Increased Hydrogen-bonding of Poly(<italic style="font-style: italic">m</italic>-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber

Na Li; Xing-Ke Zhang; Jun-Rong Yu; Yan Wang; Jing Zhu; Zu-Ming Hu

doi:10.1007/s10118-020-2416-8

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Increased Hydrogen-bonding of Poly(m-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber

ARTICLE | Updated：2020-05-06

- Increased Hydrogen-bonding of Poly(m-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber
- Chinese Journal of Polymer Science Vol. 38, Issue 11, Pages: 1230-1238(2020)
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  yjr@dhu.edu.cn
- Funds：
- DOI：10.1007/s10118-020-2416-8
  CLC：
- Received：30 January 2020，
  
  Revised：2020-2-25，
  
  Accepted：02 March 2020，
  
  Online First：06 May 2020，
  
  Published：14 August 2020
- Accepted：
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Li, N.; Zhang, X. K.; Yu, J. R.; Wang, Y.; Zhu, J.; Hu, Z. M. Increased hydrogen-bonding of poly(, m,-phenylene isophthalamide) (PMIA) with sulfonate moiety for high-performance easily dyeable fiber. Chinese J. Polym. Sci. 2020, 38, 1230–1238

Na Li, Xing-Ke Zhang, Jun-Rong Yu, et al. Increased Hydrogen-bonding of Poly(m-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1230-1238. DOI: 10.1007/s10118-020-2416-8.
Li, N.; Zhang, X. K.; Yu, J. R.; Wang, Y.; Zhu, J.; Hu, Z. M. Increased hydrogen-bonding of poly(, m,-phenylene isophthalamide) (PMIA) with sulfonate moiety for high-performance easily dyeable fiber. Chinese J. Polym. Sci. 2020, 38, 1230–1238 DOI： 10.1007/s10118-020-2416-8.

Na Li, Xing-Ke Zhang, Jun-Rong Yu, et al. Increased Hydrogen-bonding of Poly(m-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber[J]. Chinese Journal of Polymer Science, 2020, 38(11): 1230-1238. DOI: 10.1007/s10118-020-2416-8. DOI：

摘要

Abstract

The demand for high thermal stability and high strength agents is growing steadily as a result of their increasing application in advanced materials. A series of sulfonated poly(

-phenyleneisophthalamide) (SPMIA) copolymers with superior thermal stability and good mechanical properties have been prepared

via

low temperature polycondensation method. Then the structures of SPMIA copolymers with different content quantities of 2

4-diaminobenzenesulfonic acid (2

4-DABSA) were confirmed by Fourier transform infrared (FTIR). Besides

their superior thermal properties were systematically investigated by differential scanning calorimetry (DSC)

thermalgravimetreic analysis (TGA)

and dynamic mechanical analysis (DMA). SPMIA fibers were obtained by wet spinning using the resultant SPMIA solutions. In addition

the obtained SPMIA fibers were proved to combine enhanced mechanical properties and unprecedented dyeability. Significantly

the SPMIA fiber with great mechanical property

thermal stability

and dyeability shows great potential in easily dyeing high-performance protective fibers.

关键词

Keywords

references

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Increased Hydrogen-bonding of Poly(m-phenylene isophthalamide) (PMIA) with Sulfonate Moiety for High-performance Easily Dyeable Fiber

DOI：10.1007/s10118-020-2416-8

摘要

Abstract

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