Preparation of Polyaniline-coated Composite Aerogel of MnO<sub>2</sub> and Reduced Graphene Oxide for High-performance Zinc-ion Battery

Jing Mao; Fang-Fang Wu; Wen-Hui Shi; Wen-Xian Liu; Xi-Lian Xu; Gang-Feng Cai; Yi-Wen Li; Xie-Hong Cao

doi:10.1007/s10118-020-2353-6

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Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery

ARTICLE | Updated：2019-11-07

- Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery
- Chinese Journal of Polymer Science Vol. 38, Issue 5, Pages: 514-521(2020)
- Affiliations：
  
  a.College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  b.Center for Membrane Separation and Water Science & Technology, Ocean College, Zhejiang University of Technology, Hangzhou 310014, China
- Author bio：
  
  gcscaoxh@zjut.edu.cn
- Funds：
- DOI：10.1007/s10118-020-2353-6
  CLC：
- Received：14 August 2019，
  
  Revised：2019-8-30，
  
  Accepted：31 August 2019，
  
  Online First：07 November 2019，
  
  Published：2020-05
- Accepted：
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Mao, J.; Wu, F. F.; Shi, W. H.; Liu, W. X.; Xu, X. L.; Cai, G. F.; Li, Y. W.; Cao, X. H. Preparation of polyaniline-coated composite aerogel of MnO₂ and reduced graphene oxide for high-performance zinc-ion battery. Chinese J. Polym. Sci. 2020, 38, 514–521 DOI: 10.1007/s10118-020-2353-6.

Jing Mao, Fang-Fang Wu, Wen-Hui Shi, et al. Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery[J]. Chinese Journal of Polymer Science, 2020, 38(5): 514-521. DOI: 10.1007/s10118-020-2353-6.
Mao, J.; Wu, F. F.; Shi, W. H.; Liu, W. X.; Xu, X. L.; Cai, G. F.; Li, Y. W.; Cao, X. H. Preparation of polyaniline-coated composite aerogel of MnO₂ and reduced graphene oxide for high-performance zinc-ion battery. Chinese J. Polym. Sci. 2020, 38, 514–521 DOI: 10.1007/s10118-020-2353-6. DOI：

Jing Mao, Fang-Fang Wu, Wen-Hui Shi, et al. Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery[J]. Chinese Journal of Polymer Science, 2020, 38(5): 514-521. DOI: 10.1007/s10118-020-2353-6. DOI：

摘要

Abstract

Aqueous zinc-ion batteries

especially Zn-MnO

battery

have attracted intensive attention owing to their unique features of high capacity

environmental friendliness

and safety. However

the problem of Mn dissolution hinders the development of zinc-ion batteries with long-term usage and high-rate performance. In this work

a novel preparation method for the polyaniline (PANI)-coated composite aerogel of MnO

and rGO (MnO

/rGO/PANI) electrode is reported. The obtained composite possesses high electrical conductivity

and also effectively suppresses the dissolution of Mn. The fabricated MnO

/rGO/PANI//Zn battery exhibits a high capacity of 241.1 mAh·g

−1

at 0.1 A·g

−1

and an excellent capacity retention of 82.7% after 600 charge/discharge cycles. In addition

the rapid diffusion coefficient of the MnO

/rGO/PANI electrode was further examined by galvanostatic intermittent titration technique. This work provides new insights into the development of high-performance Zn-MnO

battery with a better understanding of its diffusion kinetics.

关键词

Keywords

references

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Preparation of Polyaniline-coated Composite Aerogel of MnO2 and Reduced Graphene Oxide for High-performance Zinc-ion Battery

DOI：10.1007/s10118-020-2353-6

摘要

Abstract

关键词

Keywords

references

Preparation of Polyaniline-coated Composite Aerogel of MnO₂ and Reduced Graphene Oxide for High-performance Zinc-ion Battery