Preparation and Characterization of Poly(vinyl alcohol)/ZIF-8 Porous Composites by Ice-templating Method with High ZIF-8 Loading Amount

Xuan-He Yang; Yan-Qing Yao; Mu-Hua Huang; Chun-Peng Chai

doi:10.1007/s10118-020-2368-z

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Preparation and Characterization of Poly(vinyl alcohol)/ZIF-8 Porous Composites by Ice-templating Method with High ZIF-8 Loading Amount

ARTICLE | Updated：2019-12-13

- Preparation and Characterization of Poly(vinyl alcohol)/ZIF-8 Porous Composites by Ice-templating Method with High ZIF-8 Loading Amount
- Chinese Journal of Polymer Science Vol. 38, Issue 6, Pages: 638-643(2020)
- Affiliations：
  
  School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
- Author bio：
  
  chaicp@bit.edu.cn
- Funds：
- DOI：10.1007/s10118-020-2368-z
  CLC：
- Received：28 August 2019，
  
  Revised：2019-10-8，
  
  Accepted：05 November 2019，
  
  Online First：13 December 2019，
  
  Published：2020-06
- Accepted：
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Yang, X. H.; Yao, Y. Q.; Huang, M. H.; Chai, C. P. Preparation and characterization of poly(vinyl alcohol)/ZIF-8 porous composites by ice-templating method with high ZIF-8 loading amount. Chinese J. Polym. Sci. 2020, 38, 638–643

Xuan-He Yang, Yan-Qing Yao, Mu-Hua Huang, et al. Preparation and Characterization of Poly(vinyl alcohol)/ZIF-8 Porous Composites by Ice-templating Method with High ZIF-8 Loading Amount[J]. Chinese Journal of Polymer Science, 2020, 38(6): 638-643.
Yang, X. H.; Yao, Y. Q.; Huang, M. H.; Chai, C. P. Preparation and characterization of poly(vinyl alcohol)/ZIF-8 porous composites by ice-templating method with high ZIF-8 loading amount. Chinese J. Polym. Sci. 2020, 38, 638–643 DOI： 10.1007/s10118-020-2368-z.

Xuan-He Yang, Yan-Qing Yao, Mu-Hua Huang, et al. Preparation and Characterization of Poly(vinyl alcohol)/ZIF-8 Porous Composites by Ice-templating Method with High ZIF-8 Loading Amount[J]. Chinese Journal of Polymer Science, 2020, 38(6): 638-643. DOI： 10.1007/s10118-020-2368-z.

摘要

Abstract

A bulk Poly(vinyl alcohol)/ZIF-8 (PVA/ZIF-8) porous composite with aligned porous structure was prepared by ice-templating method. The microstructure of PVA/ZIF-8 porous composites was characterized by scanning electron microscopy (SEM). The results showed that the composites had regular pore structure and ZIF-8 nanoparticles were evenly distributed on the skeleton of PVA. X-ray diffraction (XRD) test results showed that the crystalline structure of ZIF-8 was well preserved in the composites. The specific surface area of the composite was characterized by nitrogen adsorption/desorption test. The specific surface area of the composite was up to 1160 m

·g

–1

. PVA/ZIF-8 porous composites could also support a certain weight with almost no volume shrinkage. The carbon dioxide adsorption quantity of the composite was up to 11.3 cm

·g

–1

proving that PVA/ZIF-8 porous composite has a good application prospect in the field of carbon dioxide adsorption.

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references

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