Soluble Polyimide-reinforced TGDDM and DGEBA Epoxy Composites

Qi Chen; Shun Wang; Feng Qin; Kuan Liu; Qian Liu; Qing Zhao; Xing-Yi Wang; Yan-Hong Hu

doi:10.1007/s10118-020-2395-9

Your Location：

Home >

Browse articles >

Soluble Polyimide-reinforced TGDDM and DGEBA Epoxy Composites

ARTICLE | Updated：2020-05-22

- Soluble Polyimide-reinforced TGDDM and DGEBA Epoxy Composites
- Chinese Journal of Polymer Science Vol. 38, Issue 8, Pages: 867-876(2020)
- Affiliations：
  
  a.Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
  b.Key Laboratory for Specially Functional Polymers and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
- Author bio：
  
  wangxy@ecust.edu.cn (X.Y.W.)
  huyhxy@ecust.edu.cn (Y.H.H.)
- Funds：
- DOI：10.1007/s10118-020-2395-9
  CLC：
- Received：19 November 2019，
  
  Revised：2020-1-6，
  
  Accepted：20 March 2020，
  
  Online First：22 May 2020，
  
  Published：2020-08
- Accepted：
Scan QR Code
Chen, Q.; Wang, S.; Qin, F.; Liu, K.; Liu, Q.; Zhao, Q.; Wang, X. Y.; Hu, Y. H. Soluble polyimide-reinforced TGDDM and DGEBA epoxy composites. Chinese J. Polym. Sci. 2020, 38, 867–876

Qi Chen, Shun Wang, Feng Qin, et al. Soluble Polyimide-reinforced TGDDM and DGEBA Epoxy Composites[J]. Chinese Journal of Polymer Science, 2020, 38(8): 867-876.
Chen, Q.; Wang, S.; Qin, F.; Liu, K.; Liu, Q.; Zhao, Q.; Wang, X. Y.; Hu, Y. H. Soluble polyimide-reinforced TGDDM and DGEBA epoxy composites. Chinese J. Polym. Sci. 2020, 38, 867–876 DOI： 10.1007/s10118-020-2395-9.

Qi Chen, Shun Wang, Feng Qin, et al. Soluble Polyimide-reinforced TGDDM and DGEBA Epoxy Composites[J]. Chinese Journal of Polymer Science, 2020, 38(8): 867-876. DOI： 10.1007/s10118-020-2395-9.

摘要

Abstract

Polyimide (PI) synthesized from aromatic diamine and dianhydrides

via

two-step poly-condensation method was highly soluble in TGDDM (MY-720) and DGEBA (E-51) at desirable temperature. TGDDM-PI (M-PI) and DGEBA-PI (E-PI) composites within 0.5%−3% PI loading could be prepared without organic solvent. On the cryogenically fractured surfaces of M-PI and E-PI composites

no obvious heterogeneous phase was observed by SEM. The mechanical properties were promoted significantly by PI

especially for impact strength. Adding 2% PI-2W into MY-720 and E-51 composites

the impact strength increased to 21 and 51 kJ/m

the tensile strength increased by 62% and 19%

and the flexural strength by 18% and 13%

respectively

with slight increases in tensile modulus. These results were related to the promotion in plasticity of composites and changes in fragile→ductile fracture mode. Moreover

and thermal stability of M-PI and E-PI were increased effectively.

关键词

Keywords

references

Yan, W.; Zhang, M. Q.; Yu, J.; Nie, S. Q.; Zhang, D. Q.; Qin, S. H. . Synergistic flame-retardant effect of epoxy resin combined with phenethyl-bridged DOPO derivative and graphene nanosheets . Chinese J. Polym. Sci. , 2019 . 37 79 - 88 . DOI: 10.1007/s10118-019-2175-6 http://doi.org/10.1007/s10118-019-2175-6 .

Hu, Z.; Zhang, D. Y.; Lu, F.; Yuan, W. H.; Xu, X. R.; Zhang, Q.; Liu, H.; Shao Q.; Guo, Z. H.; Huang, Y. D. . Multistimuli-responsive intrinsic self-healing epoxy resin constructed by host-guest interactions . Macromolecules , 2018 . 51 5294 - 5303 . DOI: 10.1021/acs.macromol.8b01124 http://doi.org/10.1021/acs.macromol.8b01124 .

Han, X.; Wang, T.; Owuor, P. S.; Hwang, S. H.; Wang, C.; Sha, J. W.; Shen, L. L.; Yoon, J. W.; Wang, W. P.; Salvatieera, R. V.; Ajayan, P. M.; Shahsavari, R.; Lou, J.; Zhao, Y.; Tour, J. M. . Ultra-stiff graphene foams as three-dimensional conductive fillers for epoxy resin . ACS Nano , 2018 . 12 11219 - 11228 . DOI: 10.1021/acsnano.8b05822 http://doi.org/10.1021/acsnano.8b05822 .

Chen, B.; Chen, J.; Li, J. Y.; Zhao, H. C.; Wang, L. P. . Oligoaniline assisted dispersion of carbon nanotubes in epoxy matrix for achieving the nanocomposites with enhanced mechanical, thermal and tribological properties . Chinese J. Polym. Sci. , 2017 . 35 446 - 454 . DOI: 10.1007/s10118-017-1911-z http://doi.org/10.1007/s10118-017-1911-z .

Sahu, M.; Raichur, A. M. . Toughening of high performance tetrafunctional epoxy with poly(allyl amine) grafted graphene oxide . Compos. Part B-Eng. , 2019 . 168 15 - 24 . DOI: 10.1016/j.compositesb.2018.12.030 http://doi.org/10.1016/j.compositesb.2018.12.030 .

Tsang, W. L.; Taylor, A. C. . Fracture and toughening mechanisms of silica- and core-shell rubber-toughened epoxy at ambient and low temperature . J. Mater. Sci. , 2019 . 54 13938 - 13958 . DOI: 10.1007/s10853-019-03893-y http://doi.org/10.1007/s10853-019-03893-y .

Eksik, O.; Gao, J.; Shojaee, S. A.; Tomas, A.; Chow, P.; Bartolucci, S. F.; Lucca, D. A.; Koratkar, N. . Epoxy nanocomposites with two-dimensional transition metal dichalcogenide additives . ACS Nano , 2014 . 8 5282 - 5289 . DOI: 10.1021/nn5014098 http://doi.org/10.1021/nn5014098 .

Chen, J.; Nie, X. A.; Liu, Z. S.; Mi, Z.; Zhou, Y. H. . Synthesis and application of polyepoxide cardanol glycidyl ether as biobased polyepoxide reactive diluent for epoxy resin . ACS Sustain. Chem. Eng. , 2015 . 3 1164 - 1171 . DOI: 10.1021/acssuschemeng.5b00095 http://doi.org/10.1021/acssuschemeng.5b00095 .

Lakshmi, M. S.; Narmadha, B.; Reddy, B. S. R. . Enhanced thermal stability and structural characteristics of different MMT-clay/epoxy-nanocomposite materials . Polym. Degrad. Stab. , 2008 . 93 201 - 213 . DOI: 10.1016/j.polymdegradstab.2007.10.005 http://doi.org/10.1016/j.polymdegradstab.2007.10.005 .

Zhang, Y.; Shang, C. Y.; Yang, X.; Zhao, X. J.; Huang, W. . Morphology and properties of TGDDM/DDS epoxy systems toughened by amino-bearing phenyl silicone resins . J. Mater. Sci. , 2012 . 47 4415 - 4427 . DOI: 10.1007/s10853-012-6298-1 http://doi.org/10.1007/s10853-012-6298-1 .

Cheng, X. L.; Wu, Q.; Morgan, S. E.; Wiggins, J. S. . Morphologies and mechanical properties of polyethersulfone modified epoxy blends through multifunctional epoxy composition . J. Appl. Polym. Sci. , 2017 . 134 44775 .

Tian, H. Y.; Liu, Z. G.; Zhang, M.; Guo, Y. L.; Zheng, L.; Li, Y. C. . Biobased polyurethane, epoxy resin, and polyolefin wax composite coating for controlled-release fertilizer . ACS Appl. Mater. Interfaces , 2019 . 11 5380 - 5392 . DOI: 10.1021/acsami.8b16030 http://doi.org/10.1021/acsami.8b16030 .

Lee, C. H.; Chen, S. H.; Wang, Y. Z.; Lin, C. C.; Huang, C. K.; Chuang, C. N.; Wang, C. K.; Hsieh, K. H. . Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks . Energy , 2013 . 55 905 - 915 . DOI: 10.1016/j.energy.2013.03.062 http://doi.org/10.1016/j.energy.2013.03.062 .

He, X.; Liu, Y.; Zhang, R. C.; Wu, Q.; Chen, T. H.; Sun, P. C.; Wang, X. L.; Xue, G. . Unique interphase and cross-linked network controlled by different miscible blocks in nanostructured epoxy/block copolymer blends characterized by solid-state NMR . J. Phys. Chem. C , 2014 . 118 13285 - 13299 . DOI: 10.1021/jp5036772 http://doi.org/10.1021/jp5036772 .

Lin, L.; Deng, C.; Lin, G. P.; Wang, Y. Z. . Super toughened and high heat-resistant poly(lactic acid) (PLA)-based blends by enhancing interfacial bonding and PLA phase crystallization . Ind. Eng. Chem. Res. , 2015 . 54 5643 - 5655 . DOI: 10.1021/acs.iecr.5b01177 http://doi.org/10.1021/acs.iecr.5b01177 .

Vu, M. C.; Bach, Q. V.; Nguyen, D. D.; Tran, T. S.; Goodarzi, M. . 3D interconnected structure of poly(methyl methacrylate) microbeads coated with copper nanoparticles for highly thermal conductive epoxy composites . Compos. Part B-Eng. , 2019 . 175 107105 DOI: 10.1016/j.compositesb.2019.107105 http://doi.org/10.1016/j.compositesb.2019.107105 .

Ma, H.; Aravand, M. A.; Falzon, B. G. . Phase morphology and mechanical properties of polyetherimide modified epoxy resins: a comparative study . Polymer , 2019 . 179 121640 DOI: 10.1016/j.polymer.2019.121640 http://doi.org/10.1016/j.polymer.2019.121640 .

Francis, B.; Thomas, S.; Jose, J.; Ramaswamy, R.; Rao, V. L. . Hydroxyl terminated poly(ether ether ketone) with pendent methyl group toughened epoxy resin: miscibility, morphology and mechanical properties . Polymer , 2005 . 46 12372 - 12385 . DOI: 10.1016/j.polymer.2005.10.103 http://doi.org/10.1016/j.polymer.2005.10.103 .

Yuan, W.; Feng, J. L.; Judeh, Z.; Dai, J.; Chan-Park, M. B. . Use of polyimide-graft-bisphenol a diglyceryl acrylate as a reactive noncovalent dispersant of single-walled carbon nanotubes for reinforcement of cyanate ester/epoxy composite . Chem. Mater. , 2010 . 22 6542 - 6554 . DOI: 10.1021/cm101785t http://doi.org/10.1021/cm101785t .

Jena, R. K.; Yue, C. Y.; Sk, M. M.; Ghosh, K. . A novel high performance bismaleimide/diallyl bisphenol A (BMI/DBA)-epoxy interpenetrating network resin for rigid riser application . RSC Adv. , 2015 . 5 79888 - 79897 . DOI: 10.1039/C5RA14474D http://doi.org/10.1039/C5RA14474D .

Liu, Y. W.; Tang, L. S.; Qu, L. J.; Liu, S. W.; Chi, Z. G.; Zhang, Y.; Xu, J. R. . Synthesis and properties of high performance functional polyimides containing rigid nonplanar conjugated fluorene moieties . Chinese J. Polym. Sci. , 2019 . 37 416 - 427 . DOI: 10.1007/s10118-019-2225-0 http://doi.org/10.1007/s10118-019-2225-0 .

Que, X. F.; Yan, Y. R.; Qiu, Z. M.; Wang, Y. . Synthesis and characterization of trifluoromethyl-containing polyimide-modified epoxy resins . J. Mater. Sci. , 2016 . 51 10833 - 10848 . DOI: 10.1007/s10853-016-0294-9 http://doi.org/10.1007/s10853-016-0294-9 .

Zhao, Q.; Wang, X. Y.; Hu, Y. H. . The application of highly soluble amine-terminated aromatic polyimides with pendent tert -butyl groups as a tougher for epoxy resin . Chinese J. Polym. Sci. , 2015 . 33 1359 - 1372 . DOI: 10.1007/s10118-015-1685-0 http://doi.org/10.1007/s10118-015-1685-0 .

Guan, Y.; Wang, D. M.; Song, G. L.; Dang, G. D.; Chen, C. H.; Zhou, H. W.; Zhao, X. G. . Novel soluble polyimides derived from 2,2′-bis[4-(5-amino-2-pyridinoxy) phenyl] hexafluoropropane: preparation, characterization, and optical, dielectric properties . Polymer , 2014 . 55 3634 - 3641 . DOI: 10.1016/j.polymer.2014.06.078 http://doi.org/10.1016/j.polymer.2014.06.078 .

Tang, X. L.; Li, L.; Zhao, L.; Zhang, H. D.; Wu, P. Y. . Using two-dimensional time resolved light scattering to study the cure reaction induced phase separation process of epoxy-amine-polyethersulfone blend with secondary phase separation . Chinese J. Polym. Sci. , 2010 . 28 63 - 68 . DOI: 10.1007/s10118-010-8201-3 http://doi.org/10.1007/s10118-010-8201-3 .

Builes, D. H.; Tercjak, A.; Mondragon, I. . Nanostructured unsaturated polyester modified with poly[(ethylene oxide)- b -(propylene oxide)- b -(ethylene oxide)] triblock copolymer . Polymer , 2012 . 53 3669 - 3676 . DOI: 10.1016/j.polymer.2012.06.018 http://doi.org/10.1016/j.polymer.2012.06.018 .

Wang, C. Y.; Chen, W. T.; Xu, C.; Zhao, X. Y.; Li, J. . Fluorinated polyimide/POSS hybrid polymers with high solubility and low dielectric constant . Chinese J. Polym. Sci. , 2016 . 34 1363 - 1372 . DOI: 10.1007/s10118-016-1845-x http://doi.org/10.1007/s10118-016-1845-x .

Liu, W. S.; Kong, J. H.; Eric, Toh W. L.; Zhou, R.; Ding, G. Q.; Huang, S.; Dong, Y. L.; Lu, X. H. . Toughening of epoxies by covalently anchoring triazole-functionalized stacked-cup carbon nanofibers . Compos. Sci. Technol. , 2013 . 85 1 - 9 . DOI: 10.1016/j.compscitech.2013.05.009 http://doi.org/10.1016/j.compscitech.2013.05.009 .

Lei, L. Q.; Shan, J. Y.; Hu, J. H.; Liu, X. X.; Zhao, J. Q.; Tong, Z. . Co-curing effect of imidazole grafting graphene oxide synthesized by one-pot method to reinforce epoxy nanocomposites . Compos. Sci. Technol. , 2016 . 128 161 - 168 . DOI: 10.1016/j.compscitech.2016.03.029 http://doi.org/10.1016/j.compscitech.2016.03.029 .

Gantayat, S.; Rout, D.; Swain, S. K. . Mechanical properties of functionalized multiwalled carbon nanotube/epoxy nanocomposites . Mater. Today-Proc. , 2017 . 4 4061 - 4064 . DOI: 10.1016/j.matpr.2017.02.308 http://doi.org/10.1016/j.matpr.2017.02.308 .

Saleh, A. B. B.; Ishak, Z. A. M.; Hashim, A. S.; Kamil, W. A.; Ishiaku, U. S. . Synthesis and characterization of liquid natural rubber as impact modifier for epoxy resin . Physcs. Proc. , 2014 . 55 129 - 137 . DOI: 10.1016/j.phpro.2014.07.019 http://doi.org/10.1016/j.phpro.2014.07.019 .

Wu, F.; Song, B.; Hah, J.; Tuan, C. C.; Moon, K. S.; Wong, C. P. . Polyimide incorporated cyanate ester/epoxy copolymers for high-temperature molding compounds . J. Polym. Sci., Part A: Polym. Chem. , 2018 . 56 2412 - 2421 . DOI: 10.1002/pola.29214 http://doi.org/10.1002/pola.29214 .

Deepak, P.; Kumar, R. V.; Badrinarayanan, S.; Sivaraman, H.; Vimal, R. . Effects of polyamide and/or phenalkamine curing agents on the jute fibre reinforcement with epoxy resin matrix . Mater. Today-Proc. , 2017 . 4 2841 - 2850 . DOI: 10.1016/j.matpr.2017.02.164 http://doi.org/10.1016/j.matpr.2017.02.164 .

Palmeri, M. J.; Putz, K. W.; Brinson, L. C. . Sacrificial bonds in stacked-cup carbon nanofibers: biomimetic toughening mechanisms for composite systems . ACS Nano , 2010 . 4 4256 - 4264 . DOI: 10.1021/nn100661a http://doi.org/10.1021/nn100661a .

Tang, L. C.; Zhang, H.; Sprenger, S.; Ye, L.; Zhang, Z. . Fracture mechanisms of epoxy-based ternary composites filled with rigid-soft particles . Compos. Sci. Technol. , 2012 . 72 558 - 565 . DOI: 10.1016/j.compscitech.2011.12.015 http://doi.org/10.1016/j.compscitech.2011.12.015 .

Kang, W. S.; Rhee, K. Y.; Park, S. J. . Thermal, impact and toughness behaviors of expanded graphite/graphite oxide-filled epoxy composites . Compos. Part B-Eng. , 2016 . 94 238 - 244 . DOI: 10.1016/j.compositesb.2016.03.052 http://doi.org/10.1016/j.compositesb.2016.03.052 .

Huang, W.; Yan, D. Y.; Lu, Q. H.; Tao, B. . Preparation of aromatic polyimides highly soluble in conventional solvents . J. Polym. Sci., Part A: Polym. Chem. , 2002 . 40 229 - 234 . DOI: 10.1002/pola.10105 http://doi.org/10.1002/pola.10105 .

Sun, G. H.; Liu, L. H.; Wang, J.; Wang, H. L.; Wang, W. P.; Han, S. H. . Effects of hydrotalcites and tris(1-chloro-2-propyl) phosphate on thermal stability, cellular structure and fire resistance of isocyanate-based polyimide foams . Polym. Degrad. Stab. , 2015 . 115 1 - 15 . DOI: 10.1016/j.polymdegradstab.2015.01.021 http://doi.org/10.1016/j.polymdegradstab.2015.01.021 .

Xiang, A. M.; Li, Y.; Fu, L.; Chen, Y. J.; Tian, H. F.; Rajulu, A. V. . Thermal degradation and flame retardant properties of isocyanate-based flexible polyimide foams with different isocyanate indices . Thermochim. Acta , 2017 . 652 160 - 165 . DOI: 10.1016/j.tca.2017.03.019 http://doi.org/10.1016/j.tca.2017.03.019 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

The Application of Highly Soluble Amine-terminated Aromatic Polyimides with Pendent Tert-butyl Groups as a Tougher for Epoxy Resin

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

Phase Structure Formed by Rubber and Rigid Particles in a Polymer and Its Effect on the Composite Rigidity and Toughness

High-performance Polyimide Cuff Tube with Tunable Mechanics and Long-term Biocompatibility for Microvascular Anastomosis

Related Author

Qing Zhao

Xing-yi Wang

Qiao-Ran Zhang

Xin-Fei Wang

Ya-Nan Chen

Bo-Yuan Zhou

Hong-Liang Wei

Xiao-Yu Cao

Related Institution

Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology

School of Chemistry and Chemical Engineering, Henan University of Technology

Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences

Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Chemistry, Southwest Jiaotong University

College of Materials Science and Engineering, State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Key Laboratory of Textile Fiber and Products of Ministry of Education, Wuhan Textile University

⁰