Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling

William Imamura; Érik Oda Usuda; Lucas Soares Paixão; Nicolau Molina Bom; Angelo Marcio Gomes; Alexandre Magnus Gomes Carvalho

doi:10.1007/s10118-020-2423-9

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Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling

ARTICLE | Updated：2020-05-22

- Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling
- Chinese Journal of Polymer Science Vol. 38, Issue 9, Pages: 999-1005(2020)
- Affiliations：
  
  a.Faculdade de Engenharia Mecânica, UNICAMP, CEP 13083-860, Campinas, SP, Brazil
  b.Universidade Federal de São Paulo, UNIFESP, CEP 09913-030, Diadema, SP, Brazil
  c.Instituto de Física Gleb Wataghin, UNICAMP, CEP 13083-859, Campinas, SP, Brazil
  d.Catalan Institute of Nanoscience and Nanotechnology, ICN2, 08860 Belaterra, Barcelona, Spain
  e.The Institute of Photonic Sciences, ICFO, 08193 Castelldefels, Barcelona, Spain
  f.Instituto de Física, UFRJ, CEP 21941-972, Rio de Janeiro, RJ, Brazil
  g.Departamento de Engenharia Mecânica, UEM, CEP 87020-900, Maringá, PR, Brazil
- Author bio：
  
  amgcarvalho.pem.uem@gmail.com
- Funds：
- DOI：10.1007/s10118-020-2423-9
  CLC：
- Received：07 January 2020，
  
  Revised：2020-3-7，
  
  Accepted：13 March 2020，
  
  Online First：22 May 2020，
  
  Published：2020-09
- Accepted：
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Imamura, W.; Usuda, É. O.; Paixão, L. S.; Bom, N. M.; Gomes, A. M.; Carvalho, A. M. G. Supergiant barocaloric effects in acetoxy silicone rubber over a wide temperature range: great potential for solid-state cooling. Chinese J. Polym. Sci. 2020, 38, 999–1005

William Imamura, Érik Oda Usuda, Lucas Soares Paixão, et al. Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling[J]. Chinese Journal of Polymer Science, 2020, 38(9): 999-1005.
Imamura, W.; Usuda, É. O.; Paixão, L. S.; Bom, N. M.; Gomes, A. M.; Carvalho, A. M. G. Supergiant barocaloric effects in acetoxy silicone rubber over a wide temperature range: great potential for solid-state cooling. Chinese J. Polym. Sci. 2020, 38, 999–1005 DOI： 10.1007/s10118-020-2423-9.

William Imamura, Érik Oda Usuda, Lucas Soares Paixão, et al. Supergiant Barocaloric Effects in Acetoxy Silicone Rubber over a Wide Temperature Range: Great Potential for Solid-state Cooling[J]. Chinese Journal of Polymer Science, 2020, 38(9): 999-1005. DOI： 10.1007/s10118-020-2423-9.

摘要

Abstract

Solid-state cooling based on caloric effects is considered a viable alternative to replace the conventional vapor-compression refrigeration systems. Regarding barocaloric materials

recent results show that elastomers are promising candidates for cooling applications around room-temperature. In the present paper

we report supergiant barocaloric effects observed in acetoxy silicone rubber—a very popular

low-cost and environmentally friendly elastomer. Huge values of adiabatic temperature change and reversible isothermal entropy change were obtained upon moderate applied pressures and relatively low strains. These huge barocaloric changes are associated both to the polymer chain rearrangements induced by confined compression and to the first-order structural transition. The results are comparable to the best barocaloric materials reported so far

opening encouraging prospects for the application of elastomers in near future solid-state cooling devices.

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Keywords

references

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