z.; Tian, M.; Nysten, B.; Jonas, A. M. . Regular arrays of highly ordered ferroelectric polymer nanostructures for non-volatile low-voltage memories . Nat. Mater. , 2009 . 8 62 - 67 . DOI: 10.1038/nmat2339 http://doi.org/10.1038/nmat2339 .

Adhikary, P.; Biswas, A.; Mandal, D. . Improved sensitivity of wearable nanogenerators made of electrospun Eu 3+ doped P (VDF-HFP)/graphene composite nano fibers for self-powered voice recognition . Nanotechnology , 2016 . 27 495501 .

Bae, J. H.; Chang, S. H. . PVDF-based ferroelectric polymers and dielectric elastomers for sensor and actuator applications: a review . Funct. Compos. Struct. , 2019 . 1 012003 DOI: 10.1088/2631-6331/ab0f48 http://doi.org/10.1088/2631-6331/ab0f48 .

Fortunato, M.; Cavallini, D.; De Bellis, G.; Marra, F.; Tamburrano, A.; Sarto, F.; Sarto, M. S. . Phase inversion in PVDF films with enhanced piezoresponse through spin-coating and quenching . Polymers , 2019 . 11 1096 DOI: 10.3390/polym11071096 http://doi.org/10.3390/polym11071096 .

Mandal, D.; Yoon, S.; Kim, K. J. . Origin of piezoelectricity in an electrospun poly(vinylidene fluoride-trifluoroethylene) nanofiber web-based nanogenerator and nano-pressure sensor . Macromol. Rapid Commun. , 2011 . 32 831 - 837 . DOI: 10.1002/marc.201100040 http://doi.org/10.1002/marc.201100040 .

Zhu, H.; Mitsuishi, M.; Miyashita, T. . Facile preparation of highly oriented poly(vinylidene fluoride) Langmuir-Blodgett nanofilms assisted by amphiphilic polymer nanosheets . Macromolecules , 2012 . 45 9076 - 9084 . DOI: 10.1021/ma301711g http://doi.org/10.1021/ma301711g .

Mandal, D.; Henkel, K.; Schmeisser, D. . Improved performance of a polymer nanogenerator based on silver nanoparticles doped electrospun P(VDF-HFP) nanofibers . Phys. Chem. Chem. Phys. , 2014 . 16 10403 DOI: 10.1039/c3cp55238a http://doi.org/10.1039/c3cp55238a .

Garain, S.; Jana, S.; Sinha, T. K.; Mandal, D. . Design of in situ poled Ce 3+ -doped electrospun PVDF/graphene composite nanofibers for fabrication of nanopressure sensor and ultrasensitive acoustic nanogenerator . ACS Appl. Mater. Interfaces , 2016 . 8 4532 - 4540 . DOI: 10.1021/acsami.5b11356 http://doi.org/10.1021/acsami.5b11356 .

Mi, C.; Ren, Z.; Li, H.; Yan, S.; Sun, X. . Synergistic effect of hydrogen bonds and diffusion on the β -crystallization of poly(vinylidene fluoride) on poly(methyl methacrylate) interface . Ind. Eng. Chem. Res. , 2019 . 58 7389 - 7396 . DOI: 10.1021/acs.iecr.8b05545 http://doi.org/10.1021/acs.iecr.8b05545 .

Lee, S. J.; Prabu, A. A.; Jin, K. . Piezoelectric properties of electrospun poly(L-lactic acid) nanofiber web . Mater. Lett. , 2015 . 148 58 - 62 . DOI: 10.1016/j.matlet.2015.02.038 http://doi.org/10.1016/j.matlet.2015.02.038 .

Ding, B.; Wang, M.; Wang, X.; Yu, J.; Sun, G. . Electrospun nanomaterials for ultrasensitive sensors . Mater. Today , 2010 . 13 16 - 27 . .

Nasir, M.; Kotaki, M. . Fabrication of aligned piezoelectric nanofiber by electrospinning . Int. J. Nanosci. , 2009 . 08 231 - 235 . DOI: 10.1142/S0219581X09006092 http://doi.org/10.1142/S0219581X09006092 .

Jin, L.; Zheng, Y.; Liu, Z.; Li, J.; Zhai, H.; Chen, Z.; Li, Y. . Design of an ultrasensitive glexible bend sensor using a silver-doped oriented poly(vinylidene fluoride) nanofiber web for respiratory monitoring . ACS Appl. Mater. Interfaces , 2020 . 12 1359 - 1367 . DOI: 10.1021/acsami.9b18823 http://doi.org/10.1021/acsami.9b18823 .

Xin, Y.; Qi, X.; Tian, H.; Guo, C.; Li, X.; Lin, J.; Wang, C. . Full-fiber piezoelectric sensor by straight PVDF/nanoclay nanofibers . Mater. Lett. , 2016 . 164 136 - 139 . DOI: 10.1016/j.matlet.2015.09.117 http://doi.org/10.1016/j.matlet.2015.09.117 .

Abbasipour, M.; Khajavi, R.; Yousefi, A. A.; Yazdanshenas, M. E.; Razaghian, F. . The piezoelectric response of electrospun PVDF nanofibers with graphene oxide, graphene, and halloysite nanofillers: a comparative study . J. Mater. Sci. Mater. Electron. , 2017 . 28 15942 - 15952 . DOI: 10.1007/s10854-017-7491-4 http://doi.org/10.1007/s10854-017-7491-4 .

Yadav, S. K.; Cho, J. W. . Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites . Appl. Surf. Sci. , 2013 . 266 360 - 367 . DOI: 10.1016/j.apsusc.2012.12.028 http://doi.org/10.1016/j.apsusc.2012.12.028 .

Tong, W.; Zhang, Y.; Yu, L.; Luan, X.; An, Q.; Zhang, Q.; Lv, F.; Chu, P. K.; Shen, B.; Zhang, Z. . Novel method for the fabrication of flexible film with oriented arrays of graphene in poly(vinylidene fluoride- co -hexafluoropropylene) with low dielectric loss . J. Phys. Chem. C , 2014 . 118 10567 - 10573 . DOI: 10.1021/jp411828e http://doi.org/10.1021/jp411828e .

Huang, F. L.; Wei, Q. F.; Wang, J. X.; Cai, Y. B.; Huang, Y. B. . Effect of temperature on structure, morphology and crystallinity of PVDF nanofibers via electrospinning . e-Polymers , 2008 . 8 152 .

Alamusi; Xue, J.; Wu, L.; Hu, N.; Qiu, J.; Chang, C.; Atobe, S.; Fukunaga, H.; Watanabe, T.; Liu, Y.; Ning, H.; Li, J.; Zhao, Y . Evaluation of piezoelectric property of reduced graphene oxide (rGO)-poly(vinylidene fluoride) nanocomposites . Nanoscale , 2012 . 4 7250 DOI: 10.1039/c2nr32185h http://doi.org/10.1039/c2nr32185h .

Abolhasani, M. M.; Shirvanimoghaddam, K.; Naebe, M. . PVDF/graphene composite nanofibers with enhanced piezoelectric performance for development of robust nanogenerators . Compos. Sci. Technol. , 2017 . 138 49 - 56 . DOI: 10.1016/j.compscitech.2016.11.017 http://doi.org/10.1016/j.compscitech.2016.11.017 .

Martins, P.; Lopes, A. C.; Lanceros-Mendez, S. . Electroactive phases of poly(vinylidene fluoride): determination, processing and applications . Prog. Polym. Sci. , 2014 . 39 683 - 706 . DOI: 10.1016/j.progpolymsci.2013.07.006 http://doi.org/10.1016/j.progpolymsci.2013.07.006 .

Cai, X.; Lei, T.; Sun, D.; Lin, L. . A critical analysis of the α , β and γ phases in poly(vinylidene fluoride) using FTIR . RSC Adv. , 2017 . 7 15382 - 15389 . DOI: 10.1039/C7RA01267E http://doi.org/10.1039/C7RA01267E .

Hu, J.; Zhu, Y.; Zhang, H.; Gu, Y.; Yang, X. . Mixed effect of main electrospinning parameters on the β -phase crystallinity of electrospun PVDF nanofibers . Smart Mater. Struct. , 2017 . 26 085019 DOI: 10.1088/1361-665X/aa7245 http://doi.org/10.1088/1361-665X/aa7245 .

Ragab, D. M.; Elgindy, N. A. . Recent advances in nanofibers fabrication and their potential applications in wound healing and regenerative medicine . Adv. Mater. Lett. , 2018 . 9 665 - 676 . DOI: 10.5185/amlett.2018.1856 http://doi.org/10.5185/amlett.2018.1856 .

Ghosh, S. K.; Mandal, D. . Synergistically enhanced piezoelectric output in highly aligned 1D polymer nanofibers integrated all-fiber nanogenerator for wearable nano-tactile sensor . Nano Energy , 2018 . 53 245 - 257 . DOI: 10.1016/j.nanoen.2018.08.036 http://doi.org/10.1016/j.nanoen.2018.08.036 .

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Enhancement of β-Phase Crystal Content of Poly(vinylidene fluoride) Nanofiber Web by Graphene and Electrospinning Parameters

DOI：10.1007/s10118-020-2428-4

摘要

Abstract

关键词

Keywords

references