Effect of Butyl <italic style="font-style: italic">α</italic>-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced <italic style="font-style: italic">via</italic> Aqueous Emulsion Polymerization-induced Self-assembly

Shou-Kuo Man; Xiao Wang; Jin-Wen Zheng; Ze-Sheng An

doi:10.1007/s10118-019-2303-3

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Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly

ARTICLE | Updated：2019-09-06

- Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly
- Chinese Journal of Polymer Science Vol. 38, Issue 1, Pages: 9-16(2020)
- Affiliations：
  
  a.Institute of Nanochemistry and Nanobiology, College of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
  b.State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
- Author bio：
  
  wangxiao93@t.shu.edu.cn (X.W.)
  anzesheng@jiu.edu.cn (Z.S.A.)
- Funds：
- DOI：10.1007/s10118-019-2303-3
  CLC：
- Received：12 April 2019，
  
  Revised：2019-5-17，
  
  Accepted：25 May 2019，
  
  Online First：06 September 2019，
  
  Published：2020-01
- Accepted：
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Citation: Man, S. K.; Wang, X.; Zheng, J. W.; An, Z. S. Effect of butyl α-hydroxymethyl acrylate monomer structure on the morphology produced via aqueous emulsion polymerization-induced self-assembly. Chinese J. Polym. Sci. 2020, 38, 9–16

Shou-Kuo Man, Xiao Wang, Jin-Wen Zheng, et al. Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly[J]. Chinese Journal of Polymer Science, 2020, 38(1): 9-16. DOI: 10.1007/s10118-019-2303-3.
Citation: Man, S. K.; Wang, X.; Zheng, J. W.; An, Z. S. Effect of butyl α-hydroxymethyl acrylate monomer structure on the morphology produced via aqueous emulsion polymerization-induced self-assembly. Chinese J. Polym. Sci. 2020, 38, 9–16 DOI： 10.1007/s10118-019-2303-3.

Shou-Kuo Man, Xiao Wang, Jin-Wen Zheng, et al. Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly[J]. Chinese Journal of Polymer Science, 2020, 38(1): 9-16. DOI: 10.1007/s10118-019-2303-3. DOI：

摘要

Abstract

Polymerization-induced self-assembly (PISA) is an efficient and versatile method to afford polymeric nano-objects with polymorphic morphologies. Compared to dispersion PISA syntheses based on soluble monomers

the vast majority of emulsion PISA formulations using insoluble monomers leads to kinetically-trapped spheres. Herein

we present aqueous emulsion PISA formulations generating worms and vesicles besides spheres. Two monomers with different butyl groups

-butyl (

BHMA) and

tert

-butyl (

BHMA)

-hydroxymethyl acrylate

and thus possessing different water solubilities were synthesized

via

Baylis-Hillman reaction. Photoinitiated aqueous emulsion polymerizations of

BHMA and

BHMA employing poly(ethylene glycol) macromolecular chain transfer agents (macro-CTAs

PEG

-CTA

and PEG

113

-CTA) at 40 °C were systematically investigated to evaluate the effect of monomer structure and solubility on the morphology of the generated block copolymer nano-objects. Higher order morphologies including worms and vesicles were readily accessed for

BHMA

which has a higher water solubility than that of

BHMA. This study proves that plasticization of the core-forming block by water plays a key role in enhancing chain mobility required for morphological transition in emulsion PISA.

关键词

Keywords

references

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⁰

Effect of Butyl α-Hydroxymethyl Acrylate Monomer Structure on the Morphology Produced via Aqueous Emulsion Polymerization-induced Self-assembly

DOI：10.1007/s10118-019-2303-3

摘要

Abstract

关键词

Keywords

references