Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides

Kai-Ju Luo; Li-Bo Huang; Yan Wang; Jun-Rong Yu; Jing Zhu; Zu-Ming Hu

doi:10.1007/s10118-019-2328-7

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Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides

ARTICLE | Updated：2019-09-19

- Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides
- Chinese Journal of Polymer Science Vol. 38, Issue 3, Pages: 268-277(2020)
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  wy@dhu.edu.cn (Y.W.)
  hzm@dhu.edu.cn (Z.M.H.)
- Funds：
- DOI：10.1007/s10118-019-2328-7
  CLC：
- Received：28 May 2019，
  
  Revised：2019-7-3，
  
  Accepted：08 July 2019，
  
  Online First：19 September 2019，
  
  Published：2020-03
- Accepted：
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Luo, K. J.; Huang, L. B.; Wang, Y.; Yu, J. R.; Zhu, J.; Hu, Z. M. Tailoring the properties of Diels-Alder reaction crosslinked high-performance thermosets by different bismaleimides. Chinese J. Polym. Sci. 2020, 38, 268–277.

Kai-Ju Luo, Li-Bo Huang, Yan Wang, et al. Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides[J]. Chinese Journal of Polymer Science, 2020, 38(3): 268-277.
Luo, K. J.; Huang, L. B.; Wang, Y.; Yu, J. R.; Zhu, J.; Hu, Z. M. Tailoring the properties of Diels-Alder reaction crosslinked high-performance thermosets by different bismaleimides. Chinese J. Polym. Sci. 2020, 38, 268–277. DOI： 10.1007/s10118-019-2328-7.

Kai-Ju Luo, Li-Bo Huang, Yan Wang, et al. Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides[J]. Chinese Journal of Polymer Science, 2020, 38(3): 268-277. DOI： 10.1007/s10118-019-2328-7.

摘要

Abstract

A series of Diels-Alder reaction cross-linked thermosets with recyclability and healability were prepared from furan-containing aromatic polyamide and bismaleimides with different chemical structures. The structures of synthesized bismaleimides were confirmed by

H nuclear magnetic resonance (

H-NMR) spectroscopy; their reversible cross-linking with the furanic polyamide was further detected by

H-NMR technique and sol-gel transition behavior. The dynamic mechanical analysis and tensile test revealed the variable thermal and mechanical properties of thermosets cross-linked by different bismaleimides and with different molar ratios of maleimide group to furan group (

ma/fur

). The tensile test also demonstrated that the better recyclability and solvent-assisted healability of thermosets cross-linked could be achieved by more flexible bismaleimides. This work is expected to provide valuable information for design of recyclable and healable high-performance thermosets with desired properties.

关键词

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references

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